The abundance profile of CO in Neptune's atmosphere

The J = 3-2 rotational line of CO in Neptune has been measured using the heterodyne receiver B3 at the JCMT. The spectral resolution was 1.25 MHz and 25 tunings were used to cover a frequency range of almost 20 GHz. The measured line shape, encompassing both the broad absorption feature arising in the lower atmosphere and a narrow emission core from the upper stratosphere, indicates that the CO mole ratio is not uniform with altitude, with best-fit values of in the upper stratosphere and 0.6±0.4×¹⁰⁻⁶ in the lower stratosphere and troposphere. The higher stratospheric abundance indicates that a dual, internal and external, origin of CO is most likely.     

Auriacusite, Fe3+Cu2+AsO4O, the first M 3+ member of the olivenite group, from the Black Pine mine, Montana, USA

Auriacusite, ideally Fe³⁺Cu²⁺AsO₄O, is a new arsenate mineral (IMA2009–037) and the Fe³⁺ analogue of olivenite, from the Black Pine mine, 14.5 km NW of Philipsburg, Granite Co., Montana, USA. It occurs lining quartz vughs and coating quartz crystals and is associated with segnitite, brochantite, malachite, tetrahedrite and pyrite. Auriacusite forms fibrous crystals up to about 5?µm in width and up to about 100?µm in length, which are intergrown to form fibrous mats. Individual crystals are a brownish golden yellow, whilst the fibrous mats are ochreous yellow. The crystals have a silky lustre and a brownish yellow streak. Mohs hardness is about 3 (estimated). The fracture is irregular and the tenacity is brittle. Auriacusite crystals are biaxial (+), with α?=?1.830(5), β?=?1.865(5) and γ?=?1.910(5), measured using white light, and with 2V _meas.?=?83(3)º and 2V _calc. = 84.6º. Orientation: X?=?a, Y?=?c, Z?=?b. Crystals are nonpleochroic or too weakly so to be observed. The empirical formula (based on 5 O atoms) is (Fe _1.33 ³⁺ Cu_0.85Zn_0.03)_Σ2.21(As_0.51Sb_0.27Si_0.04?S_0.02Te_0.01)_Σ0.85O₅. Auriacusite is orthorhombic, space group Pnnm, a?=?8.6235(7), b?=?8.2757(7), c?=?5.9501(5) Å, V?=?424.63(6) ų, Z?=?4. The five strongest lines in the powder X-ray diffraction pattern are [d _obs in Å / (I) / hkl]: 4.884 / (100) / 101, 001; 2.991 / (92) / 220; 2.476 / (85) / 311; 2.416 / (83) / 022; 2.669 / (74) / 221. The crystal structure was solved from single-crystal X-ray diffraction data utilising synchrotron radiation and refined to R ₁?=?0.1010 on the basis of 951 unique reflections with F _o?>?4σF. Auriacusite is identified as a member of the olivenite group with Fe³⁺ replacing Zn²⁺ or Cu²⁺ in trigonal bipyramidal coordination. Evidence suggests that auriacusite is an intermediate member between olivenite and an as yet undescribed Fe³⁺Fe³⁺-dominant member. The name is derived from the Latin auri (golden yellow) and acus (needle), in reference to its colour and crystal morphology.     

Assessment of integrity and geochronology of archaeological sites using amino acid racemization in land snail shells: Examples from central Texas

Detailed racemization analyses were carried out on samples of the land snail Rabdotus mooreanus from archaeological sites at Fort Hood, in central Texas. D -alloisoleucine/L -isoleucine (A/I) values were determined for 260 individual shells from 29 proveniences, including sites in alluvium, colluvium, and rockshelters, as well as burned rock middens. A/I values show a good correlation with radiocarbon age, and so provide reasonably precise estimates of ages. Analyses indicate the presence of redeposited material in a large number of proveniences. These result from sedimentary processes involved in burial of the sites as well as from later disturbance (aboriginal or recent) of site stratigraphy. Because amino acid racemization analyses are relatively easy to carry out, this method lends itself to very detailed chronostratigraphic analyses of archaeological sites, thus permitting assessment of site integrity and assisting in the interpretation of site formation processes. © 1996 John Wiley & Sons, Inc.