Spectroscopic standard for tetrahedrally coordinated ferric iron: γ LiAlO2:Fe3+

γ LiAlO₂ doped with Fe³⁺ in the tetrahedral site has been examined by extended X-ray absorption fine structure (EXAFS) analysis, and Mössbauer and optical spectroscopy. The isomer shift (IS) is ?0.026 mm/s (Fe-Pd); the quadrupole splitting (QS) is 0.62 mm/s. Anisotropic optical absorption is prominent at ～391, 452, and 463 nm. The K-edge absorption spectrum shows a prominent absorption near 7,113 ev typical of tetrahedrally coordinated Fe³⁺.     

Some properties of decorrelation techniques in the ambiguity space

The most recent contributions to ambiguity resolution techniques have mainly focused on resolution in the ambiguity domain. Two techniques utilizing a decorrelation approach are compared. These techniques are the least-squares ambiguity decorrelation adjustment method and the lattice basis reduction. The latter is also known as the LLL method. The main focus in this article is on the decorrelation performance of these state-of-the-art techniques, which are aiming at ambiguity space decorrelation through unimodular transformations. The performances of the two-decorrelation techniques are compared through their ability in making the ambiguity space as orthogonal as possible.     

Measuring streambank erosion due to ground water seepage: correlation to bank pore water pressure,precipitation and stream stage

Limited information exists on one of the mechanisms governing sediment input to streams: streambank erosion by ground water seepage. The objective of this research was to demonstrate the importance of streambank composition and stratigraphy in controlling seepage flow and to quantify correlation of seepage flow/erosion with precipitation, stream stage and soil pore water pressure. The streambank site was located in Northern Mississippi in the Goodwin Creek watershed. Soil samples from layers on the streambank face suggested less than an order of magnitude difference in vertical hydraulic conductivity (K_s) with depth, but differences between lateral K_s of a concretion layer and the vertical K_s of the underlying layers contributed to the propensity for lateral flow. Goodwin Creek seeps were not similar to other seeps reported in the literature, in that eroded sediment originated from layers underneath the primary seepage layer. Subsurface flow and sediment load, quantified using 50 cm wide collection pans, were dependent on the type of seep: intermittent low‐flow (LF) seeps (flow rates typically less than 0·05 L min^?1), persistent high‐flow (HF) seeps (average flow rate of 0·39 L min^?1) and buried seeps, which eroded unconsolidated bank material from previous bank failures. The timing of LF seeps correlated to river stage and precipitation. The HF seeps at Goodwin Creek began after rainfall events resulted in the adjacent streambank reaching near saturation (i.e. soil pore water pressures greater than ?5 kPa). Seep discharge from HF seeps reached a maximum of 1·0 L min^?1 and sediment concentrations commonly approached 100 g L^?1. Buried seeps were intermittent but exhibited the most significant erosion rates (738 g min^?1) and sediment concentrations (989 g L^?1). In cases where perched water table conditions exist and persistent HF seeps occur, seepage erosion and bank collapse of streambank sediment may be significant. Copyright © 2007 John Wiley & Sons, Ltd.     

A Bayesian Nonparametric Approach to Unmixing Detrital Geochronologic Data

Mathematical Geosciences - Sedimentary deposits constitute the primary record of changing environmental conditions that have acted on Earth’s surface over geologic time. Clastic material is...     

JHK photometry of Comet Bowell (1982I)

Comet Bowell (1982I) was observed at JHK (1.25, 1.68, 2.25 μm) with the NASA Infrared Telescope Facility on 10 March 1981, 3–5 June 1981, and 22 February 1982. The inner coma was no brighter near perihelion in February 1982 than it was in 1981. Total are × albedo of the grains within 10⁴ km of the nucleus was ～5 × 10¹²cm².     

Influence of rock strength on the valley morphometry of Big Creek, central Idaho, USA

Analysis of valley morphometry and bedrock strength along Big Creek, central Idaho, shows that valley floor width is strongly controlled by bedrock. We performed statistical analysis of Schmidt hammer rock strength as a function of lithology and aspect and of valley morphometry as a function of rock strength. Rock strength is significantly greater on the south side of the valley and in Eocene granodiorites. Rock strength is weakest in Eocene volcanic tuffs. Valley floor width depends negatively on weakest valley-side rock strength, and hillslope gradient on the north side of the valley depends positively on rock strength. Stream gradient does not depend on rock strength. Valley floor width appears to be controlled by bedrock strength on the weaker side of the valley, which was generally the north (south-facing) side. We speculate that a higher degree of weathering via freeze–thaw cycles contributes to lower strength on the north side. The positive dependence of hillslope gradient on rock strength on the north side provides evidence that differential weathering across lithologies determines the gradient that can be maintained as lateral migration of the stream erodes valley walls. These results suggest that in situ rock strength exerts strong influences on some measures of valley morphometry by modulating hillslope mass wasting processes and limiting lateral erosion.     

An approach to hydrograph classification

The stream hydrograph is an integration of spatial and temporal variations in water input, storage and transfer processes within a catchment. For glacier basins in particular, inferences concerning catchment‐scale processes have been developed from the varying form and magnitude of the diurnal hydrograph in the proglacial river. To date, however, such classifications of proglacial diurnal hydrographs have developed in a relatively subjective manner. This paper develops an objective approach to the classification of diurnal discharge hydrograph ‘shape’ and ‘magnitude’ using a combination of principal components analysis and cluster analysis applied to proglacial discharge time‐series and to diurnal bulk flow indices. The procedure is applied to discharge time‐series from two different glacier basins and four separate ablation seasons representing a gradient of increasing hydrological perturbation as a result of (i) variable water inputs generated by rainstorm activity and (ii) variable location and response of hydrological stores through a systematic decrease in catchment glacierized area. The potential of the technique for application in non‐glacial hydrological contexts is discussed. Copyright © 2000 John Wiley & Sons, Ltd.