Geochemistry and origin of massif-type anorthosites

Samples of Proterozoic anorthosite complexes from the Adirondack Mountains of New York, Burwash Area of Ontario, and the Nain Complex of Labrador, ranging in composition from anorthosite to anorthositic gabbro, have been analyzed for major elements, Rb, Sr, Ba and nine rare-earth elements (REE), in order to set limits on the compositions and origins of their parent magmas. Similar rock types from the different areas have similar major and trace element compositions. The anorthosites have high Sr/Ba ratios, low REE abundances (Ce about 10, Yb about 0.5–1.5 times chondrites) and large positive Eu anomalies. The associated anorthositic gabbros have lower Sr/Ba ratios, REE abundances nearly an order of magnitude higher than the anorthosites, and small to negligible positive Eu anomalies.Model calculations using the adcumulate rocks with the lowest REE abundances and published distribution coefficients yield parent liquids having REE abundances and patterns similar to those of the associated anorthositic gabbros with the highest REE abundances. Rocks with intermediate REE abundances are the result of incorporation of a liquid component by a plagioclase-rich cumulate similar to the adcumulate samples. The analytical data and model calculations both suggest parent liquids having compositions of 50–54% SiO₂, greater than 20% Al₂O₃, about 1% K₂O, atomic Mg/(Mg+Fe²⁺) ratios (Mg No.'s) of less than 0.4, 15–30 ppm Rb, 400–600 ppm Sr and 400–600 ppm Ba, 40–50 times chondrites for Ce and 8–10 times chondrites for Yb.The low atomic Mg/(Mg+Fe²⁺) values for these rocks combined with geophysical evidence suggesting there are not large quantities of ferromagnesian material at depth, indicate that the anorthositic masses are not products of fractional crystallization of mafic melt derived from melting of the mantle. Rather, it is suggested that they are a result of partial melting of tholeiitic compositions at depths shallower than the basalt-eclogite transformation, leaving a pyroxene-dominated residue.     

Assessing the use of global land cover data for guiding large area population distribution modelling

Gridded population distribution data are finding increasing use in a wide range of fields, including resource allocation, disease burden estimation and climate change impact assessment. Land cover information can be used in combination with detailed settlement extents to redistribute aggregated census counts to improve the accuracy of national-scale gridded population data. In East Africa, such analyses have been done using regional land cover data, thus restricting application of the approach to this region. If gridded population data are to be improved across Africa, an alternative, consistent and comparable source of land cover data is required. Here these analyses were repeated for Kenya using four continent-wide land cover datasets combined with detailed settlement extents and accuracies were assessed against detailed census data. The aim was to identify the large area land cover dataset that, combined with detailed settlement extents, produce the most accurate population distribution data. The effectiveness of the population distribution modelling procedures in the absence of high resolution census data was evaluated, as was the extrapolation ability of population densities between different regions. Results showed that the use of the GlobCover dataset refined with detailed settlement extents provided significantly more accurate gridded population data compared to the use of refined AVHRR-derived, MODIS-derived and GLC2000 land cover datasets. This study supports the hypothesis that land cover information is important for improving population distribution model accuracies, particularly in countries where only coarse resolution census data are available. Obtaining high resolution census data must however remain the priority. With its higher spatial resolution and its more recent data acquisition, the GlobCover dataset was found as the most valuable resource to use in combination with detailed settlement extents for the production of gridded population datasets across large areas.     

Geochemistry of the shawmere anorthosite complex,kapuskasing structural zone,Ontario

The Archean Shawmere Anorthosite Complex, at the southern end of the Kapuskasing Structural Zone, consists dominantly of anorthosite (An_{65 –85}) with minor gabbroic and ultramafic units, which are completely enclosed and cut by tonalites. Both the anorthosites and the tonalites are themselves cut by narrow dikes of gabbroic anorthosite. All of the rocks have undergone high grade metamorphism and are recrystallized so that few igneous textures remain.The anorthosites, gabbros and ultramafic rocks of this complex are cumulates which contain calcic plagioclase (An_65–95) and have atomic Mg/(Mg + Fe²⁺) ratios (Mg#) greater than 0.6; less than 3 ppm Rb; 150–210 ppm Sr; and less than 60 ppm Ba. REE abundanees range from 0.2 to 10 times chondritic and exhibit both light-enriched and light-depleted REE patterns. The lower Mg^# for the samples having more enriched light REE indicates substantial fractions of ferromagnesian minerals crystallized in addition to plagioclase during fractional crystallization, suggesting that the parent magma was basaltic, and not anorthositic. The ranges in Sr, Ba and REE abundances required for the magmas are typical of those for tholeiitic basalts from Archean greenstone belts. Thus the Shawmere Anorthosite Complex may represent cumulates of a crustal-level magma chamber which could have been the immediate source of basic Archean volcanics.One gabbroic anorthositic dike sample has a steeply fractionalted REE pattern with heavy REE abundances less than chondrites and a large positive Eu anomaly. The proposed interpretations is that this rock formed by partial melting of mafic cumulates, perhaps those of the Shawmere Anorthosite Complex itself.     

Non-explosive,constructional evolution of the ice-filled caldera at Volcán Sollipulli,Chile

 A radar and gravity survey of the ice-filled caldera at Volcán Sollipulli, Chile, indicates that the intra-caldera ice has a thickness of up to 650 m in its central part and that the caldera harbours a minimum of 6 km³ of ice. Reconnaissance geological observations show that the volcano has erupted compositions ranging from olivine basalt to dacite and have identified five distinct volcanic units in the caldera walls. Pre- or syn-caldera collapse deposits (the Sharkfin pyroclastic unit) comprise a sequence which evolved from subglacial to subaerial facies. Post-caldera collapse products, which crop out along 17 of the 20 km length of the caldera wall, were erupted almost exclusively along the caldera margins in the presence of a large body of intra-caldera ice. The Alpehué crater, formed by an explosive eruption between 2960 and 2780 a. BP, in the southwest part of the caldera is shown to post date formation of the caldera. Sollipulli lacks voluminous silicic pyroclastic rocks associated with caldera formation and the collapse structure does not appear to be a consequence of a large-magnitude explosive eruption. Instead, lateral magma movement at depth resulting in emptying of the magma chamber may have generated the caldera. The radar and gravity data show that the central part of the caldera floor is flat but, within a few hundred metres of the caldera walls, the floor has a stepped topography with relatively low-density rock bodies beneath the ice in this region. This, coupled with the fact that most of the post-caldera eruptions have taken place along the caldera walls, implies that the caldera has been substantially modified by subglacial marginal eruptions. Sollipulli caldera has evolved from a collapse to a constructional feature with intra-caldera ice playing a major role. The post-caldera eruptions have resulted in an increase in height of the walls and concomitant deepening of the caldera with time. Received: 12 June 1995 / Accepted: 7 December 1995     

Propagator matrices in elastic wave and vibration problems

The boundary value problems most frequently encountered in studies of elastic wave propagation in stratified media can be formulated in terms of a finite number of linear, first order and ordinary differential equations with variable coefficients. Volterra (1887) has shown that solutions to such a system of equations are conveniently represented by the product integral, or propagator, of the matrix of coefficients. In this paper we summarize some of the better known properties of propagators plus numerica methods for their computation. When the dispersion relation is somem ^th order minor of the integral matrix it is possible to deal withm ^th minor propagators so that the dispersion relation is a single element of them ^th minor integral matrix. In this way one of the major sources of loss of numerical accuracy in computing the dispersion relation is avoided. Propagator equations forSH and forP-SV waves are given for both isotropic and transversely isotropic media. In addition, the second minor propagator equations forP-SV waves are given. Matrix polynomial approximations to the propagators, obtained from the method of mean coefficients by the Cayley-Hamilton theorem and the Lagrange-Sylvester, interpolation formula, are derived.     

Environmental assessment from the sedimentary record of high-latitude fiords

The sedimentary record of fiords at high latitude where global change may be occurring earliest and will be greatest has the potential for assessment of environmental change at both low resolution (the scale of millennia) and high resolution (decadal to less than daily). Unlike the lacustrine record which has been used very successfully in these studies, the sedimentary processes and thus the sedimentary deposits of fiords differ (1) in the role of salt water in inhibiting mixing and promoting flocculation, and through the role of sea-ice, (2) in the exchange of mass and energy with the much larger ocean beyond, and (3) in the role of benthic biota in the sedimentary environment. The work reviewed in this paper shows that fiord sediments are being used to assess sedimentary and oceanic processes, as well as glacial, periglacial and geomorphic history, and that they are important proxies for long-term climate and hydrology. Recommendations for advancing this work include long-term monitoring of conditions in fiords and their drainage basins so that the transfer relations can be more solidly constructed from the proxy of fiord sediment. Integration of results from fiords in opposite polar latitudes, and among proxies especially from lacustrine and ice-core records will produce valuable insights. Assessment of the range of conditions in fiords from the most polar to temperate regions is important to building models of their processes and understanding of the paleoenvironmental signals that can be interpreted from each type.     

The application of trace elements to the petrogenesis of igneous rocks of granitic composition

Although trace element modeling has been used to great advantage for petrogenetic interpretations of basaltic systems, similar studies on igneous rocks of granitic composition have been fewer. In general the mineral/melt distribution coefficients for rare earth elements (REE) in granitic melts are equal to or greater than those for similar minerals in the basaltic system. Thus the effects of these minerals on the REE patterns of granitic melts during partial melting or differentiation are exaggerated as compared to basaltic systems, making detection of residual phases easier. For the K/Rb ratio, if neither a K-feldspar component nor biotitephlogopite is present in the residue, it is difficult to reduce the K/Rb ratio of the melt relative to the parent by a factor of two by either differentiation or partial melting.The petrogenesis of four distinctly different rocks are received: (1) an Archean tonalite presumably derived by partial melting of an Archean tholeiite at mantle depths, leaving a garnet plus clinopyroxene residue; (2) an Archean quartz monzonite presumably derived by partial melting of a short-lived graywacke-argillite sequence at crustal depths; (3) a dacite from Saipan presumably derived by differentiation from a basaltic parent; and (4) a trachyte from Ross Island, Antarctica, presumably derived by differentiation from a basanitoid parent and contaminated by continental crustal components.