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101.
The concentration of solvent-extractable (SE) and bound hydrocarbons, ketones, alcohols, sterols, monocarboxylic acids, hydroxyacids and α,ω-dicarboxylic acids of a surface sample (0–2.5 cm) from a recent carbonate tropical sediment taken at 60ft (18m) depth north-west of the Low Isles, North Queensland, are reported in detail. n-Alkanes are a minor constituent in the SE and bound hydrocarbon fractions with the major component being unresolved complex hydrocarbon material which is not an anthropogenic input. 6,10,14-Trimethylpentadecan-2-one derived from chlorophyll, as well as phytol, were identified as major components of the ketone and alcohol constituents. No chlorophyll pigments or pigmented degradation products were present, implying degradation before incorporation into the sediment. This conclusion is consistent with evidence for higher-plant input in which all sensitive lipids have been degraded before incorporation. SE and bound fractions have been studied in detail and show considerable differences probably arising from the importance of viable biomass in the SE fraction. Inputs to the sediment are determined as higher plants, algae, bacteria, fungi and meiofauna in descending order of importance. 相似文献
102.
Arthur D. Cohen William Spackman Philip Dolsen 《International Journal of Coal Geology》1984,4(1):73-96
Cores and surface samples of peats from the Everglades—Mangrove region of Southern Florida were analyzed for total sulfur and pyritic sulfur. These values were compared with the petrographic-botanical components of the peats as determined from point-counts of oriented microtome sections. Pyrite occurs as individual euhedral crystals, loosely packed framboids, and lenses or crusts of minute crystals. Framboids and minute crystals are often associated with organic matter and sometimes with bacteria and fungi. Pyrite tends to selectively occur in void spaces in or between peat tissues. In samples containing very small amounts of pyrite, framboidal pyrite is the prevalent form.Marine to brackish peats contain the highest pyrite and total sulfur contents, with brackish peats generally containing more pyrite than marine peats. Pyrite tends to be lower in all peats within 30 cm of the surface, whether marine or brackish.Burial of freshwater peats beneath marine or brackish peats tends to increase the total sulfur and pyritic sulfur in the underlying peats. Burial beneath brackish-water, clay-rich deposits (such as splays) tends to increase total sulfur and pyritic sulfur in the underlying deposits more than burial beneath less clay-rich deposits. 相似文献
103.
Benjamin D. Santer Karl E. Taylor Tom M. L. Wigley Joyce E. Penner Philip D. Jones Ulrich Cubasch 《Climate Dynamics》1995,12(2):77-100
It has been hypothesized recently that regional-scale cooling caused by anthropogenic sulfate aerosols may be partially obscuring
a warming signal associated with changes in greenhouse gas concentrations. Here we use results from model experiments in which
sulfate and carbon dioxide have been varied individually and in combination in order to test this hypothesis. We use centered
[R (t)] and uncentered [C (t)] pattern similarity statistics to compare observed time-evolving surface temperature change patterns with the model-predicted
equilibrium signal patterns. We show that in most cases, the C (t) statistic reduces to a measure of observed global-mean temperature changes, and is of limited use in attributing observed
climate changes to a specific causal mechanism. We therefore focus on R (t), which is a more useful statistic for discriminating between forcing mechanisms with different pattern signatures but similar
rates of global mean change. Our results indicate that over the last 50 years, the summer (JJA) and fall (SON) observed patterns
of near-surface temperature change show increasing similarity to the model-simulated response to combined sulfate aerosol/CO2 forcing. At least some of this increasing spatial congruence occurs in areas where the real world has cooled. To assess the
significance of the most recent trends in R (t) and C (t), we use data from multi-century control integrations performed with two different coupled atmosphere-ocean models, which
provide information on the statistical behavior of 'unforced' trends in the pattern correlation statistics. For the combined
sulfate aerosol/CO2 experiment, the 50-year R (t) trends for the JJA and SON signals are highly significant. Results are robust in that they do not depend on the choice of
control run used to estimate natural variability noise properties. The R (t) trends for the CO2-only signal are not significant in any season. C (t) trends for signals from both the CO2-only and combined forcing experiments are highly significant in all seasons and for all trend lengths (except for trends
over the last 10 years), indicating large global-mean changes relative to the two natural variability estimates used here.
The caveats regarding the signals and natural variability noise which form the basis of this study are numerous. Nevertheless,
we have provided first evidence that both the largest-scale (global-mean) and smaller-scale (spatial anomalies about the global
mean) components of a combined CO2/anthropogenic sulfate aerosol signal are identifiable in the observed near-surface air temperature data. If the coupled-model
noise estimates used here are realistic, we can be highly confident that the anthropogenic signal that we have identified
is distinctly different from internally generated natural variability noise. The fact that we have been able to detect the
detailed spatial signature in response to combined CO2 and sulfate aerosol forcing, but not in response to CO2 forcing alone, suggests that some of the regional-scale background noise (against which we were trying to detect a CO2-only signal) is in fact part of the signal of a sulfate aerosol effect on climate. The large effect of sulfate aerosols found
in this study demonstrates the importance of their inclusion in experiments designed to simulate past and future climate change.
Received: 10 November 1994 / Accepted: 19 July 1995 相似文献
104.
105.
106.
The existence of detachment surfaces or décollement zones beneath folded rocks of the Valley and Ridge and Plateau provinces of the Appalachians has been recognized as an important condition of folding. Large folds at the border between the two provinces resulted primarily from repetition of strata by thrusting of blocks over ramp faults that connect detachement surfaces at different horizons. Some investigators have suggested that folds in the Plateau province of Pennsylvania were produced by splay faults arising from detachment surfaces, but field observations and theoretical analyses by Sherwin and by Wiltschko & Chapple suggest that the folds are a result of buckling of multilayered rocks above a décollement. An exception may be the Burning Springs anticline in West Virginia, which appears to have formed at the termination of a detachment surface.Investigation of the translation of an homogenous, viscous material above a flat detachment surface that terminates laterally indicates that the termination produces a broad, low-amplitude anticline in passive layering as a result of thickening induced by a gradient of shear stresses in the vertical direction. This thickening above the termination of a detachment is a mechanism of folding. If the viscous fluid contained mechanical layering, the fold would become amplified by buckling. Computations of stresses in the material indicate that minor faults should be generated first near the termination of the flat detachment surface. The Burning Springs anticline probably was initiated by termination of a detachment surface and subsequently amplified by buckling. 相似文献
107.
Mo and W have been determined in five CRPG and eight ANRT geochemical reference samples by spectrophotometric - zinc dithiol procedures. Although data are lacking for adequate comparisons on most samples, our data for tungsten in GIT-IWG MA-N and GIT-IWG BE-N are very near the presently proposed values. 相似文献
108.
109.
I. Camilo Higuera-Díaz Philip J. Carpenter Michael D. Thompson 《Environmental Geology》2007,53(4):805-812
Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features
such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at
the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic
refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction
tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated
sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression,
at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests
the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the
western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low,
the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to
the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool
for identification of filled sinkholes and bedrock depressions in karst areas. 相似文献
110.
Differential diatom dissolution in Late Quaternary sediments from Lake Manyara,Tanzania: an experimental approach 总被引:3,自引:0,他引:3
Philip Barker 《Journal of Paleolimnology》1992,7(3):235-251
Diatom dissolution in saline lakes represents an important obstacle to the quantitative reconstruction of water chemistry and climate from lake sediment archives. This problem is here approached experimentally by artificially dissolving diatom-bearing core sediment from Lake Manyara, Tanzania. Manyara holds one of the longest continuous palaeolimnological records from tropical Africa although its interpretation is based on a fragmentary diatom record due to frustule dissolution. These experiments have revealed clear changes in assemblage composition as dissolution operated differentially with respect to diatom taxa. Differential dissolution has considerable impact on the water chemistry estimates derived from transfer functions. Taphonomy, rather than environmental change, may have been responsible for minor fluctuations in the diatom assemblages from Manyara, although major palaeohydrological changes during the Late Pleistocene and Early Holocene can be identified. Particularly well represented by MANE-87 is a period of intermediate lake level between 27 500 and 23 000 14C yr BP which has regional palaeohydrological significance. 相似文献