Geochemical, mineralogical and isotopic signatures of the Semikan, West Kasrık “Turkish” phosphorites from the Derik–Mazıdağı–Mardin area, SE Anatolia

The geochemistry and mineralogy of a condensed section, ~6 m thick of the West Kasrik member (Coniacian–Santonian) near the uplifted northern flank of the Mardin–Derik anticline (south-eastern Turkey) was studied. The only deposit exploited in Turkey is found in this area. The sediment textures as well as the mineralogical and the geochemical results collectively suggest that these recycled phosphorites accumulated in areas of intensive very early diagenesis of the sediments in highly oxic bottom waters, and almost no detrital apport. The total concentration of redox-sensitive trace metals is very low (<600 μg/g); in addition the structural CO₂ and F/P₂O₅ are unusually high (~5 wt % and 0.14, respectively). REE distribution shows a clear “seawater” pattern with a strongly negative Ce-anomaly (0.20 ± 0.02) and heavy REE enrichment (Lu_N/La_N = 1.50 ± 0.12), however their total concentration is very low. The low REE contents, quite unexpected in recycled phosphorites, are explained by the scarcity of terrigenous components which leads to minimal incorporation of REEs from detrital clastic phases in the CFA fraction. Weathering previously suggested as responsible for the high P enrichment of the Mazidagi phosphorites is rather improbable in the samples we studied, in view of their high structural CO₂, high F/P₂O₅, high (La/Nd)_N and (La/Sm)_N ratios, and high Sr/P and Ca/P of separated CFA fractions that all negate post-depositional weathering. More likely, the high P enrichment of some rocks (P₂O₅ content reaches 34%) was produced by sedimentary and early diagenetic processes acting in oxygenated areas of starved sedimentation on and around tectonic highs.     

Influence from Hydrological Modification on Energy and Nutrient Transference in a Deltaic Food Web

Alterations of hydrology are known to trigger changes in coastal ecosystems, such as the composition and abundances of local flora and fauna. It is less well known how these alterations lead to changes in nutrient and energy transfers in these systems. We used comparisons of stable isotope signatures (δ ¹³C, δ ¹⁵N, and δ ³⁴S) in the tissues of conspecific plants and animals collected on each side of the Mobile Bay Causeway to determine the extent to which the causeway may have altered energy and nutrient exchange between the Mobile–Tensaw Delta and upper Mobile Bay. While the δ ¹³C signatures of most plants and animals varied irrespective of their location relative with causeway location, their δ ¹⁵N and δ ³⁴S signatures were almost always more enriched south of the causeway, indicating significant alterations of trophic linkages within this estuarine food web. Dual isotope plots and mixing model analyses indicated that while terrestrial and floating plants were trophically important to consumers north of the causeway, submerged aquatic vegetation was more important to consumers south of the causeway. Although limited in spatial and temporal scale, our results preliminarily show that there are noteworthy differences in stable isotope signatures most likely due to the Mobile Bay Causeway altering energy and nutrient transference.     

Refractory inclusions from the ungrouped carbonaceous chondrites MacAlpine Hills 87300 and 88107

Abstract— MacAlpine Hills (MAC) 87300 and 88107 are two unusual carbonaceous chondrites that are intermediate in chemical composition between the CO3 and CM2 meteorite groups. Calcium‐aluminum‐rich inclusions (CAIs) from these two meteorites are mostly spinel‐pyroxene and melilite‐rich (Type A) varieties. Spinel‐pyroxene inclusions have either a banded or nodular texture, with aluminous diopside rimming Fe‐poor spinel. Melilite‐rich inclusions (Åk_4–42) are irregular in shape and contain minor spinel (FeO <1 wt%), perovskite and, more rarely, hibonite. The CAIs in MAC 88107 and 87300 are similar in primary mineralogy to CAIs from low petrologic grade CO3 meteorites but differ in that they commonly contain phyllosilicates. The two meteorites also differ somewhat from each other: melilite is more abundant and slightly more Al‐rich in inclusions from MAC 88107 than in those from MAC 87300, and phyllosilicate is more abundant and Mg‐poor in MAC 87300 CAIs relative to that in MAC 88107. These differences suggest that the two meteorites are not paired. The CAI sizes and the abundance of melilite‐rich CAIs in MAC 88107 and 87300 suggests a genetic relationship to CO3 meteorites, but the CAIs in both have suffered a greater degree of aqueous alteration than is observed in CO meteorites. Aluminum‐rich melilite in CAIs from both meteorites generally contains excess ²⁶Mg, presumably from the in situ decay of ²⁶Al. Although well‐defined isochrons are not observed, the ²⁶Mg excesses are consistent with initial ²⁶Al/²⁷Al ratios of approximately 3–5 times 10^?5. An unusual hibonite‐bearing inclusion is isotopically heterogeneous, with two large and abutting hibonite crystals showing significant differences in their degrees of mass‐dependent fractionation of ²⁵Mg/²⁴Mg. The two crystals also show differences in their inferred initial ²⁶Al/²⁷Al ratios, 1 × 10^?5 vs. ≤3 × 10^?6.     

Timeline analysis and wavelet multiscale analysis of the AKARI All-Sky Survey at 90 μm

We present a careful analysis of the point-source detection limit of the AKARI All-Sky Survey in the WIDE-S 90-μm band near the North Ecliptic Pole (NEP). Timeline analysis is used to detect IRAS ( Infrared Astronomy Satellite ) sources and then a conversion factor is derived to transform the peak timeline signal to the interpolated 90-μm flux of a source. Combined with a robust noise measurement, the point-source flux detection limit at signal-to-noise ratio  (S/N) > 5  for a single detector row is  1.1 ± 0.1 Jy  which corresponds to a point-source detection limit of the survey of ∼0.4 Jy.
Wavelet transform offers a multiscale representation of the Time Series Data ( tsd ). We calculate the continuous wavelet transform of the tsd and then search for significant wavelet coefficients considered as potential source detections. To discriminate real sources from spurious or moving objects, only sources with confirmation are selected. In our multiscale analysis, IRAS sources selected above 4σ can be identified as the only real sources at the Point Source Scales. We also investigate the correlation between the non- IRAS sources detected in timeline analysis and cirrus emission using wavelet transform and contour plots of wavelet power spectrum. It is shown that the non- IRAS sources are most likely to be caused by excessive noise over a large range of spatial scales rather than real extended structures such as cirrus clouds.     

Performance characteristics of a new electronic snow water equivalent sensor in different climates

The US Army ERDC CRREL and the US Department of Agriculture Natural Resources Conservation Service developed a square electronic snow water equivalent (e‐SWE) sensor as an alternative to using fluid‐filled snow pillows to measure SWE. The sensors consist of a centre panel to measure SWE and eight outer panels to buffer edge stress concentrations. Seven 3 m square e‐SWE sensors were installed in five different climate zones. During the 2011–2012 winter, 1.8 and 1.2 m square e‐SWE sensors were installed and operated in Oregon. With the exception of New York State and Newfoundland, the e‐SWE sensors accurately measured SWE, with R² values between the sensor and manual SWE measurements of between 0.86 and 0.98. The e‐SWE sensor at Hogg Pass, Oregon, accurately measured SWE during the past 8 years of operations. In the thin, icy snow of New York during midwinter 2008–2009, the e‐SWE sensors overmeasured SWE because of edge stress concentrations associated with strong icy layers and a shallow snow cover. The New York e‐SWE sensors' measurement accuracy improved in spring 2009 and further improved during the 2011–2012 winter with operating experience. At Santiam Junction, measured SWE from the 1.8 and 1.2 m square e‐SWE sensors agreed well with the snow pillow, 3 m square e‐SWE sensor, and manual SWE measurements until February 2013, when dust and gravel blew onto the testing area resulting in anomalous measurements. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Impact of the spatial distribution of imperviousness on the hydrologic response of an urbanizing basin

An event‐based model is used to investigate the impact of the spatial distribution of imperviousness on the hydrologic response of a basin characterized by an urban land use. The impact of the spatial distribution of imperviousness is investigated by accounting for its location within the basin when estimating the generated runoff and the hydrologic response. The event model accounts for infiltration and saturation excess; the excess runoff is routed to the outlet using a geomorphologic unit hydrograph. To represent the spatial distribution of rainfall and imperviousness, radar and remotely derived data are used, respectively. To estimate model parameters and analyse their behaviour, a split sample test and parameter sensitivity analysis are performed. From the analysis of parameters, we found the impervious cover tends to increase the sensitivity and storm dependency of channel routing parameters. The calibrated event model is used to investigate the impact of the imperviousness gradient by estimating and comparing hydrographs at internal locations in the basin. From this comparison, we found the urban land use and the spatial variability of rainfall can produce bigger increases in the peak flows of less impervious areas than the most urbanized ones in the basin. To examine the impacts of the imperviousness pattern, scenarios typifying extreme cases of sprawl type and clustered development are used while accounting for the uncertainty in parameters and the initial condition. These scenarios show that the imperviousness pattern can produce significant changes in the response at the main outlet and at locations internal to the overall watershed. Overall, the results indicate the imperviousness pattern can be an influential factor in shaping the hydrologic response of an urbanizing basin. Copyright © 2010 John Wiley & Sons, Ltd.     

Jupiter's atmospheric temperatures: From Voyager IRIS to Cassini CIRS

Retrievals performed on Cassini Composite Infrared Spectrometer data obtained during the distant Jupiter flyby in 2000/2001 have been used to generate global temperature maps of the planet in the troposphere and stratosphere, but to higher latitudes than were shown previously by Flasar et al. [Flasar, F.M., 39 colleagues, 2004a. Nature 427, 132-135; Flasar, F.M., 44 colleagues, 2004b. Space Sci. Rev. 115, 169-297]. Similar retrievals were performed on Voyager 1 IRIS data to provide the first detailed IRIS map of the stratosphere, and high latitudes in the troposphere. Thermal winds were calculated for each data set and show strong vertical shears in the zonal winds at low latitudes, and meridional temperature gradients indicate the presence of circumpolar jets, as well. The temperatures retrieved from the two spacecraft were also compared with yearly ground-based data obtained over the intervening two decades. Tropospheric temperatures reveal gradual changes at low latitudes, with little obvious seasonal or short-term variation [Orton et al., 1994. Science 265, 625-631]. Stratospheric temperatures show much more complicated behavior over short timescales, consistent with quasi-quadrennial oscillations at low latitudes, as suggested in prior analyses of shorter intervals of ground-based data [Orton et al., 1991. Science 252, 537-542; Friedson, A.J., 1999. Icarus 137, 34-55]. A scaling analysis indicates that meridional motions, mechanically forced by wave or eddy convergence, play an important role in modulating the temperatures and winds in the upper troposphere and stratosphere on seasonal and shorter timescales. At latitudes away from the equator, the mechanical forcing can be derived simply from a temporal record of temperature and its vertical derivative. Ground-based observations with improved vertical resolution and/or long-term monitoring from spacecraft are required for this purpose, though the Voyager and Cassini data given indications that the magnitude of the forcing is very small.