Long-term Field Observations on Seasonality in Chlorophyll-<Emphasis Type="Italic">a</Emphasis> Concentrations in a Shallow Coastal Marine Ecosystem,the Wadden Sea

Analyses of long-term field observations (1974–2007) on chlorophyll-a concentrations in the western Wadden Sea showed no long-term trends in the timing of the wax and wane of phytoplankton spring blooms. There is weak evidence, however, that the height of the autumn bloom has decreased since the early 1990s. This fading of the autumn bloom may have had consequences for the carbon transfer to higher trophic levels, currently hampering primary consumer species that mostly rely on food supply during late summer. Current and other findings suggest a shortening of the growing season due to the fading of the autumn bloom in the Wadden Sea and a lengthening of the growing season due to an advancement of the spring bloom in the North Sea. These regionally different changes in seasonality may have contributed to the coinciding decrease in bivalve filtering capacity in the western Wadden Sea and the large-scale offshore shift of juvenile plaice from the Wadden Sea to the adjacent North Sea.     

A pore-throat model based on grain-size distribution to quantify gravity-dominated DNAPL instabilities in a water-saturated homogeneous porous medium

A pore-scale network model based on spherical pore bodies and cylindrical pore throats was developed to describe the displacement of water by DNAPL. The pore body size and the pore throat size were given by statistical distributions with user-specified values for the minimum, mean and maximum sizes. The numerical model was applied to a laboratory experiment conducted on a sand-filled glass column. The parameters relative to pore body size and pore throat size that were used in the construction of the equivalent network were derived from the discrete grain-size distribution of the real porous medium. The calculated arrival times of the DNAPL front were compared with those measured using optic fibre sensors placed at different points on the control section of the experimental device. Furthermore, the model simulated DNAPL pressure measured at the entrance section of the system. In general, the numerical results obtained with the model were in good agreement with the actual measurements.     

Trace element partitioning between orthopyroxene and anhydrous silicate melt on the lherzolite solidus from 1.1 to 3.2 GPa and 1,230 to 1,535°C in the model system Na<Subscript>2</Subscript>O–CaO–MgO–Al<Subscript>2</Subscript>O<Subscript>3</Subscript>–SiO<Subscript>2</Subscript>

We determined experimentally the Nernst distribution coefficient between orthopyroxene and anhydrous silicate melt for trace elements i in the system Na₂O–CaO–MgO–Al₂O₃–SiO₂ (NCMAS) along the dry model lherzolite solidus from 1.1 GPa/1,230°C up to 3.2 GPa/1,535°C in a piston cylinder apparatus. Major and trace element composition of melt and orthopyroxene were determined with a combination of electron microprobe and ion probe analyses. We provide partitioning data for trace elements Li, Be, B, K, Sc, Ti, V, Cr, Co, Ni, Rb, Sr, Y, Zr, Nb, Cs, Ba, La, Ce, Sm, Nd, Yb, Lu, Hf, Ta, Pb, U, and Th. The melts were chosen to be boninitic at 1.1 and 2.0 GPa, picritic at 2.3 GPa and komatiitic at 2.7 and 3.2 GPa. Orthopyroxene is Tschermakitic with 8 mol% Mg-Tschermaks MgAl[AlSiO₆] at 1.1 GPa while at higher pressure it has 18–20 mol%. The rare earth elements show a continuous, significant increase in compatibility with decreasing ionic radius from D _La^opx−melt ∼ 0.0008 to D _Lu^opx−melt ∼ 0.15. For the high-field-strength elements compatibility increases from D _Th^opx−melt ∼ 0.001 through D _Nb^opx−melt ∼ 0.0015, D _U^opx−melt ∼ 0.002, D _Ta^opx−melt ∼ 0.005, D _Zr^opx−melt ∼ 0.02 and D _Hf^opx−melt ∼ 0.04 to D _Ti^opx−melt ∼ 0.14. From mathematical and graphical fits we determined best-fit values for D ₀^M1, D ₀^M2, r ₀^M1, r ₀^M2, E ₀^M1, and E ₀^M2 for the two different M sites in orthopyroxene according to the lattice strain model and calculated the intracrystalline distribution between M1 and M2. Our data indicate extreme intracrystalline fractionation for most elements in orthopyroxene; for the divalent cations D _i ^M2−M1 varies by three orders of magnitude between D _Co^M2−M1 = 0.00098–0.00919 and D _Ba^M2−M1 = 2.3–28. Trivalent cations Al and Cr almost exclusively substitute on M1 while the other trivalent cations substitute on M2; D _La^M2−M1 reaches extreme values between 6.5 × 10⁷ and 1.4 × 10¹⁶. Tetravalent cations Ti, Hf, and Zr almost exclusively substitute on M1 while U and Th exclusively substitute on M2. Our new comprehensive data set can be used for polybaric-polythermal melting models along the Earth’s mantle solidus. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Are fossil groups a challenge of the cold dark matter paradigm?

We study six groups and clusters of galaxies suggested in the literature to be 'fossil' systems (i.e. to have luminous diffuse X-ray emission and a magnitude gap of at least 2 mag R between the first and the second ranked member within half of the virial radius), each having good quality X-ray data and Sloan Digital Sky Survey (SDSS) spectroscopic or photometric coverage out to the virial radius. The poor cluster AWM 4 is clearly established as a fossil system, and we confirm the fossil nature of four other systems (RX J1331.5+1108, RX J1340.6+4018, RX J1256.0+2556 and RX J1416.4+2315), while the cluster RX J1552.2+2013 is disqualified as fossil system. For all systems, we present the luminosity functions within 0.5 and 1 virial radius that are consistent, within the uncertainties, with the universal luminosity function of clusters. For the five bona fide fossil systems, having a mass range  2 × 10¹³–3 × 10¹⁴ M_⊙  , we compute accurate cumulative substructure distribution functions (CSDFs) and compare them with the CSDFs of observed and simulated groups/clusters available in the literature. We demonstrate that the CSDFs of fossil systems are consistent with those of normal observed clusters and do not lack any substructure with respect to simulated galaxy systems in the cosmological Λ cold dark matter (ΛCDM) framework. In particular, this holds for the archetype fossil group RX J1340.6+4018 as well, contrary to earlier claims.     

High Lake gossan deposit: An Arctic analogue for ancient Martian surficial processes?

Gossan samples collected during a reconnaissance expedition to High Lake in Nunavut, Canada, were analyzed to determine their mineral components and to define parameters for the geochemical environment in which they formed. The gossan represents a natural acid drainage site in an arctic environment that serves as an analogue to the conditions under which sulfate and Fe-oxide possibly formed on Mars. Rock and soil samples were taken from three different outcrops and analyzed using XRD, SEM/EDS and Mössbauer. Two main mineral assemblages were observed. The first assemblage, which was found primarily in samples from the first outcrop, contained chlorite, Fe-phosphates, Fe-oxide and quartz. The second assemblage, which was found at the second and third outcrops, was primarily quartz, mica and jarosite. One sample (G41), containing Fe-oxide, jarosite and gypsum, appears to be transitional between a Fe-oxide dominant assemblage to a jarosite dominant assemblage. Thermodynamic equilibria predicts that the gossan pore water should range from mildly acidic, relatively sulfate-poor (pH 3-6; SO₄ <1000 mg l⁻¹) to highly acidic and relatively sulfate-rich (pH 0.5-3; SO₄ >3000 mg l⁻¹) for the first and second mineral assemblages, respectively. Kinetic reaction models indicate that the second assemblage replaces the first during evaporation or freezing of water. Compared to acid mine drainage (AMD) sites located in temperate regions, the arctic High Lake gossan lacks diversity in sulfate species and has smaller diagenetic crystal sizes. The smaller crystal size may reflect the slower reaction rates at colder temperatures and the seasonal water saturation. These initial results indicate that the High Lake gossan deposit does record mechanisms for which minerals like hematite, goethite, gypsum and jarosite, which are found on Mars, can form in an environment that involves seasonal water occurrence in a cold climate.     

Results from regional vibroseis profiling: Appalachian ultra-deep core hole site study

Summary. In 1985, 180 km of regional vibroseis profiles were acquired in the Carolinas and Georgia, southeastern United States, as part of the Appalachian Ultra-Deep Core Hole (ADCOH) Site Study. The data quality is excellent, with large-amplitude reflections from faults and crystalline rocks, lower Palaeozoic shelf strata and from within autochthonous Grenville basement. The profiles image the subsurface more clearly than other available data and allow the possibility of alternative interpretations of important elements of the tectonic framework of the southern Appalachians.
The major points in the interpretation are: 1) The Blue Ridge master decollement is at a depth of 2-3 km beneath the Blue Ridge. This thrust increases in dip just NW of the Brevard fault zone. 2) The Brevard fault zone appears to splay from the master decollement at 6 km (2.2 s) near Westminster, S.C., and defines the base of the crystalline Inner Piedmont allochthon. 3) Below the Blue Ridge thrust sheet are images of duplex and imbricate structures ("duplex tuning wedges") connected by other thrust faults that duplicate shelf strata to a thickness of 4–5 km. 4) Subhorizontal reflections from depths of 6 to 9 km may be from relatively undisturbed lower Palaeozoic strata as suggested by others. 5) Eocambrian-Cambrian(?) rift basins in the Grenville basement are also imaged.
The ADCOH data were originally recorded with 14–56 Hz bandwidth and 8 s length, but an extended Vibroseis correlation was used to produce 17 s data length revealing reflections from within the upper crust. Below 8 s, reflections from within the Grenville basement become weak, but are observable as late as 13 s; however, these Moho (?) reflections are generally short segments.     

Anisotropy of solar hard X-radiation during flares

The angular distribution of solar flare associated hard X-rays ( 10 keV) is calculated on the assumption that they originate as bremsstrahlung emission of energetic electrons with a power law spectrum. For the cross section the relativistic Sauter formula was used. Supposing the electrons to move in a fixed direction, the X-radiation is considerably anisotropic, especially at high photon energies. Taking into account a magnetic field, the anisotropy decreases with increasing pitch angles of the electrons. The anisotropic angular distribution of solar X-radiation seems to be connected with the centre-to-limb variation of hard X-ray bursts and with the correlation of shortwave fadeouts and geomagnetic crochets to H flares.     

Der petrogenetische Werdegang der Klinopyroxene in den tertiären Vulkaniten der Hocheifel I. Die Klinopyroxene der Alkaliolivinbasalt-Trachyt-Assoziation

Zusammenfassung Von über 150 Eraptionspunkten in der Hocheifel werden. 14 Gesteine als Verwtreter der Entwicklungsreihe. Alkaliolivinbasalt-Trachyt nach petrochemischen, optischen und aufbereitungstechnischen Gesichtspunkten ausgewählt und phasen mechanisch in ihre gesteinsbildenden Minerals zerlegt. Neben verschiedenen Klinopyroxenphasen, die sowohl die Klinopyroxeneingprenglinge als each die Grundmasseklinopyroxene enthalten, können fast ells assoziierten Minerals mitgewonnen und chemisch, optisch and röntgenographisch untersucht werden.Im Verlauf der Petrogenese zeigen die Klinopyroxene sine kontinuierliche Entwicklung vonCr- überTi-reiche Augite als Einsprenglinge zuNa-reichen oilerNa-Augiten in der Grundmasse, ohne daß aber Ägirinaugite oiler Ägirine in den sauersten Differentiaten erreicht werden. Neben intratellurischen und subeffusiven bis effusiven Stadien in der Mineralentwicklung, die rich mineralfaziell belegen lassen, tritt reliktisch mitNi-reichem Olivin, Cr-reichem Augit, Bronzit undCr-Spinell eine Mineralparagenese auf, die mit der der ultrabasitischen Xenolithe aus Alkalibasalten identisch ist and sich bis in die Mugearite in verschiedenen Überprägungszuständen nachweisen. läßt. lhr Vorhandensein wird genetisch auf ein initiates Hochdruck-Hochtemperatur- Stadium zurükgeführt, ilea die alkalibasaltische Schmelze am Anfang ibrer Entwicklung durchlanfen hat and dessen mögliche Ursachen mineralfaziell diskutiert werden.