A complete and easily accessible means of calculating surface exposure ages or erosion rates from Be and Al measurements

We codify previously published means of calculating exposure ages and erosion rates from ¹⁰Be and ²⁶Al concentrations in rock surfaces, and present a single complete and straightforward method that reflects currently accepted practices and is consistent with existing production rate calibration measurements. It is intended to enable geoscientists, who wish to use cosmogenic-nuclide exposure age or erosion rate measurements in their work to: (a) calculate exposure ages and erosion rates; (b) compare previously published exposure ages or erosion rate measurements on a common basis; (c) evaluate the sensitivity of their results to differences between published production rate scaling schemes. The method is available online at http://hess.ess.washington.edu.     

On residual currents in the central strait of Georgia,B.C.: Research note

Abstract

Numerical modelling effort to understand low‐frequency circulation in the Strait of Georgia has been found to underestimate the strength of the circulation by roughly an order of magnitude. At least in part, this model defect may be due to the absence of statistical‐dynamical tendencies that result from eddy interactions (in reality). This defect is generic to ocean numerical models ranging from estuarine to global‐scale applications. A simple change to the formulation of eddy viscosity may help, making models somewhat “less wrong” if not yet “right”.     

Identification of water quality and zooplankton characteristics in Daya Bay, China, from 2001 to 2004

Data collected from 12 marine monitoring stations in Daya Bay from 2001 to 2004 reveal a substantial change in ecological environment in this region. Cluster analysis based on water quality and zooplankton results divided stations into three clusters: Cluster I consisted of stations S1, S2 and S6 in the south part of Daya Bay; Cluster II consisted of stations S3, S8 and S11 in the cage culture areas in the southwest part, the northwest part near Aotou harbor and the northeast part near the Fanhe harbor of Daya Bay; Cluster III consisted of stations S4, S5, S7, S9, S10 and S12 that were in southwest, the middle and northeast parts of Daya Bay. Bivariate correlations between zooplankton biomass and the major physical and nutrient variables were evaluated for all stations. The zooplankton biomass in all stations correlated positively with salinity, pH, secchi, NO₃-N, NH₄-N, TIN/PO₄-P and SiO₃-Si/PO₄-P, and negatively correlated with temperature, DO, COD, NO₂-N and TIN, PO₄-P, SiO₃-Si and BOD₅. Factors analysis shows high positive loading salinity, secchi and NH₄-N of three clusters, which indicates that all stations of the three clusters were primarily grouped according to their respective nutrient conditions. The results of multivariate statistical analysis revealed that temperature, DO, TIN and BOD₅ could also play an important role in determining the biomass of the zooplankton in Daya Bay, especially in the stations near the nuclear power plants and in the cage culture areas.     

Influence of Pore Fluid Chemistry on the Mechanical Properties of Clay-Based Materials

The producers of nuclear waste, within all countries exploring options, including Canada, have determined the long-term solution to be a deep geological repository. In the Canadian concept, within the deep geologic repository a number of clay-based barriers will separate the containers from the surrounding geosphere. Following placement the surrounding groundwater will infiltrate into the repository. In order to analyze the performance of the repository under very complex conditions, accurate material properties are required. The chemistry of the host rock is an important aspect as the behaviour of clay-based barrier materials could be affected by the saturating saline groundwater. This paper investigates the saturated mechanical behaviour of light backfill (composed of 50 % silica sand and 50 % Na-bentonite clay) and dense backfill (composed of 70 % crushed granite, 25 % glacial lake clay and 5 % Na-bentonite clay) and the quantifying the effect of pore fluid chemistry on the strength and compressibility behaviour of the materials. The results indicate that light backfill behaviour is strongly influenced by its pore fluid chemistry while dense backfill shows limited effects. The material parameters of light backfill and dense backfill are interpreted for input into numerical simulations. These results and interpretation enrich the understanding of the mechanical response of light and dense backfill, two components of the sealing system of the Canadian deep geologic repository.     

Intermediate sulfidation epithermal gold-base metal deposits in Tertiary subaerial volcanic rocks,Sahinli/Tespih Dere (Lapseki/Western Turkey)

Gold in the Sahinli and Tespih Dere intermediate sulfidation gold-base metal deposits in Western Turkey occurs in relatively deep epithermal quartz veins along with base metal minerals which have epithermal textures, including plumose quartz, vug infills, comb and cockade textures and matrix-supported milled breccias. The total sulfide content of the veins in the area is variable ranging from < 1% to 60% and is dominated by pyrite, galena, sphalerite and chalcopyrite. Sphalerite is Fe-poor (0.6 to 1.4 mol% FeS). Minor amounts of Ag-rich tetrahedrite are present. Primary hydrothermal alteration minerals include illite/muscovite, mixed-layer illite/smectite (11.6 Å) and clinochlore towards the east and, alunite, dickite/nacrite and pyrophyllite towards the west at Sahinli; major illite/muscovite and dickite occur at Tespih Dere and Sarioluk, respectively.Fluid inclusions in main-stage quartz at Sahinli are only liquid-rich, with homogenization temperatures ranging from 220 to 322 °C and the majority of T_h values between 250 and 300 °C. Salinity ranges from 4.3 to 6.9 wt.% NaCl equiv. First ice-melting temperatures (T_mf) between ?24.5 and ?19.0 °C indicate that the fluids were dominated by NaCl – H₂O during mineralization. The relatively higher average T_h at the Tespih Dere deposit (295 °C) is attributed to a relatively deeper level of exposure.Calculated δ¹⁸O values indicate that ore-forming hydrothermal fluids in the study area had δ¹⁸O_H2O ranging from + 1.1 to + 9.7‰ (average = 3.8‰), strongly ¹⁸O-enriched compared with present-day hydrothermal meteoric water in the area (δ¹⁸O = ?8.5‰). δD values of fluid inclusions in quartz range from ?58 to ?93‰ and δD values of clay minerals and alunite from ?40 to ?119‰. δD values from intermediate argillic alteration (average = ?68‰) in the study area are very similar to δD values of the present-day local geothermal system (average δD = ?54‰) whereas δD values from advanced-argillic alteration (average δD = ?33‰) are very different from the present-day local geothermal system.The δ³⁴S values in samples from the Sahinli and Tespih Dere deposits average ?2.9‰ for pyrite; ?3.3‰ for chalcopyrite; ?5.4‰ for sphalerite and ?7.6‰ for galena. These data are consistent with derivation of the sulfur from either igneous rocks or possibly from local wallrock.     

Delta13C and delta15N shifts in benthic invertebrates exposed to sewage from McMurdo Station, Antarctica

In an effort to identify biomonitors for contamination of Antarctic marine benthos by sewage, this study determines whether the US Antarctic Program’s McMurdo Station produces a benthic sewage footprint and whether resident megafauna are assimilating sewage-derived material. We identified strong C and N isotopic gradients in benthic sediment as a function of downstream distance from McMurdo Station’s point-source sewage addition. Sediment C and N isotope ratios approached marine background levels at the sampling end-point 612 m downcurrent. Based on isotope abundances in their tissues, at least some sewage C and N were assimilated by the sedentary, suspension feeding soft coral Alcyonium antarcticum, ascidian Cnemidocarpa verrucosa and bivalve Laternula elliptica. However, as inferred by tissue-sediment differences in downstream isotope trends, such assimilation was not in proportion to sewage exposure and input, therefore implying non-generalist feeding behavior by these species. In contrast, the motile, generalist feeding sea urchin Sterechinus neumayeri, sea star Odontaster validus and ribbon worm Parborlasia corrugatus showed isotopic evidence of sewage C and N assimilation roughly in proportion to sewage input. We recommend these generalist feeders for further use as biomonitors at this site now that sewage treatment has been implemented. As these species are circumpolar in distribution, they may also prove useful elsewhere in the Antarctic.     

Cycles and shifts: 1,300 years of multi-decadal temperature variability in the Gulf of Alaska

The Gulf of Alaska (GOA) is highly sensitive to shifts in North Pacific climate variability. Here we present an extended tree-ring record of January–September GOA coastal surface air temperatures using tree-ring width data from coniferous trees growing in the mountain ranges along the GOA. The reconstruction (1514–1999), based on living trees, explains 44% of the temperature variance, although, as the number of chronologies decreases back in time, this value decreases to, and remains around ∼30% before 1840. Verification of the calibrated models is, however, robust. Utilizing sub-fossil wood, we extend the GOA reconstruction back to the early eighth century. The GOA reconstruction correlates significantly (95% CL) with both the Pacific Decadal Oscillation Index (0.53) and North Pacific Index (−0.42) and therefore likely yields important information on past climate variability in the North Pacific region. Intervention analysis on the GOA reconstruction identifies the known twentieth century climate shifts around the 1940s and 1970s, although the mid-1920s shift is only weakly expressed. In the context of the full 1,300 years record, the well studied 1976 shift is not unique. Multi-taper method spectral analysis shows that the spectral properties of the living and sub-fossil data are similar, with both records showing significant (95% CL) spectral peaks at ∼9–11, 13–14 and 18–19 years. Singular spectrum analysis identifies (in order of importance) significant oscillatory modes at 18.7, 50.4, 38.0, 91.8, 24.4, 15.3 and 14.1 years. The amplitude of these modes varies through time. It has been suggested (Minobe in Geophys Res Lett 26:855–858, 1999) that the regime shifts during the twentieth century can be explained by the interaction between pentadecadal (50.4 years) and bidecadal (18.7 years) oscillatory modes. Removal of these two modes of variance from our GOA time series does indeed remove the twentieth century shifts, but many are still identified prior to the twentieth century. Our analysis suggests that climate variability of the GOA is very complex, and that much more work is required to understand the underlying oscillatory behavior that is observed in instrumental and proxy records from the North Pacific region.

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Shock melts in QUE 94411, Hammadah al Hamra 237, and Bencubbin: Remains of the missing matrix?

Abstract— We have studied the CB carbonaceous chondrites Queen Alexandra Range (QUE) 94411, Hammadah al Hamra (HH) 237, and Bencubbin with an emphasis on the petrographical and mineralogical effects of the shock processing that these meteorite assemblages have undergone. Iron‐nickel metal and chondrule silicates are the main components in these meteorites. These high‐temperature components are held together by shock melts consisting of droplets of dendritically intergrown Fe,Ni‐metal/sulfide embedded in silicate glass, which is substantially more FeO‐rich (30–40 wt%) than the chondrule silicates (FeO <5 wt%). Fine‐grained matrix material, which is a major component in most other chondrite classes, is extremely scarce in QUE 94411 and HH 237, and has not been observed in Bencubbin. This material occurs as rare, hydrated matrix lumps with major and minor element abundances roughly similar to the ferrous silicate shock melts (and CI). We infer that hydrated, fine‐grained material, compositionally similar to these matrix lumps, was originally present between the Fe,Ni‐metal grains and chondrules, but was preferentially shock melted. Other shock‐related features in QUE 94411, HH 237, and Bencubbin include an alignment and occasionally strong plastic deformation of metal and chondrule fragments. The existence of chemically zoned and metastable Fe,Ni‐metal condensates in direct contact with shock melts indicates that the shock did not substantially increase the average temperature of the rock. Because porphyritic olivine‐pyroxene chondrules are absent in QUE 94411, HH 237, and Bencubbin, it is difficult to determine the precise shock stage of these meteorites, but the shock was probably relatively light (S2–S3), consistent with a bulk temperature increase of the assemblages of less than ?300 °C. The apparently similar shock processing of Bencubbin, Weatherford, Gujba (CB_a) and QUE 94411/HH 237 (CB_b) supports the idea of a common asteroidal parent body for these meteorites.     

Star formation in a multi-phase interstellar medium

This contribution reports on our first efforts to simulate a multiphase interstellar medium on a kiloparsec scale in three dimensions with the stars and gas modeled self-consistently. Starting from inhomogenous initial conditions, our closed box simulations follow the gas as it cools and collapses under its own self-gravity to form stars which eventually return material and energy back through supernovae explosions and winds. This revised version was published online in August 2006 with corrections to the Cover Date.