Development of techniques for monitoring gas-phase sodium species formed during coal combustion and gasification

The development of techniques suitable for on-line analysis of gas-phase molecular sodium species, resulting from the combustion and gasification of low-rank coals is described. In particular two techniques have been demonstrated, these are: (a) laser-induced photofragment fluorescence and (b) microwave spectroscopy. The photofragment technique can be applied in situ and yields excellent detection limits (<0.1 ppb of NaCl and 1 ppb NaOH) with good discrimination between the two major gas-phase species — NaCl and NaOH. Limitations of this technique include absorption of the ultraviolet (UV) photolysis excitation by other chemical species and particulates. Microwave spectroscopy shows promise in determining the sodium species distribution in the gas-phase. A purpose built analytical instrument (known as MILLIJET HT) is being developed for application in high-temperature environments. Early results indicate detection limits of <100 ppb NaCl. Lack of sensitivity for NaOH is being attributed to the formation of NaOH dimers and larger clusters. Detailed calculations of the dimer structure and the dimer-monomer reaction have been undertaken in order to maximise the performance of the instrument.     

A new late Pleistocene subfossil site (Tsaramody,Sambaina basin,central Madagascar) with implications for the chronology of habitat and megafaunal community change on Madagascar's Central Highlands

Madagascar is a complex ‘biodiversity hotspot’ with a rapidly dwindling biota. The Late Quaternary subfossil record includes many extinct species whose loss is attributed to natural climate change and human impacts. Investigation of the chronology of these events is challenging because few localities document pre‐Holocene communities not impacted by humans. Caves with extinct lemurs of large body size comprise some of Madagascar's richest subfossil sites, but provide only a limited window into the island's past. Open highland sites may have fewer primates, but may better document other megafauna, and allow the analysis of the role of the Central Highlands as refugia and as corridors for the dispersal of vertebrates before and after human arrival. Here we present a new subfossil site, Tsaramody (Sambaina basin, Central Madagascar), a high‐altitude wetland area that preserves a diverse late glacial and postglacial vertebrate community. Tsaramody bears testimony to fluctuations in the highland flora during the transition from glacial to postglacial conditions, and the composition of a highland vertebrate community before humans arrived. We compare its biota to those of other sites to begin to document the decline and disappearance of megafauna from some of Madagascar's open ecosystems – wetlands dominated by hippopotamuses and crocodylians. © 2019 John Wiley & Sons, Ltd.     

New interstellar masers in nonmetastable ammonia

We report the astronomical detections of several ammonia inversion transitions involving nonmetastable levels with energies as high s 1090 K above the ground state. The (J, K) = (9, 6) inversion transition shows maser-like emission in the directions of W51, NGC 7538, W49, and DR 21(OH). The NH3 (6, 3) line exhibits similar characteristics in W51 but is seen in absorption in NGC 7538. These are the first definite detections of ammonia masers in space. The intensities and narrow line widths (0.5-1.5 km s-1) for the emission features are in contrast to the previously detected broad, weak, nonmetastable lines attributed to thermal emission in these sources. Temporal variability appears to be evident in the (9, 6) emission in W49 over a 4 month period. The highly excited (J, K) = (9, 6) and (6, 3) ammonia lines are found in regions containing compact H II regions and strong infrared sources with associated H2O and OH masers; i.e., in regions of active star formation.     

Modelling methanol and hydroxyl masers in star-forming regions

Class II methanol masers are found in close association with OH main-line masers in many star-forming regions, where both are believed to flag the early stages in the evolution of a massive star. We have studied the formation of masers in methanol and OH under identical model conditions for the first time. Infrared pumping by radiation from warm dust at temperatures >100 K can account for the known maser lines in both molecules, many of which develop simultaneously under a range of conditions. The masers form most readily in cooler gas (<100 K) of moderately high density  (10⁵–10⁸ cm^-3)  , although higher gas temperatures and/or lower densities are also compatible with maser action. The agreement between the current model (developed for methanol) and the established OH maser trends is very encouraging, and we anticipate that further tuning of the model will further improve such agreement.
We find the gas-phase molecular abundance to be the key determinant of observable maser activity for both molecules. Sources exhibiting both 6668-MHz methanol and 1665-MHz OH masers have a typical flux density ratio of 16; our model suggests that this may be a consequence of maser saturation. We find that the 1665-MHz maser approaches the saturated limit for OH abundances >10^−7.3, while the 6668-MHz maser requires a greater methanol abundance >10⁻⁶. OH-favoured sources are likely to be less abundant in methanol, while methanol-favoured sources may be less abundant in OH or experiencing warm (>125 K), dense (∼10⁷ cm⁻³) conditions. These abundance requirements offer the possibility of tying the appearance of masers to the age of the new-born star via models of gas-phase chemical evolution following the evaporation of icy grain mantles.     

On the mechanism of the seasonal variability of SST in the tropical Indian Ocean

A general form of an equation that "explicitly" diagnoses SST change is derived. All other equations in wide use are its special case. Combining with the data from an ocean general circulation model (MOM2) with an integration of 10 years (1987-1996), the relative importances of various processes that determine seasonal variations of SST in the tropical Indian Ocean are compared mainly for January, April, July and October. The main results are as follows. (1) The net surface heat flux is the most important factor affecting SST over the Arabian Sea, the Bay of Bengal and the region south of the equator in January; in April, its influence covers almost the whole region studied; whereas in July and October, this term shows significance only in the regions south of 10°S and north of the equator, respectively. (2) The horizontal advection dominates in the East African-Arabian coast and the region around the equator in January and July; in October, the region is located south of 10°S. (3) The entrainment is s     

THE HISTORICAL GEOGRAPHY OF HONG KONG INVESTMENTS IN THE ASEAN REGION

Conventional studies of “Third World multinationals” tend to focus on their recent origins. This paper argues that the transnational operations of Hong Kong firms have had a long tradition originating in its Overseas Chinese networks and in the colonial experience of many Southeast Asian countries. Based on secondary and primary data, this paper takes a historical view to describe how the ASEAN operations of Hong Kong transnational corporations (HKTNCs) and their foreign direct investment (HKFDI) have evolved over more than a century to become one of the most important economic players in the ASEAN region. Four phases of their historical development are benchmarked in this paper. Before World War II, HKTNCs in the commercial and banking sectors had a notable presence in the region. It was, however, in the post-war period that HKTNCs and their FDI flows flourished. During the period 1945–69, industrialisation took off in Hong Kong and this led to the expansion of manufacturing HKTNCs into the ASEAN region. The real zenith of outward investment from Hong Kong was the 1970s and 1980s so that in the 1990s Hong Kong has become one of the largest investors in Indonesia, Singapore and Thailand.     

Class II maser candidates in substituted methanol: CH3OD, 13CH3OH, CH318OH and CH3SH

We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH₃OD, ¹³CH₃OH and CH₃¹⁸OH, and of CH₃SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, ¹²CH₃¹⁶OH. Several potential maser candidates are identified for CH₃OD, their detectability depending on the enrichment of this species in star-forming regions. In ¹³CH₃OH and CH₃¹⁸OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH₃SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.     

Correlation between magnetic susceptibility and distribution of heavy metals in contaminated sea-floor sediments of Hong Kong Harbour

 Magnetic susceptibility measurements were conducted on 24 vibrocores obtained from an area located off the northeastern coast of Lantau Island in Hong Kong. High intensities of magnetic susceptibility were detected in the uppermost sections of the majority of the cores. Several magnetic parameters measured for one of the cores suggest that the variations in the magnetic characteristics over depth are mainly due to varying concentrations of the magnetic minerals. Since a strong correlation has been found between magnetic susceptibility and the heavy metals Pb, Cu, Zn and Cr, an anthropogenic contamination origin is thought to be the cause. The present study shows that magnetic susceptibility is a fast, inexpensive and non-destructive method for the detection and mapping of contaminated sediments. Received: 12 August 1997 · Accepted: 18 November 1997