Upper limits on hydrogen halides in Jupiter from Cassini/CIRS observations

We have determined the following upper limits for the mole fraction of hydrogen halides in Jupiter's atmosphere from Cassini/CIRS observations: [HF]<2.7×10−11, [HCl]<2.3×10−9, [HBr]<1.0×10−9, [HI]<7.6×10−9. These limits are smaller than solar composition for HF and HCl, and support the halogens' condensation in ammonium salts predicted by thermochemical models for the upper jovian troposphere.     

Mg and Si isotopic fractionation patterns in types B1 and B2 CAIs: Implications for formation under different nebular conditions

Magnesium and silicon isotopic profiles across melilite grains in two type B1 and two type B2 calcium‐aluminum‐rich inclusions (CAIs) reveal differing but constant enrichments in heavy isotopes everywhere except ≤1000 μm from the CAI margins. There is no close correlation in the B1s or the B2s between isotopic composition and åkermanite content of the melilite, a measure of progressive igneous crystallization, yet such a correlation might be expected in a type B2: without a melilite mantle (as in B1s) to seal the interior off and prevent further evaporation, the melt would have maintained communication with the external gas. These observations indicate a model in which B1s and B2s solidified under differing conditions. The B2s solidified under lower hydrogen pressures ( ≤ 10^?4 – 10^?5 bars) than did B1s ( > 10^?4 bars), so surface volatilization was slower in the B2s and internal chemical and isotopic equilibrium was maintained over the interval of melilite crystallization. The outermost zones of the CAIs (≤1000 μm from the edge) are not consistently enriched in heavy isotopes relative to the interiors, as might be expected from diffusion‐limited surface evaporation of the melt. In all cases, the magnesium in the CAI margins is lighter than in the interiors. In one case, silicon in the margin also is lighter, but locally in some CAIs, it is isotopically heavier near the surface. If melt evaporation played a role in the formation of these outer zones, a later event in many cases caused isotopic re‐equilibration with an external and isotopically near‐normal reservoir.     

Khatyrka,a new CV3 find from the Koryak Mountains,Eastern Russia

A new meteorite find, named Khatyrka, was recovered from eastern Siberia as a result of a search for naturally occurring quasicrystals. The meteorite occurs as clastic grains within postglacial clay‐rich layers along the banks of a small stream in the Koryak Mountains, Chukotka Autonomous Okrug of far eastern Russia. Some of the grains are clearly chondritic and contain Type IA porphyritic olivine chondrules enclosed in matrices that have the characteristic platy olivine texture, matrix olivine composition, and mineralogy (olivine, pentlandite, nickel‐rich iron‐nickel metal, nepheline, and calcic pyroxene [diopside‐hedenbergite solid solution]) of oxidized‐subgroup CV3 chondrites. A few grains are fine‐grained spinel‐rich calcium‐aluminum‐rich inclusions with mineral oxygen isotopic compositions again typical of such objects in CV3 chondrites. The chondritic and CAI grains contain small fragments of metallic copper‐aluminum‐iron alloys that include the quasicrystalline phase icosahedrite. One grain is an achondritic intergrowth of Cu‐Al metal alloys and forsteritic olivine ± diopsidic pyroxene, both of which have meteoritic (CV3‐like) oxygen isotopic compositions. Finally, some grains consist almost entirely of metallic alloys of aluminum + copper ± iron. The Cu‐Al‐Fe metal alloys and the alloy‐bearing achondrite clast are interpreted to be an accretionary component of what otherwise is a fairly normal CV3 (oxidized) chondrite. This association of CV3 chondritic grains with metallic copper‐aluminum alloys makes Khatyrka a unique meteorite, perhaps best described as a complex CV3 (ox) breccia.     

Fall,classification, and exposure history of the Mifflin L5 chondrite

The Mifflin meteorite fell on the night of April 14, 2010, in southwestern Wisconsin. A bright fireball was observed throughout a wide area of the midwestern United States. The petrography, mineral compositions, and oxygen isotope ratios indicate that the meteorite is a L5 chondrite fragmental breccia with light/dark structure. The meteorite shows a low shock stage of S2, although some shock‐melted veins are present. The U,Th‐He age is 0.7 Ga, and the K‐Ar age is 1.8 Ga, indicating that Mifflin might have been heated at the time of the 470 Ma L‐chondrite parent body breakup and that U, Th‐He, and K‐Ar ages were partially reset. The cosmogenic radionuclide data indicate that Mifflin was exposed to cosmic rays while its radius was 30–65 cm. Assuming this exposure geometry, a cosmic‐ray exposure age of 25 ± 3 Ma is calculated from cosmogenic noble gas concentrations. The low ²²Ne/²¹Ne ratio may, however, indicate a two‐stage exposure with a longer first‐stage exposure at high shielding. Mifflin is unusual in having a low radiogenic gas content combined with a low shock stage and no evidence of late stage annealing; this inconsistency remains unexplained.     

Atlantic Ocean sea-surface temperatures and regional streamflow variability in the Adour-Garonne basin,France

Abstract

The identification of Atlantic Ocean (AO) climatic drivers may prove valuable in long lead-time forecasting of streamflow in the Adour-Garonne basin in southwestern France. Previous studies have identified the Atlantic Multidecadal Oscillation (AMO) and the North Atlantic Oscillation (NAO) as drivers of European hydrology. The current research applied the singular value decomposition (SVD) statistical method to AO sea-surface temperatures (SSTs) to identify the primary AO climatic drivers of the Adour-Garonne basin streamflow. Annual and seasonal streamflow volumes were selected as the hydrological response, while average AO SSTs were calculated for three different 6-month averages (January–June, April–September and July–December) for the year preceding streamflow. The results identified a region along the Equator as the probable driver of the basin streamflow. Additional analysis evaluated the influence of the AMO and NAO on Adour-Garonne basin streamflow.

Editor Z.W. Kundzewicz; Associate editor H. Aksoy

Citation Oubeidillah, A.A., Tootle, G. and Anderson, S.-R., 2012. Atlantic Ocean sea-surface temperatures and regional streamflow variability in the Adour-Garonne basin, France. Hydrological Sciences Journal, 57 (3), 496–506.     

Reference hydrologic networks I. The status and potential future directions of national reference hydrologic networks for detecting trends

Abstract

Identifying climate-driven trends in river flows on a global basis is hampered by a lack of long, quality time series data for rivers with relatively undisturbed regimes. This is a global problem compounded by the lack of support for essential long-term monitoring. Experience demonstrates that, with clear strategic objectives, and the support of sponsoring organizations, reference hydrologic networks can constitute an exceptionally valuable data source to effectively identify, quantify and interpret hydrological change—the speed and magnitude of which is expected to a be a primary driver of water management and flood alleviation strategies through the future—and for additional applications. Reference hydrologic networks have been developed in many countries in the past few decades. These collections of streamflow gauging stations, that are maintained and operated with the intention of observing how the hydrology of watersheds responds to variations in climate, are described. The status of networks under development is summarized. We suggest a plan of actions to make more effective use of this collection of networks.

Editor Z.W. Kundzewicz; Associate editor K. Hamed

Citation Whitfield, P.H., et al., 2012 Burn, D.H. 2012. Reference hydrologic networks, II. Using reference hydrologic networks to assess climate-driven changes in streamflow. Hydrological Sciences Journal, 57(8) (this issue)[Taylor & Francis Online] , [Google Scholar]. Reference hydrologic networks I. The status and potential future directions of national reference hydrologic networks for detecting trends. Hydrological Sciences Journal, 57 (8), 1562–1579.     

Io: Volcanic thermal sources and global heat flow

We have examined thermal emission from 240 active or recently-active volcanic features on Io and quantified the magnitude and distribution of their volcanic heat flow during the Galileo epoch. We use spacecraft data and a geological map of Io to derive an estimate of the maximum possible contribution from small dark areas not detected as thermally active but which nevertheless appear to be sites of recent volcanic activity. We utilize a trend analysis to extrapolate from the smallest detectable volcanic heat sources to these smallest mapped dark areas. Including the additional heat from estimates for “outburst” eruptions and for a multitude of very small (“myriad”) hot spots, we account for ～62 × 10¹² W (～59 ± 7% of Io’s total thermal emission). Loki Patera contributes, on average, 9.6 × 10¹² W (～9.1 ± 1%). All dark paterae contribute 45.3 × 10¹² W (～43 ± 5%). Although dark flow fields cover a much larger area than dark paterae, they contribute only 5.6 × 10¹² W (～5.3 ± 0.6%). Bright paterae contribute ～2.6 × 10¹² W (～2.5 ± 0.3%). Outburst eruption phases and very small hot spots contribute no more than ～4% of Io’s total thermal emission: this is probably a maximum value. About 50% of Io’s volcanic heat flow emanates from only 1.2% of Io’s surface. Of Io’s heat flow, 41 ± 7.0% remains unaccounted for in terms of identified sources. Globally, volcanic heat flow is not uniformly distributed. Power output per unit surface area is slightly biased towards mid-latitudes, although there is a stronger bias toward the northern hemisphere when Loki Patera is included. There is a slight favoring of the northern hemisphere for outbursts where locations were well constrained. Globally, we find peaks in thermal emission at ～315°W and ～105°W (using 30° bins). There is a minimum in thermal emission at around 200°W (almost at the anti-jovian longitude) which is a significant regional difference. These peaks and troughs suggest a shift to the east from predicted global heat flow patterns resulting from tidal heating in an asthenosphere. Global volcanic heat flow is dominated by thermal emission from paterae, especially from Loki Patera (312°W, 12°N). Thermal emission from dark flows maximises between 165°W and 225°W. Finally, it is possible that a multitude of very small hot spots, smaller than the present angular resolution detection limits, and/or cooler, secondary volcanic processes involving sulphurous compounds, may be responsible for at least part of the heat flow that is not associated with known sources. Such activity should be sought out during the next mission to Io.     

Forsterite‐bearing type B refractory inclusions from CV3 chondrites: From aggregates to volatilized melt droplets

Abstract– Detailed petrologic and oxygen isotopic analysis of six forsterite‐bearing Type B calcium‐aluminum‐rich inclusions (FoBs) from CV3 chondrites indicates that they formed by varying degrees of melting of primitive precursor material that resembled amoeboid olivine aggregates. A continuous evolutionary sequence exists between those objects that experienced only slight partial melting or sintering through objects that underwent prolonged melting episodes. In most cases, melting was accompanied by surface evaporative loss of magnesium and silicon. This loss resulted in outer margins that are very different in composition from the cores, so much so that in some cases, the mantles contain mineral assemblages that are petrologically incompatible with those in the cores. The precursor objects for these FoBs had a range of bulk compositions and must therefore have formed under varying conditions if they condensed from a solar composition gas. Five of the six objects show small degrees of mass‐dependent oxygen isotopic fractionation in pyroxene, spinel, and olivine, consistent with the inferred melt evaporation, but there are no consistent differences among the three phases. Forsterite, spinel, and pyroxene are ¹⁶O‐rich with Δ¹⁷O ～ ?24‰ in all FoBs. Melilite and anorthite show a range of Δ¹⁷O from ?17‰ to ?1‰.     

Compound ultrarefractory CAI‐bearing inclusions from CV3 carbonaceous chondrites

Two compound calcium‐aluminum‐rich inclusions (CAIs), 3N from the oxidized CV chondrite Northwest Africa (NWA) 3118 and 33E from the reduced CV chondrite Efremovka, contain ultrarefractory (UR) inclusions. 3N is a forsterite‐bearing type B (FoB) CAI that encloses UR inclusion 3N‐24 composed of Zr,Sc,Y‐rich oxides, Y‐rich perovskite, and Zr,Sc‐rich Al,Ti‐diopside. 33E contains a fluffy type A (FTA) CAI and UR CAI 33E‐1, surrounded by Wark‐Lovering rim layers of spinel, Al‐diopside, and forsterite, and a common forsterite‐rich accretionary rim. 33E‐1 is composed of Zr,Sc,Y‐rich oxides, Y‐rich perovskite, Zr,Sc,Y‐rich pyroxenes (Al,Ti‐diopside, Sc‐rich pyroxene), and gehlenite. 3N‐24’s UR oxides and Zr,Sc‐rich Al,Ti‐diopsides are ¹⁶O‐poor (Δ¹⁷O approximately ?2‰ to ?5‰). Spinel in 3N‐24 and spinel and Al‐diopside in the FoB CAI are ¹⁶O‐rich (Δ¹⁷O approximately ?23 ± 2‰). 33E‐1’s UR oxides and Zr,Sc‐rich Al,Ti‐diopsides are ¹⁶O‐depleted (Δ¹⁷O approximately ?2‰ to ?5‰) vs. Al,Ti‐diopside of the FTA CAI and spinel (Δ¹⁷O approximately ?23 ± 2‰), and Wark‐Lovering rim Al,Ti‐diopside (Δ¹⁷O approximately ?7‰ to ?19‰). We infer that the inclusions experienced multistage formation in nebular regions with different oxygen‐isotope compositions. 3N‐24 and 33E‐1’s precursors formed by evaporation/condensation above 1600 °C. 3N and 33E’s precursors formed by condensation and melting (3N only) at significantly lower temperatures. 3N‐24 and 3N’s precursors aggregated into a compound object and experienced partial melting and thermal annealing. 33E‐1 and 33E avoided melting prior to and after aggregation. They acquired Wark‐Lovering and common forsterite‐rich accretionary rims, probably by condensation, followed by thermal annealing. We suggest 3N‐24 and 33E‐1 originated in a ¹⁶O‐rich gaseous reservoir and subsequently experienced isotope exchange in a ¹⁶O‐poor gaseous reservoir. Mechanism and timing of oxygen‐isotope exchange remain unclear.