A study of lunar impact crater size-distributions

Discrepancies in published crater frequency data prompted this study of lunar crater distributions. Effects modifying production size distributions of impact craters such as surface lava flows, blanketing by ejecta, superposition, infilling, and abrasion of craters, mass wasting, and the contribution of secondary and volcanic craters are discussed. The resulting criteria have been applied in the determination of the size distributions of unmodified impact crater populations in selected lunar regions of different ages. The measured cumulative crater frequencies are used to obtain a general calibration size distribution curve by a normalization procedure. It is found that the lunar impact crater size distribution is largely constant in the size range 0.3 km ?D ? 20 km for regions with formation ages between ≈ 3 × 10⁹ yr and ? 4 × 10⁹ yr. A polynomial of 4th degree, valid in the size range 0.8 km ?D ? 20 km, and a polynomial of 7th degree, valid in the size range 0.3 km ?D ? ? 20 km, have been approximated to the logarithm of the cumulative crater frequencyN as a function of the logarithm of crater diameterD. The resulting relationship can be expressed asN ～D ^α(D) where α is a function depending onD. This relationship allows the comparison of crater frequencies in different size ranges. Exponential relationships with constant α, commonly used in the literature, are shown to inadequately approximate the lunar impact crater size distribution. Deviations of measured size distributions from the calibration distribution are strongly suggestive of the existence of processes having modified the primary impact crater population.     

High-temperature carbon reduction of silica: A novel approach for oxygen isotope analysis of biogenic opal

A new technique has been developed for the determination of the oxygen isotope composition from biogenic silica. The iHTR method (inductive high temperature carbon reduction) is based on the reduction of silica by carbon with temperatures of up to 1830°C (maximum T 2200°C) to produce carbon monoxide for isotope analysis. Basically, samples of silica are mixed with graphite and filled into a sample holder made of a glassy carbon rod. The rod is introduced into a glassy carbon cylinder liner closed at the top which itself is enclosed by a double-walled glass vessel. The glassy carbon rod is inductively heated under vacuum to the temperature needed for quantitative conversion of the particular silica material to CO. The most critical process of dehydration (in the case of opal) and reduction to CO is routinely achieved in the iHTR device. Weakly bound oxygen and oxygen-containing contaminants, like hydroxyl groups, as well as remaining minor organic constituents are volatilized stepwise under high vacuum at temperatures of 850°C and 1050°C without isotopic exchange before the reduction of the silica. After completion of dehydration, the temperature is raised to the value needed for silica reduction. For both biogenic silica and quartz a temperature of 1550°C was found to be adequate. The technical design with a standard preparation routine and various test experiments is presented proving the reliability and capability of the new iHTR method, especially with respect to fresh diatom materials and diatom opal. The amount of sample material necessary at present is ∼1.5 mg of silica and the reproducibility achieved for natural samples is better than ±0.15‰. Replicate analysis of the quartz standard NBS28 resulted in a δ¹⁸O value of 9.62‰ ± 0.11‰ (n = 17).     

Distribution of clay minerals in surface sediments of the Aegean Sea: a compilation

Extensive published data sets and some new data on the clay mineral composition of surface sediments in the Aegean Sea, northeastern Mediterranean Sea, have been compiled in order to map the distribution patterns of clay mineral assemblages and to decipher source areas and transport paths. We distinguished six provinces, a Northwest Aegean Province, a Marmara-Dardanelles Province, a West Turkey Province, a Southeast Aegean Province, a Kithira Province and a Central Aegean Province. The clay mineral assemblages in the coastal and shelf areas carry the signature of the riverine sediment discharge from southeast Europe and Turkey, respectively. The southern Aegean Sea is probably influenced by the River Nile discharge and transport of clay minerals by surface currents. The clay minerals in the central Aegean Sea form a mixed assemblage comprising components of the other assemblages. A dispersion and dilution of clay minerals by surface currents is obvious.     

Petrochemical evidence on the probable origin of ferriferous metasediments in western Bushmanland

The mineralized Proterozoic metasediments of Bushmanland are characterized by the presence of ferriferous rocks. This includes banded and unbanded iron formations and various types of gossans. These units are not laterally extensive and occur in different stratigraphic levels. The prevalent minerals in the ferriferous rocks are hematite, magnetite, quartz, garnet, muscovite, biotite and sillimanite, but less common occurrences of graphite, alunite, plumbojarosite, gahnite and dufrenite have been noted. The chemical variation (wt%) is extensive: total Fe₂O₃ (1.3–93.5), SiO₂ (4–93), Al₂O₃ (0.2–14.0), CaO (0.02–20.7), MnO (0.0–14.3), MgO (0.0–5.7), TiO₂ (0.0–4.4), Na₂O (0.0–2.0), K₂O (0.0–1.5) and P₂O₅ (0.1–7.0). The preliminary nature of the data set precludes, however, firm conclusions regarding stratigraphic control of the chemical composition. The trace-element contents (ppm) extend over several orders of magnitude: Zn (0–7,000), Ba (0–5,200), Cu (0–1,400), Pb (0–1,070) and Ni (6–540). Collectively, the data indicate that most of the ferriferous rocks represent highly metamorphosed sediments.