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Measurements were made of the degree of trace metal pyritization (DTMP) and ancillary characteristics of four undisturbed sediment cores collected from the subtidal zone of the Nanpaishui Estuary on the Western Bank of the Bohai Sea, a seriously polluted inland sea in northeastern China. The remarkably low concentrations of organic carbon (<0.72%) in these sediments likely constrained sulfate reduction rates, and the low concentrations of acid volatile sulfide (AVS) (<12.5 μmol g−1) limited the sequestration of metals through association with pyrite. The most consistent cause of inter-station differences and depth variations in the degree of pyritization was differences in pyrite metal concentrations rather than reactive metal concentrations. Reactive metal concentrations were in several cases negatively correlated with pore water concentrations, consistent with a dissolution/precipitation mechanism. The relationship between pore water metal concentrations and DTMPs was evidenced by a qualitative similarity of the inter-station variability of these same parameters. 相似文献
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Chunyan Li Nan Walker Aixin Hou Ioannis Georgiou Harry Roberts Ed Laws J. Alex McCorquodale Eddie Weeks Xiaofeng Li Jessica Crochet 《Estuarine, Coastal and Shelf Science》2008
Circular shaped density plumes of low turbidity, low fecal indicator (Escherichia coli and enterococci) concentrations, and high salinity have been observed near the Industrial Canal in Lake Pontchartrain, north of the City of New Orleans. A conceptual model in polar coordinates and a numerical model are developed, together with data analysis, to illustrate the dense plume. It is demonstrated that the northward expansion of the plume occurs under northerly winds. The northward expansion of the plume occurs under northerly winds that drive downwind flow at the surface and upwind radial flow at the bottom. Northerly wind-induced straining, similar to tidal straining, promotes vertical stratification. As a result, the water becomes stratified near a thin bottom layer (<1 m), within which density currents are facilitated. The stability of the stratified plume suppresses wind-induced turbulent mixing inside the plume. The bottom water outside of the plume is more effectively stirred by the wind, the result being that the suspended sediment concentration outside of the plume area is much higher than inside. This contrast in mixing makes the plume visible from the surface by satellites even though the stratification is at the bottom. Laterally, wind stress produces a torque (vorticity) in areas of non-uniform depth such that upwind flow is developed in deep water and downwind flow in shallow water. The continuity requirement produces an upwind flow along the axis of the Industrial Canal (IC). The upwind flow is balanced by the downwind flow over the shallower peripheral areas along the coast. 相似文献
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R.M. Laws D. Halliday J.-F. Hopperstad D. Gerez M. Supawala A. Özbek T. Murray E. Kragh 《Geophysical Prospecting》2019,67(6):1443-1471
Marine seismic vibrators are generally considered to be less intrusive than airguns from an environmental perspective. This is because they emit their energy spread out in time, rather than in a single, high-intensity pulse. There are also significant geophysical benefits associated with marine vibrators, and they stem from the ability to specify in detail the output acoustic waveform. The phase can be specified independently at each frequency. Such detailed control cannot be achieved with conventional airgun sources, where the phase can only be modified using simple overall time delays. The vibrator phase can be employed in several different ways: it can be applied to the overall source phase in a sequence so that it varies from one source point to the next; it can be applied to the individual vibrators within the source array so the source directivity is changed; it can be applied to the overall source phase of each source in a simultaneous source acquisition. Carefully designed phase sequences can attenuate the residual source noise, and this in turn allows extra source points to be interleaved between the conventional ones. For these extra source points, the relative phase of the vibrators within the array can be chosen to create a transverse gradient source, which illuminates the earth predominantly in directions out of the plane of the sail line without left/right ambiguity. If seismic vibrator data are acquired using interleaved conventional and transverse gradient sweeps, more information is collected per kilometre of vessel travel than is the case in conventional acquisition. This richer data acquisition leads to the possibility of acquiring all the necessary seismic data in a shorter time. Three-dimensional reconstruction techniques are used to recover the same image quality that would have been obtained using the conventional, more time-consuming acquisition. For a marine vibrator to be suitable for these techniques it must, in general terms, have ‘high fidelity’. The precise device specifications are defined through realistic end-to-end simulations of the physical systems and the processing. The specifications are somewhat more onerous than for a conventional vibrator, but they are achievable. A prototype vibrator that satisfies these requirements has been built. In a simulated case study of a three-dimensional deep-water ocean bottom node survey, the seismic data could have been acquired using marine vibrators in one third of the time that it would have taken using airguns. 相似文献
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Bidigare RR Fluegge A Freeman KH Hanson KL Hayes JM Hollander D Jasper JP King LL Laws EA Milder J Millero FJ Pancost R Popp BN Steinberg PA Wakeham SG 《Global biogeochemical cycles》1997,11(2):279-292
The carbon isotopic fractionation accompanying formation of biomass by alkenone-producing algae in natural marine environments varies systematically with the concentration of dissolved phosphate. Specifically, if the fractionation is expressed by epsilon p approximately delta e - delta p, where delta e and delta p are the delta 13C values for dissolved CO2 and for algal biomass (determined by isotopic analysis of C37 alkadienones), respectively, and if Ce is the concentration of dissolved CO2, micromole kg-1, then b = 38 + 160*[PO4], where [PO4] is the concentration of dissolved phosphate, microM, and b = (25 - epsilon p)Ce. The correlation found between b and [PO4] is due to effects linking nutrient levels to growth rates and cellular carbon budgets for alkenone-containing algae, most likely by trace-metal limitations on algal growth. The relationship reported here is characteristic of 39 samples (r2 = 0.95) from the Santa Monica Basin (six different times during the annual cycle), the equatorial Pacific (boreal spring and fall cruises as well as during an iron-enrichment experiment), and the Peru upwelling zone. Points representative of samples from the Sargasso Sea ([PO4] < or = 0.1 microM) fall above the b = f[PO4] line. Analysis of correlations expected between mu (growth rate), epsilon p, and Ce shows that, for our entire data set, most variations in epsilon p result from variations in mu rather than Ce. Accordingly, before concentrations of dissolved CO2 can be estimated from isotopic fractionations, some means of accounting for variations in growth rate must be found, perhaps by drawing on relationships between [PO4] and Cd/Ca ratios in shells of planktonic foraminifera. 相似文献
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Primary production rates, chlorophyll a and nutrient concentrations, particulate carbon, nitrogen and phosphorus concentrations, Secchi depths and submarine light levels were measured at stations within, and near, the zone of mixing of the Sand Island and Mokapu Point ocean sewage outfalls near the island of Oahu in the Hawaiian Islands. Multiyear averages of several parameters indicated that the Sand Island outfall had no adverse impact on phytoplankton communities or water quality. The major effect of the Mokapu Point outfall was a reduction in photosynthetic rates, probably due to the rapid uptake of nutrients introduced into the mixed layer with the secondarily treated sewage. The Sand Island outfall, which discharged coarsely screened raw sewage within the thermocline, had less of an impact because the inorganic nutrient concentrations in the sewage were lower and because the sewage rarely rose into the mixed layer. The results indicate that, under appropriate conditions, ocean outfalls may be preferable to estuarine or freshwater outfalls and that secondary treatment is not always necessary to reduce the impacts of ocean outfalls to an acceptable level. 相似文献
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The rough sea surface causes perturbations in the seismic data that can be significant for time‐lapse studies. The perturbations arise because the reflection response of the non‐flat sea perturbs the seismic wavelet. In order to remove these perturbations from the received seismic data, special deconvolution methods can be used, but these methods require, as input, the time varying wave elevation above each hydrophone in the streamer. In addition, the vertical displacement of the streamer itself must also be known at the position of each hydrophone and at all times. This information is not available in conventional seismic acquisition. However, it can be obtained from the hydrophone measurements provided that the hydrophones are recorded individually (not grouped), that the recording bandwidth is extended down to 0.05 Hz and that data are recorded without gaps between the shot records. The sea surface elevation, and also the wave‐induced vertical displacement of the streamer, can be determined from the time‐varying pressure that the sea waves cause in the hydrophone measurements. When this was done experimentally, using a single sensor seismic streamer without a conventional low cut filter, the wave induced pressure variations were easily detected. The inversion of these experimental data gives results for the sea surface elevation that are consistent with the weather and sea state at the time of acquisition. A high tension approximation allows a simplified solution of the equations that does not demand a knowledge of the streamer tension. However, best results at the tail end of the streamer are obtained using the general equation. 相似文献
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