Analysis of solutions to the inverse problem on the retrieval of the microstructure of stratospheric aerosol from satellite measurements

A statistical ensemble of microphysical parameters of the background stratospheric aerosol at altitudes of 15 to 30 km is modeled on the basis of experimental data. The aerosol attenuation coefficients (AACs) in the wavelength range 0.38–16.3 μm are calculated for all realizations of the ensemble by algorithms of the Mie theory. Analysis of correlations between the AACs and the microphysical parameters indicate that the AAC correlates most strongly with the total volume V and area S of all particles. The errors of determining the microphysical parameters from AAC measurements are analyzed via the method of linear regression. It is shown that, if the AAC is measured with an error of 5%, the errors of determining both the particle size distribution (PSD) for particles with sizes of 0.4 to 4 μm and the parameter S are an order of magnitude smaller than the prior uncertainty, whereas the error of determining V is two orders of magnitude smaller than the prior uncertainty. Schemes of AAC measurements with the SAGE III, ISAMS, CLAES, HALOE instruments and an IR interferometer in the visible and IR regions are discussed. It is shown that combining the schemes makes it possible to extend the range of particle sizes for which the PSD is retrieved with a satisfactory accuracy and to increase the accuracy of determining S and V substantially and the accuracy of determining the total number of particles N _opt to a lesser extent. Examples of interpreting AAC measurements carried out simultaneously with the SAGE III and HALOE instruments within the same spatial region are presented. A systematic discrepancy between vertical profiles of S and V obtained from SAGE III and HALOE measurements is revealed.     

Cloning of the major 3-MC inducible phase I and phase II detoxification enzymes of plaice liver

cDNA's coding for cytochrome P4501A1 (CYP1A1), phenol UDP-glucuronosyltransferase (UDPGT) and glutathione S-transferase (GST-A) were cloned and sequenced from an expression library prepared from the liver of a 3-methylcholanthrene (3-MC) induced plaice. Plaice CYP1A1 and Phenol UDPGT display a high degree of structural conservation with homologous mammalian isoforms and their mRNAs were shown to be highly induced in liver after 3-MC treatment of fish. Expression of plaice GST-A, which displays closer homology to GSTs from plants and invertebrates than those of mammals, is repressed after 3-MC treatment.     

Seasonal variations in the speciation of dissolved iodine in the Chesapeake Bay

The speciation of dissolved iodine and the distributions of the iodine species in the deep Chesapeake Bay underwent seasonal variations in response to changes in the prevailing redox condition. In the deep water, the ratios of iodate to iodide and iodate to inorganic iodine decreased progressively from the Winter through the Summer as the deep water became more poorly oxygenated before they rebounded in the Fall when the deep water became re-oxygenated again. The composition of the surface water followed the same trend. However, in this case, the higher biological activities in the Spring and the Summer could also have enhanced the biologically mediated reduction of iodate to iodide by phytoplankton and contributed to the lower ratios found during those seasons. Superimposed on this redox cycle was a cycle of input and removal of dissolved iodine probably as a result of the interactions between the water column and the underlying sediments. Iodine was added to the Bay during the Summer when the deep water was more reducing and removed from the Bay in the Fall when the deep water became re-oxygenated. A third cycle was the inter-conversion between inorganic iodine and ‘dissolved organic iodine’, or ‘‘DOI’’. The conversion of inorganic iodine to ‘DOI’ was more prevalent in the Spring. As a result of these biogeochemical reactions in the Bay, during exchanges between the Bay and the North Atlantic, iodate-rich and ‘DOI’-poor water was imported into the Bay while iodide- and ‘DOI’-rich water was exported to the Atlantic. The export of iodide from these geochemically reactive systems along the land margins contributes to the enrichment of iodide in the surface open oceans.     

Seasonal variation in lysosomal destabilization in oysters,Crassostrea virginica

Lysosomal destabilization assays have been used as valuable biomarkers of pollutant exposures in a variety of bivalve and fish species. The responses of oysters, Crassostrea virginica, deployed at and native to various reference and degraded sites were evaluated for lysosomal destabilization during both summer and winter seasons. In both native and deployed oysters, lysosomal destabilization rates tended to be higher during the winter at both reference and polluted sites. There are at least two hypothetical explanations. Greater lysosomal destabilization rates may be related to physiological changes associated with mobilization of nutrient reserves during the winter and gametogenesis. However, lysosomal destabilization in deployed oysters was correlated with tissue metal concentrations. These data also support a second hypothesis that seasonal differences in physico-chemical factors (such as reduced levels of acid volatile sulfides) may increase the bioavailability of metals during the winter so that adverse effects are more pronounced.     

Distribution of nonlinear wave crests

The distribution of nonlinear wave crests is examined on the basis of a theoretical probability density previously given elsewhere (J. Eng. Mech. 120 (1994) 1009). Certain errors contained in the original theoretical density are corrected, and the corresponding exceedance distribution is derived. The resulting theoretical forms of the probability density and exceedance distribution are then slightly simplified and compared with nonlinear wave data gathered under hurricane conditions. The results indicate that the proposed theoretical forms describe the observed distributions of large wave crests better than the Rayleigh law. However, the quantitative accuracy of the predictions is somewhat poor, as is typical of approximate theories based on Gram–Charlier-type expansions.     

On the calculation of extreme wave heights: A review

Over the past two decades there has been a great deal of interest in calculating design waves for offshore structures. This paper reviews the data limitations, statistical assumptions, distributions, fitting methods, and statistical tests used to determine confidence intervals and goodness of fit. Use is made of an illustrative example from the Grand Banks of Canada to indicate how a design wave could be calculated. It is concluded that no single method will be entirely suitable for all data sets.     

In situ velocity profiles in gassy sediments: Kiel Bay

Acoustic behavior of gas-bearing sediments is significantly different from that of gas-free sediments. In situ velocity profiles and acoustic signal characteristics in gas-bearing sediments of the upper several meters of the sea floor in Kiel Bay are presented in this study. Observed velocities in gas-bearing sediments are both higher and lower than those of the gas-free sediments. Small amounts of gas appear to cause signal reverberation without much attenuation. whereas large amounts of gas cause substantial attenuation.