The effects of soil moisture on synthetic aperture radar delineation of geomorphic surfaces in the Great Basin, Nevada, USA

RADARSAT-1 synthetic aperture radar (SAR) images from the western Great Basin, North America are used to map geomorphic features using environmental data (increased soil moisture), differences in incidence angles and ascending/descending satellite passes. These attributes are shown to increase the ability to delineate subtle geomorphic features along old shorelines. The change in moisture and the temporal resolution of the images provides a unique opportunity to use moisture as a geomorphic mapping tool in addition to traditional techniques such as image texture and the size and shape of the image features.     

ANTARCTIC GEOGRAPHIC DATA INTEGRATION(AGDI) “BRINGING IT ALL TOGETHER”

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The impact of recent climate change on flooding and sediment supply within a Mediterranean mountain catchment,southwestern Crete,Greece

This paper presents work from a geomorphological investigation carried out in the Aradena Gorge, southwestern Crete, Greece. The gorge is typical of many steepland fluvial systems in the Mediterranean, with steep relief, coarse‐gravel sediments and high rates of sedimentation generated during intense winter storm events. Hillslope deposits and coarse‐gravel flood units within a 5 km section of the gorge have been mapped, dated (using lichenometry and dendrochronology), and their sedimentological characteristics recorded to establish a c. 200‐year record of flood frequency/magnitude and hillslope/channel sediment supply variability. This record has been compared with instrumented and previously published records of climate change from Crete and the Mediterranean region and used to establish the major controls on flooding and sediment dynamics within the Aradena Gorge. Rates of colluviation and sediment delivery to the channel appear to have been greater than the present sometime before c. AD 1800 and may be related to cooler climates with a more seasonal precipitation regime during the Little Ice Age (c. AD 1450 to 1850). In gorge sections where the present rate of sediment supply from hillslope colluvium is very low, the channel has incised into older alluvial and colluvial deposits. Conversely, in the few sections where sediment supply is currently very high, the channel is aggrading with a braided pattern. Major rock‐fall deposits at certain locations in the gorge have restricted any major downstream sediment transfer. Twelve periods of increased flooding during the last 150 years have been identified and these correlate quite well with negative or declining phases of the North Atlantic Oscillation (NAO). Analysis of daily precipitation data from Crete suggests negative phases of the winter NAO are characterized by an increase in the number of long‐duration, high‐intensity storms. These storms, particularly those with five‐day and greater duration, appear to be significant in triggering major floods in the Aradena Gorge. During the last 40 years the NAO index has been increasing and become locked into a positive phase. As a consequence of this, major flooding appears to have declined during the same period. Copyright © 2002 John Wiley & Sons, Ltd.     

Comparisons between the diets of distant taxa (teleost and cormorant) in an Australian estuary

While most studies of the utilisation of food resources in aquatic ecosystems have focused on comparing the diets of closely related taxa, the present study was aimed at elucidating whether the diets of five species, representing two distant taxa, were correlated and overlapped. We have thus compared the diets of a fish species (the flathead, Platycephalus speculator) with those of two small species of cormorant (little pied, Phalocrocorax melanoleucos, and little black, P. sulcirostris) and two larger species of cormorant (pied, P. varius, and black, P. carbo) in a temperate southwestern Australian estuary. The flathead and the two smaller cormorants consumed predominantly shrimp and small, short-lived teleosts, whereas the two larger cormorants fed almost exclusively on larger species of teleost. Although the diet of flathead were correlated with and overlapped those of the two smaller cormorant species, there was no correlation or overlap between the diets of these three species and those of either of the larger species of cormorant. Our observations of P. speculator are consistent with the results of previous studies which have shown that platycephalids are ambush predators, whereas cormorants are pursuit surface plungers, with the little pied cormorant feeding solitarily and the little black cormorant feeding communally. Flathead preyed on both demersal and mid-water teleosts. The little pied cormorant fed almost exclusively on demersal teleosts and the little black cormorant exploited predominantly mid-water schooling fish. Thus, differences in the fish components of the diets of these three predators can be related to differences in the mode of foraging and the level in the water column in which feeding takes place. The respective daily consumption of shrimp and teleosts in the estuary was estimated as 1,000 kg and 450 kg by flathead and as 180 kg and 150kg by the four species of cormorants combined. The results of this study show that, in estuaries, the degree to which diets were correlated and overlapped amongst predatory vertebrates can be greater between representatives of distant taxa than between species within the same genus.     

Infrared absorption spectra of atmospheric dust over an interior desert basin

Summary Based on the qualitative microspectrophotometric analysis of 287 atmospheric dust samples taken within the surface boundary layer over south central New Mexico, U.S.A. from May 1966 through October 1967, a representative infrared absorption spectrum from 4000 to 250 cm^–1 (2.5 to 40 m) is presented. The strongest absorption band is centered at 1027 cm^–1 (9,7 m), within the 1250 to 770 cm^–1 (8 to 13 m) atmospheric window, and is silicate induced. Two other strong broad absorption bands are the carbonate band at 1425 cm^–1 (7.0 m) and the silicate band at 468 cm^–1 (21.4 m). Temporal variations in the absorption spectra of the dust are observed primarily in the varying relative intensities of the 1027 and 1425 cm^–1 (9.7 and 7.0 m) absorption bands and in the occasional enhancement of the 1027 cm^–1 (9.7 m) band caused by sulfates in the dust. This study indicates that there is a close similarity between the absorption spectra of the atmospheric dust and the spectra of the small particle fraction of area soils, and between the representative dust spectrum and a spectrum of a synthetic mixture (by weight) of 80% silicates, 16% carbonates, and 4% nitrates.     

Stereochemistry of amino acids in surface samples of a marine sediment

In two surface samples of marine sediment, the percentages of d-alanine and d-aspartic acid are significantly higher than the other d-amino acids and are similar to the range found in soils. The percentage of d-glutamic acid is also higher than the other amino acids but less than d-alanine and d-aspartic acid. These d-amino acids may come mainly from bacteria.     

“Fluffy” Type A Ca-, Al-rich inclusions in the Allende meteorite

Allende “fluffy” Type A's (FTA's) are a distinct sub-group of Ca-, Al-rich inclusions whose primary mineral assemblage consists of Al-rich melilite (Åk 0–33), spinel that is commonly very V-rich, perovskite and, frequently, hibonite. Some contain relatively coarse-grained melilite (up to 1.5 mm) that is intensely kink-banded and commonly reversely-zoned, hibonite and V-rich spinel. Others contain much finer-grained and strain-free melilite (?50 μm) and have not been found to contain hibonite or V-rich spinel. Some FTA's contain both coarser- and finer-grained melilite and textural relationships indicate that the latter is replacing the former. FTA's are characterized by extremely irregular shapes and 60–75 volume per cent of fine-grained, secondary alteration products. Many are aggregates of innumerable nodules, each of which is surrounded by a Wark-Lovering-type rim sequence. These nodules are frequently separated from one another by matrix-like clastic rim material. Other FTA's do not have nodular structure. Structural and mineralogical characteristics of their Wark-Lovering rims suggest that FTA's did not achieve their shapes by deformation of a liquid or a hot, plastic solid. In contrast to those in Type B inclusions, formation of reverse zoning in the coarser-grained melilite crystals in FTA's cannot be understood in terms of crystallization from a liquid but are readily explainable by condensation from a solar nebular gas during a period of falling pressure. Further evidence against a liquid origin is the wide range of spinel compositions within individual coarser-grained FTA's. The fact that the reversely-zoned melilite crystals cannot have been produced in any kind of sublimation or distillation process precludes formation of these inclusions as volatilization residues. FTA's are aggregates in some of which are preserved vapor-solid condensate grains that formed at high temperature in the solar nebula.     

X-ray K-edge absorption spectra of Fe minerals and model compounds: II. EXAFS

K-edge extended X-ray absorption fine structure (EXAFS) spectra of Fe in varying environments in a suite of well-characterized silicate and oxide minerals were collected using synchrotron radiation and analyzed using single scattering approximation theory to yield nearest neighbor Fe-O distances and coordination numbers. The partial inverse character of synthetic hercynite spinal was verified in this way. Comparison of the results from all samples with structural data from X-ray diffraction crystal structure refinements indicates that EXAFS-derived first neighbor distances are generally accurate to ±0.02 Å using only theoretically generated phase information, and may be improved over this if similar model compounds are used to determine EXAFS phase functions. Coordination numbers are accurate to ±20 percent and can be similarly improved using model compound EXAFS amplitude information. However, in particular cases the EXAFS-derived distances may be shortened, and the coordination number reduced, by the effects of static and thermal disorder or by partial overlap of the longer Fe-O first neighbor distances with second neighbor distances in the EXAFS structure function. In the former case the total information available in the EXAFS is limited by the disorder, while in the latter case more accurate results can in principle be obtained by multiple neighbor EXAFS analysis. The EXAFS and XANES spectra of Fe in Nain, Labrador osumulite and Lakeview, Oregon plagioclase are also analyzed as an example of the application of X-ray absorption spectroscopy to metal ion site occupation determination in minerals.     

Characterization of the shallow groundwater system in an area with thin soils and sinkholes

Door County, Wisconsin, is a region of karst topography underlain by Silurian dolomite bedrock. Numerous sinkholes intercept much of the surface runoff and act as sites for direct groundwater recharge. The clay-rich and impermeable Upper Ordovician Maquoketa formation separates the dolomite aquifer from the deeper aquifers and appears to be a factor in groundwater circulation and karst formation Thin glacial drift and Quaternary materials overlie the dolomite and are hydrologically connected with it The interactions of surface and groundwater, and the role of solution features in water interchange were studied in a small drainage basin. This basin contains several large sinkholes and a nearby spring complex Mapping identified many additional sinks and swallets in surface drainage routes Water flowing into two sinks was traced and found to have a residence time of several hours. Water flowing into sinkholes and from the spring was sampled to identify the quality and seasonal trends in composition of the shallow groundwater Water quality parameters monitored include magnesium, sodium, potassium, chloride, phosphorous, nitrate and ammonia, nitrogen, alkalinity, pH, turbidity, and specific conductance. Nitrate levels were found to increase 5 to 6 times during periods when there was zero input through sinkhole recharge sites. Nitrate levels approached the 10 mg/l NO₃ ⁻-N limit set by the U.S. Public Health Service for drinking water In this basin sandy soils are most susceptible to sink development, whereas clay-rich soils have a lesser number of sinks. It appears, however, that a network of bedrock solution features exists under all soils The loss of soil into sinkholes has impacted groundwater quality and reduced agricultural productivity through a reduction in tillable acreage and water retention capacity.     

Ionospheric reflection coefficients at vlf from sferics measurements

Summary A method for calculating the complex ionospheric reflection coefficients at vlf using sferic waveforms is presented. The mathematical analysis was carried out for a number of different waveforms to illustrate the method. Reflection coefficients determined from sferics observations were compared with those calculated using an ionospheric model. In most cases, the agreement with theory is fairly good although in some cases, reflection coefficients exceeding unity were obtained. The discrepancies are believed to result from horizontally polarized flashes rather than limitations in the ionospheric model.