壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

一类信号恢复问题的投影迭代硬阈值算法

本文给出了基于L₀模求解该问题的非凸模型,借助于稀疏正则化方法来克服问题的不适定性。该模型利用紧小波框架对信号进行稀疏逼近,并利用L₀模度量稀疏性。提出了求解该模型的投影迭代硬阈值算法,并证明了算法的全局收敛性。该算法每一步都有闭式解,计算过程简洁高效。数值实验表明,方法在重建信号的视觉质量和量化指标方面均优于所对比的pFISTA方法。     

北康-曾母盆地中中新世以来层序地层样式特征探讨

开展地震资料解释,分析上超、下超、顶超等地震反射终止关系、不整合面以及沉积趋势,识别出北康-曾母盆地中中新世以来14个三级层序界面。在层序界面内部,通过层序地层内幕结构刻画和原形剖面恢复,并结合地层堆砌方式,在北康-曾母盆地中中新世以来的层序地层内,划分了海进、高位正常海退、强制海退和低位正常海退4种成因单元。通过进一步研究该4种成因单元内地层结构和相分布关系,提出北康-曾母盆地中中新世以来的3种层序地层样式,即陆架边缘富砂型三角洲进积楔、退积型生物礁和陆架边缘富砂-富泥型退积楔,其中,沉积物源供应量充足且可容空间减小时,发育富砂的三角洲进积楔,陆架边缘-斜坡-盆地区域发育含砂深水扇;而可容空间增量远大于沉积物供应量时,发育退积型生物礁和富砂-富泥退积楔,斜坡-盆地区域含砂深水扇欠发育。     

黑潮及相邻海域表层砂壳纤毛虫分布模式:以夏季黄海、东海至西太平洋断面为例

2019年夏季对沿黄、东海至西太平洋跨越黑潮一个断面(122°E～145°E)的表层砂壳纤毛虫群落进行调查,研究了黑潮中砂壳纤毛虫与相邻水体的差异.根据水文环境及各站位所处的空间位置,我们将研究区域划分为大洋边缘区域、黑潮区域和大洋区域.各站位砂壳纤毛虫的丰度范围为3.95～31.94 ind·L–1,种丰富度范围为6...     

Unveiling controls of the latitudinal gradient of surface pCO2 in the Kuroshio Extension and its recirculation regions（northwestern North Pacific） in late spring

In the northwestern North Pacific, annual net air-sea CO₂ flux is greatest in the Kuroshio Extension（KE） zone,owing to its low annual mean partial pressure of CO₂（pCO₂）, and it decreases southward across the basin. To quantify the influences of factors controlling the latitudinal gradient in CO₂ uptake, sea surface pCO₂ and related parameters were investigated in late spring of 2018 in a study spanning the KE, Kuroshio Recirculation（KR）, and...     

Simulating the influence of various nutrient sources on hypoxia off the Changjiang River Estuary

Hypoxia is increasingly reported off the Changjiang River Estuary with the confluence of multiple high volume nutrient sources. The Regional Ocean Modeling System coupled with a biological model was used to analyze the effect of different nutrient sources on the development of hypoxia off the Changjiang River Estuary. By comparing to observed data, our model suitably captured the regional dynamics of chlorophyll a, dissolved oxygen, and nutrient concentration. A series of sensitivity experiments were conducted to investigate the hypoxia response to the various nutrient sources, such as loading from the Changjiang River, Kuroshio and Taiwan Warm Current. Our model results indicated that nutrients from different sources significantly influenced the hypoxia off the Changjiang River Estuary, and it was mostly affected by nutrients sourced from the Kuroshio. The nutrients input from the Changjiang River had larger impacts on the hypoxia in the north of 30°N than that in the south of 30°N. The nutrients sourced from the Taiwan Strait had a least influence on the hypoxia off the Changjiang River Estuary.     

Characteristics of sea ice kinematics from the marginal ice zone to the packed ice zone observed by buoys deployed during the 9th Chinese Arctic Expedition

Sea ice growth and consolidation play a significant role in heat and momentum exchange between the atmosphere and the ocean. However, few in situ observations of sea ice kinematics have been reported owing to difficulties of deployment of buoys in the marginal ice zone (MIZ). To investigate the characteristics of sea ice kinematics from MIZ to packed ice zone (PIZ), eight drifting buoys designed by Taiyuan University of Technology were deployed in the open water at the ice edge of the Canadian Basin. Sea ice near the buoy constantly increased as the buoy drifted, and the kinematics of the buoy changed as the buoy was frozen into the ice. This process can be determined using sea ice concentration, sea skin temperature, and drift speed of buoy together. Sea ice concentration data showed that buoys entered the PIZ in mid-October as the ice grew and consolidated around the buoys, with high amplitude, high frequency buoy motions almost ceasing. Our results confirmed that good correlation coefficient in monthly scale between buoy drift and the wind only happened in the ice zone. The correlation coefficient between buoys and wind was below 0.3 while the buoys were in open water. As buoys entered the ice zone, the buoy speed was normally distributed at wind speeds above 6 m/s. The buoy drifted mainly to the right of the wind within 45° at wind speeds above 8 m/s. During further consolidation of the ice in MIZ, the direct forcing on the ice through winds will be lessened. The correlation coefficient value increased to 0.9 in November, and gradually decreased to 0.7 in April.     

基于遥感数据和表层声速的全海深声速剖面反演

海洋声速剖面严重影响着水下声传播特性,近实时地获取声速剖面对水下声通信、水下定位、鱼群探测等都有重要意义。单经验正交函数回归（single Empirical Orthogonal Function regression,sEOF-r）方法通过建立声速剖面的经验正交系数与海面遥感数据之间的线性回归关系来反演声速剖面。但是,海洋是一个复杂的动力系统,声速与海面遥感数据并不是简单的线性关系,因此,本文基于Argo历史网格数据,通过自组织映射（Self-Organizing Map,SOM）生成海平面高度异常（Sea Level Anomaly,SLA）、海表面温度（Sea Surface Temperature,SST）等海表遥感数据以及表层声速仪测量的表层声速与声速剖面异常之间的非线性映射;然后利用近实时的海表遥感数据和表层声速反演三维海洋声速场。声速剖面反演的结果表明,在多源信息融合的优势下,本文方法的反演性能最稳定且精度最高,声速剖面的平均反演精度比经典sEOF-r方法提高约2 m/s,比未考虑表层声速的经典SOM方法提高约1 m/s。     

Self-Weight Penetration Characteristics of the Suction Foundation with Different Diameters in Sand

During the self-weight penetration process of the suction foundation on the dense sand seabed, due to the shallow penetration depth, the excess seepage seawater from the outside to the inside of the foundation may cause the negative pressure penetration process failure. Increasing the self-weight penetration depth has become an important problem for the safe construction of the suction foundation. The new suction anchor foundation has been proposed, and the self-weight penetration characteristics of the traditional suction foundation and the new suction anchor foundation are studied and compared through laboratory experiments and analysis. For the above two foundation types, by considering five foundation diameters and two bottom shapes, 20 models are tested with the same penetration energy. The effects of different foundation diameters on the penetration depth, the soil plug characteristics, and the surrounding sand layer are studied. The results show that the penetration depth of the new suction foundation is smaller than that of the traditional suction foundation. With the same penetration energy, the penetration depth of the suction foundation becomes shallower as the diameter increases. The smaller the diameter of the suction foundation, the more likely it is to be fully plugged, and the smaller the height of the soil plug will be. In the stage of self-weight penetration, the impact cavity appears around the foundation, which may affect the stability of the suction foundation.

     

大陆岛入海沉积物通量的估算研究

大陆岛入海沉积物通量（Q_s）信息对于精确解译大陆架沉积记录的研究是个重要补充。针对如何估算大陆岛Q_s的科学问题,本文以中国东南部海域的8 227个大陆岛为例,提出了一种基于邻近大陆中小型河流Q_s的经验公式计算大陆岛Q_s的解决方案。该方案在实施时需设置两个假定,即大陆岛的Q_s法则遵循邻近大陆中小河流的Q_s法则和可将1个大陆岛当作1个河流流域计算其Q_s。结果表明：（1）经验公式计算的大陆岛Q_s为其最小估计值;如考虑大陆岛流域的具体情况,实际的Q_s值会稍微增加,但其增幅不超过n^0.13（n为流域数量）;（2）经验公式能获取大陆岛Q_s的大致数量级信息;大陆岛的总面积为4 418.49 km²,对应Q_s的数量级为10⁶ t/a,与邻近大陆中型河流入海通量的数量级相当;（3）在大河河口湾充填阶段完成以前,大陆岛沉积物是内陆架泥质沉积体的主要物源之一。因此,大陆岛入海沉积物会对大陆架沉积体系的形成和演化造成一定程度的影响,需引起研究人员的高度重视。