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171.
Since 1980 when F. Lippmann's seminal paper appeared, ourunderstanding of solubility equilibria involving ionic solidsolutions has been advanced by theoretical considerations as wellas careful experimental studies designed to determine excess Gibbsfunctions. A unified theory of solid-solution aqueous-solutionequilibria as well as the thermodynamic background of thephenomenon of ``stoichiometric saturation' are reviewed.It is shown that Lippmann diagrams effectively summarize thethermodynamic basis of solid-solute aqueous-solution equilibria ofsparingly soluble metal carbonate systems. Clearly, the predictivepower of these diagrams may be limited due to kineticrestrictions. Only when dissolution and precipitation areessentially reversible, favourable conditions to synthesizehomogeneous solid phases can be derived from studies of equilibria. 相似文献
172.
Nickel partitioning between forsterite and aluminosilicate melt of fixed bulk composition has been determined at 1300°C to 20 kbar pressure. The value of the forsterite-liquid nickel partition coefficient is lowered from >20 at pressures equal to or less than 15 kbar to <10 at pressures above 15 kbar.Published data indicate that melts on the join Na2O-Al2O3-SiO2 become depolymerized in the pressure range 10–20 kbar as a result of Al shifting from four-coordination at low pressure to higher coordination as the pressure is increased. This coordination shift results in a decreasing number of bridging oxygens in the melt. It is suggested that the activity coefficient of nickel decreases with this decrease in the number of bridging oxygens. As a result, the nickel partition coefficient for olivine and liquid is lowered.Magma genesis in the upper mantle occurs in the pressure range where the suggested change in aluminum coordination occurs in silicate melts. It is suggested, therefore, that data on nickel partitioning obtained at low pressure are not applicable to calculation of the nickel distribution between crystals and melts during partial melting in the upper mantle. Application of high-pressure experimental data determined here for Al-rich melts to the partial melting process indicates that the melts would contain about twice as much nickel as indicated by the data for the low-pressure experiments. If, as suggested here, the polymerization with pressure is related to the Al content of the melt, the difference in the crystal-liquid partition coefficient for nickel at low and high pressure is reduced with decreasing Al content of the melt. Consequently, the change ofDNiol-andesite melt is greater than that ofDNiol-basalt melt, for example. 相似文献
173.
Ohne Zusammenfassung 相似文献
174.
Ocean Dynamics - Meeresoptische Messungen auf der Forschungsplattform “Nordsee” haben gezeigt, daß dort während schwerer Stürme, hauptsächlich durch den Einfluß... 相似文献
175.
H. Neunhöfer 《Pure and Applied Geophysics》1969,72(1):76-83
Summary The linear adjustment of the energy-frequency distribution of earthquakes is critically regarded. However, it contains some faults. Therefore, the logarithmic-normal distribution is proposed for adjusting energy-frequency observations of earthquakes. The parameters of the logarithmicnormal distribution are determined from observations by the method of least squares. For many examples from different epicentral areas and different time intervals the parameters of the logarithmicnormal distribution are calculated and compared with one another. It follows that the exact shape of the energy-frequency distribution is fixed by the total energy of all earthquakes occurring per unit of time. There must be the possibility of liberating the seismic energy of 1013 ergs in a given epicentral area of 1000 km2 during one year, so that earthquakes can really occur.Publication No. 49 of the Institut für Geodynamik, 69 Jena (GDR), Burgweg 11. Forschungs-gemeinschaft der Deutschen Akademie der Wissenschaften zu Berlin. 相似文献
176.
177.
The fractionation of the oxygen isotopes between water molecules from different sites in CuSO4 · 5H2O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed. 相似文献
178.
First- and second-order adaptation to natural hazards and extreme events in the context of climate change 总被引:2,自引:1,他引:2
Jörn Birkmann 《Natural Hazards》2011,58(2):811-840
This paper deals with coping and adaptation processes to natural hazards and (potential) climate change impacts. Selected
response measures to natural hazards are critically reviewed with respect to the actual and potential consequences that these
measures might imply for additional adaptation needs and changes within social-ecological systems. In this context, the author
introduces the concept of first- and second-order adaptation processes in order to underline the cascade process that adaptation
implies, the potentials for failure, and the limits of adaptation. Important aspects of first- and second-order adaptation
processes as well as the issue of the limits of adaptation are illustrated based on observations and empirical work conducted
in Vietnam. In its final part, the paper discusses the findings in light of selected theoretical approaches that might help
to understand how stabilization and destabilization processes are influenced or even triggered by adaptation measures. 相似文献
179.
Considering the high population growth rate of Ankara, it is inevitable that landfill(s) will be required in the area in the near future to sustain the sanitary waste disposal needs of the city. The main scope of this study is to select alternative landfill sites for Ankara based on the growing trends of Ankara toward the northwest, particularly toward the Sincan municipality, and to eventually select the best alternative through utilizing multi-criteria decision making. Landfill site selection was carried out utilizing Geographic Information System (GIS) and Multi-Criteria Decision Analysis. A number of criteria, namely, settlement, slope, proximity to roads, geology, availability and proximity of landfill containment material (i.e., clay for composite lining system), suitability for agriculture, erosion, vegetation cover and lineament system were gathered in a GIS environment. Each criterion was assigned a weight value by applying the Pairwise Comparison Method and the Analytical Hierarchy Method. In order to choose the best alternative, the Technique for Order Preference by Similarity to the Ideal Solution, which is regarded as an ideal point method, was applied and a landfill site was selected. The geotechnical properties of the so-called “Ankara clay” that shows widespread distribution in Ankara were reviewed and assessed for its suitability as a compacted clay liner. 相似文献
180.
Rolf Köster 《International Journal of Earth Sciences》1959,46(2):564-571
Zusammenfassung Die wichtigsten glazialen Stauchungsvorgänge wurden experimentell nachgeahmt. Als Versuchsmaterial fanden erwärmte Sand-Paraffin-Gemenge mit eingelegten Schichten von Modellgips Verwendung. Bei Temperaturen über dem Schmelzpunkt des Paraffins besitzen sie ähnlich günstige Eigenschaften wie der meist bevorzugte Tonschlamm, bei Zimmertemperatur sind sie erhärtet und erlauben, im Gegensatz zum Tonschlamm, beliebige Profilschnitte und damit Einblicke in den inneren Bau.Die Experimente ergaben Zusammenhänge zwischen Veränderungen im Versuchsansatz und verschiedenen Störungstypen. Es entstanden:Schuppen bei Stauchung vor dem Modell einer Eiszunge,Falten bei Stauchung unter Belastung,Horizontal eingeschlichtete Streifen bei Bewegung des Modelles unter seiner Sohle.Die Beobachtungen stimmen weitgehend überein mit den Lagerungsstörungen in eisentstandenen Formen entsprechender Bildungsbedingungen. 相似文献