Trace element composition of near-surface silica deposits—A powerful tool for detecting hydrothermal mineral and energy resources

Extensive Paleozoic sinter deposits occur at the surface associated with sub-surface quartz veining and epithermal Au mineralisation in the Drummond Basin, Australia. We investigated the trace element composition of the sinter deposits and quartz veins in an attempt to develop a new geochemical exploration guide for geological resources. The Drummond Basin hydrothermal silica deposits are unique in having anomalously enriched incompatible element (Cs, Li, Be, U, Th and REE) concentrations in comparison to hydrothermal quartz veins from various granitic-pegmatitic systems elsewhere. The development of relative Ce deficiencies (Ce/Ce*_norm < 1) in silica deposits indicate preferential mobilisation of REE over Ce from source rocks by oxidised hydrothermal fluids, leading to relative Ce enrichment in the source material (e.g., rhyolite intrusions). Sinters and quartz veins and some volcanic source rocks show a conspicuous positive Y anomaly relative to REE. This is interpreted in terms of Y fractionation due to fluorine complexation with REE during hydrothermal activity. The majority of sinter and quartz samples within or near the Au mineralisation zone are more enriched in mobile elements (Cs, Li, Rb and Be) than the silica deposits from areas distal to the mineralised area. Normalised Y–REE patterns of the sinter deposits, quartz veins, and wall rocks provide important information on the physico-chemical environment of epithermal mineral deposition in geothermal systems. Trace element systematics as revealed in the current study, particularly in relation to the alkali element mobility, have significant implications for finding new prospect areas and evaluating the potential of existing prospect areas for epithermal metal deposits and active geothermal fields.     

A numerical model of a solar flare based on electron beam heating of the chromosphere

There are two parts to this paper. In the first we calculate the hydrodynamic response of the solar atmosphere to the injection of an intense beam of electrons in a numerical simulation of a solar flare. In the second we predict the spectroscopic consequences of the hydrodynamic behaviour calculated in the first part. The hydrodynamics is predicted by solving the equations of conservation of mass, momentum, and energy. The latter is expressed as two temperature equations; one for the electrons and the other for the neutral atoms and positive ions of hydrogen. The equations are solved in one dimension and the geometric form is of a semi-circular loop having its ends in the photosphere. The results show how the loop is filled at supersonic speed with plasma at temperatures characteristic of flares. At the same time a compression wave is predicted to propagate down towards the photosphere. After the heating pulse stops, the plasma that has risen into the loop, starts to decay and return to the condition it was in before the pulse started. In predicting the spectrum that would be emitted by such a plasma calcium was chosen for illustration. The first and main part of this calculation was setting up and solving the time-dependent equations of ionization/recombination. In order to provide a standard for comparison the same ionization and recombination rate coefficients are used to predict the steady-state distribution of populations of ionization stages. This is then compared with the distribution found from the time-dependent solution and shows that there is a negligibly small time lag predicted by the time-dependent result. However the more significant comparisons to make are between the temperatures of the peak abundances of the various ions under the assumptions of steady-state and time-dependent ionization. For the particular circumstances chosen here the temperature differences are predicted to be in the neighbourhood of 10% or less and in view of the overall accuracy of the atomic data are not significant. It would appear therefore that the much simpler assumption of steady-state ionization balance leads to results of acceptable accuracy for the particular case considered.     

Distribution, magnitude and characterization of the toxicity of Ukrainian estuarine sediments

During the Soviet era, Ukraine was an important industrial and agricultural region of the Soviet Union. This industrial and agricultural activity resulted in contamination of Ukraine’s estuaries with legacy anthropogenic pollutants. Investigations on the toxicological effects of this estuarine contamination have been limited. For this research, we measured the toxicity of contaminated sediments from four Ukrainian estuaries to several aquatic organisms over 3 years. Sediment chemical analyses and whole sediment toxicity identification evaluations (TIEs) were also performed to determine the classes of contaminants contributing to toxicity. Toxic sediments were observed in several of the Ukrainian estuaries and chemical analyses of the sediments demonstrated anthropogenic contaminants were widely distributed. Contaminants were also detected in macrobenthic organisms collected from the sediments. Several lines of evidence, including TIEs, indicated hydrophobic organic chemicals (HOCs) were contributing substantially to observed toxicity. This information can guide environmental managers to prioritize portions of the estuaries requiring remediation.     

An upper‐ocean general circulation model for the north pacific: Preliminary experiments

Abstract

A model with two active layers, a mixed layer and a pycnocline layer, over a semipassive deep ocean is described. The model is used to simulate a climatological seasonal cycle in the upper North Pacific. The formulation is similar to that in Cherniawsky et al. (1990). The model resolution is 1° latitude by 1.5° longitude, extending from 62°N to the equator. It is driven with monthly wind stress (Hellerman and Rosenstein, 1983) and with Newtonian heat and freshwater fluxes, which were inferred from climatological (Levitus, 1982) sea‐surface monthly temperatures and annual mean salinities. The monthly temperature anomalies (without the annual mean) are multiplied by a prescribed gain factor and advanced in time, compensating for time delay in the response of the mixed layer. No‐slip and no‐flux constraints are applied on north, east, west and land boundaries, while the following open boundary conditions are used at the equator: (a) free‐slip on zonal velocities in the two layers; (b) a prescribed meridional transport, due to local curl of the wind stress, in the mixed layer; (c) an antisymmetric meridional velocity plus a small flux‐balancing term in the second layer; and (d) across‐equator symmetry for layer depths, temperatures and salinities. Sensitivity to two aspects of parametrization is investigated: (1) the change to horizontal diffusion/viscosity coefficients that depend on the velocity deformation field (as in Smagorinsky, 1963), and (2) the use of idealized piecewise‐linear profiles for second‐layer temperatures and salinities for calculating mixed layer entrainment fluxes.     

Muddling through with climate change targets: a multi-level governance perspective on the transport sector

The UK Climate Change Act 2008 commits to a reduction of 80% in national GHG emissions by 2050 compared to 1990 levels. This article explores what happens next where these top-level aspirations are expected to be turned into radical action. It does so through examination of the transport sector, which is a highly complex, fragmented, and multi-level delivery environment. The research draws on cases studies of four major cities with different governance structures within the two distinct, yet connected, national contexts of England and Scotland. It integrates a range of theoretical legacies, namely ‘muddling through’, multi-level governance, and positional analysis, to look across governmental layers and out to non-governmental actors at all levels. Underneath the 80% target, the framework for action remains unclear. Lower-tiered authorities report difficulties in acting in a more comprehensive or rapid manner than upper tiers of government, largely because of the potential costs involved and a significant resource dependency on national governments. Ambition is also tempered by conflicts with economic growth objectives and the difficulties in aligning the objectives of the myriad of public and private organizations that need to take action.     

Methods for exploring management options to reduce greenhouse gas emissions from tropical grazing systems

Increasing atmospheric concentrations of greenhouse gases are expected to result in global climatic changes over the next decades. Means of evaluating and reducing greenhouse gas emissions are being sought. In this study an existing simulation model of a tropical savanna woodland grazing system was adapted to account for greenhouse gas emissions. This approach may be able to be used in identifying ways to assess and limit emissions from other rangeland, agricultural and natural ecosystems.GRASSMAN, an agricultural decision-support model, was modified to include sources, sinks and storages of greenhouse gases in the tropical and sub-tropical savanna woodlands of northern Australia. The modified model was then used to predict the changes in emissions and productivity resulting from changes in stock and burning management in a hypothetical grazing system in tropical northeastern Queensland. The sensitivity of these results to different Global Warming Potentials (GWPs) and emission definitions was then tested.Management options to reduce greenhouse gas emissions from the tropical grazing system investigated were highly sensitive to the GWPs used, and to the emission definition adopted. A recommendation to reduce emissions by changing burning management would be toreduce fire frequency if both direct and indirect GWPs of CO₂, CH₄, N₂O, CO and NO are used in evaluating emissions, but toincrease fire frequency if only direct GWPs of CO₂, CH₄ and N₂O are used. The ability to reduce greenhouse gas emissions from these systems by reducing stocking rates was also sensitive to the GWPs used. In heavily grazed systems, the relatively small reductions in stocking rate needed to reduce emissions significantly should also reduce the degradation of soils and vegetation, thereby improving the sustainability of these enterprises.The simulation studies indicate that it is possible to alter management to maximise beef cattle production per unit greenhouse gases or per unit methane emitted, but that this is also dependent upon the emission definition used. High ratios of liveweight gain per unit net greenhouse gas emission were found in a broadly defined band covering the entire range of stocking rates likely to be used. In contrast, high values of liveweight gain per unit anthropogenic greenhouse gas emission were found only at very low stocking rates that are unlikely to be economically viable.These results suggest that policy initiatives to reduce greenhouse gas emissions from tropical grazing systems should be evaluated cautiously until the GWPs have been further developed and the implications of emission definitions more rigorously determined.     

Errors and uncertainty in physically-based rainfall-runoff modelling of catchment change effects

The error in physically-based rainfall-runoff modelling is broken into components, and these components are assigned to three groups: (1) model structure error, associated with the model’s equations; (2) parameter error, associated with the parameter values used in the equations; and (3) run time error, associated with rainfall and other forcing data. The error components all contribute to “integrated” errors, such as the difference between simulated and observed runoff, but their individual contributions cannot usually be isolated because the modelling process is complex and there is a lack of knowledge about the catchment and its hydrological responses. A simple model of the Slapton Wood Catchment is developed within a theoretical framework in which the catchment and its responses are assumed to be known perfectly. This makes it possible to analyse the contributions of the error components when predicting the effects of a physical change in the catchment. The standard approach to predicting change effects involves: (1) running “unchanged” simulations using current parameter sets; (2) making adjustments to the sets to allow for physical change; and (3) running “changed” simulations. Calibration or uncertainty-handling methods such as GLUE are used to obtain the current sets based on forcing and runoff data for a calibration period, by minimising or creating statistical bounds for the “integrated” errors in simulations of runoff. It is shown that current parameter sets derived in this fashion are unreliable for predicting change effects, because of model structure error and its interaction with parameter error, so caution is needed if the standard approach is to be used when making management decisions about change in catchments.     

Entanglement of Antarctic fur seals at Bouvetøya, Southern Ocean

Entanglements of Antarctic fur seals Arctocephalus gazella were recorded during four summers from 1996 to 2002 at the subantarctic island, Bouvetøya. Rates of entanglement varied between 0.024% and 0.059%. These rates are low for a pinniped population and might be because of the geographic isolation of the haulout site. An apparent decrease in the levels of entanglement over the course of the study was likely due, at least in part, to the removal of entanglements by observers. At least two-thirds of entangling materials were generated by fishery sources. Since there is no known local source of anthropogenic marine pollution, seals become entangled either in waters distant from the island, or when materials drift into local waters. Significantly more subadults were found entangled than expected from the postulated population age class distribution.