Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.     

26Al‐26Mg isotope systematics of the first solids in the early solar system

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.     

The Long-term Ecosystem Observatory: an integrated coastalobservatory

An integrated ocean observatory has been developed and operated in the coastal waters off the central coast of New Jersey, USA. One major goal for the Long-term Ecosystem Observatory (LEO) is to develop a real-time capability for rapid environmental assessment and physical/biological forecasting in coastal waters. To this end, observational data are collected from satellites, aircrafts, ships, fixed/relocatable moorings and autonomous underwater vehicles. The majority of the data are available in real-time allowing for adaptive sampling of episodic events and are assimilated into ocean forecast models. In this observationally rich environment, model forecast errors are dominated by uncertainties in the model physics or future boundary conditions rather than initial conditions. Therefore, ensemble forecasts with differing model parameterizations provide a unique opportunity for model refinement and validation. The system has been operated during three annual coastal predictive skill experiments from 1998 through 2000. To illustrate the capabilities of the system, case studies on coastal upwelling and small-scale biological slicks are discussed. This observatory is one part of the expanding network of ocean observatories that will form the basis of a national observation network     

Infrared photometry of comets Bowell and P/Stephan-Oterma

We report broadband infrared photometry of comets P/Stephan-Oterma and Bowell between 1 and 20 μm. Their JHK colors are similar to P/Meier and P/Tuttle and are compatible with scattering of sunlight by micron-sized grains. The thermal emission from P/Stephan-Oterma showed an effective temperature significantly higher than that expected from a blackbody in equilibrium. The thermal emission can be models be fit by models of the dust coma consisting of micron-sized grains. Most of the flux at all observed wavelengths comes from the dust grains rather than form the nucleus.     

Relative sea‐level observations in western Scotland since the Last Glacial Maximum for testing models of glacial isostatic land movements and ice‐sheet reconstructions

Observations of relative sea‐level change and local deglaciation in western Scotland provide critical constraints for modelling glacio‐isostatic rebound in northern Britain over the last 18 000 years. The longest records come from Skye, Arisaig and Knapdale with a shorter, Holocene, record from Kintail. Biostratigraphic (diatom, pollen, dinoflagellate, foraminifera and thecamoebian), lithological and radiocarbon analyses provide age and elevation parameters for each sea‐level index point. All four sites reveal relative sea‐level change that is highly non‐monotonic in time as the local vertical component of glacio‐isostatic rebound and eustasy (or global meltwater influx) dominate at different periods. Copyright © 2006 John Wiley & Sons, Ltd.     

Relative sea‐level changes,glacial isostatic modelling and ice‐sheet reconstructions from the British Isles since the Last Glacial Maximum

While contributing <1 m equivalent eustatic sea‐level rise the British Isles ice sheet produced glacio‐isostatic rebound in northern Britain of similar magnitude to eustatic sea‐level change, or global meltwater influx, over the last 18 000 years. The resulting spatially variable relative sea‐level changes combine with observations from far‐field locations to produce a rigorous test for quantitative models of glacial isostatic adjustment, local ice‐sheet history and global meltwater influx. After a review of the attributes of relative sea‐level observations significant for constraining large‐scale models of the isostatic adjustment process we summarise long records of relative sea‐level change from the British Isles and far‐field locations. We give an overview of different global theoretical models of the isostatic adjustment process before presenting intercomparisons of observed and predicted relative sea levels at sites in the British Isles and far‐field for a range of Earth and ice model parameters in order to demonstrate model sensitivity and the resolving power available from using evidence from the British Isles. For the first time we show a good degree of fit between relative sea‐level observations and predictions that are based upon global Earth and ice model parameters, independently derived from analysis of far‐field data, with a terrain‐corrected model of the British Isles ice sheet that includes extensive glaciation of the North Sea and western continental shelf, that does not assume isostatic equilibrium at the Last Glacial Maximum and keeps to trimline constraints of ice surface elevation. We do not attempt to identify a unique solution for the model lithosphere thickness parameter or the local‐scale detail of the ice model in order to provide a fit for all sites, but argue that the next stage should be to incorporate an ice‐sheet model that is based on quantitative, glaciological model simulations. We hope that this paper will stimulate this debate and help to integrate research in glacial geomorphology, glaciology, sea‐level change, Earth rheology and quantitative modelling. Copyright © 2006 John Wiley & Sons, Ltd.     

Associations between elevated atmospheric temperature and human mortality: a critical review of the literature

The effects of the anomalously warm European summer of 2003 highlighted the importance of understanding the relationship between elevated atmospheric temperature and human mortality. This review is an extension of the brief evidence examining this relationship provided in the IPCC’s Assessment Reports. A comprehensive and critical review of the literature is presented, which highlights avenues for further research, and the respective merits and limitations of the methods used to analyse the relationships. In contrast to previous reviews that concentrate on the epidemiological evidence, this review acknowledges the inter-disciplinary nature of the topic and examines the evidence presented in epidemiological, environmental health, and climatological journals. As such, present temperature–mortality relationships are reviewed, followed by a discussion of how these are likely to change under climate change scenarios. The importance of uncertainty, and methods to include it in future work, are also considered.