Glacial isostatic adjustment in Fennoscandia for a laterally heterogeneous earth

Glaciation and deglaciation in Fennoscandia during the last glacial cycles has significantly perturbed the Earth's equilibrium figure. Changes in the Earth's solid and geoidal surfaces due to external and internal mass redistributions are recorded in sequences of ancient coastlines, now either submerged or uplifted, and are still visible in observations of present‐day motions of the surface and glacially induced anomalies in the Earth's gravitational field. These observations become increasingly sophisticated with the availability of GPS measurements and new satellite gravity missions.
Observational evidence of the mass changes is widely used to constrain the radial viscosity structure of the Earth's mantle. However, lateral changes in earth model properties are usually not taken into account, as most global models of glacial isostatic adjustment assume radial symmetry for the earth model. This simplifying assumption contrasts with seismological evidence of significant lateral variations in the Earth's crust and upper mantle throughout the Fennoscandian region.
We compare predictions of glacial isostatic adjustment based on an ice model over the Fennoscandian region for the last glacial cycle for both radially symmetric and fully 3‐D earth models. Our results clearly reveal the importance of lateral variations in lithospheric thickness and asthenospheric viscosity for glacially induced model predictions. Relative sea‐level predictions can differ by up to 10–20 m, uplift rate predictions by 1–3 mm yr⁻¹ and free‐air gravity anomaly predictions by 2–4 mGal when a realistic 3‐D earth structure as proposed by seismic modelling is taken into account.     

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.     

Site occupation and electric field gradient in acentric neptunite-measurements and evaluations concerning powder- and single crystal – Mössbauer spectroscopy and x-ray diffractometry

Mössbauer measurements on neptunite (KNa₂Li(Fe,Mn,Mg)₂Ti₂Si₈O₂₄) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V _zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V _zz which is in satisfactory agreement with V _zz derived from Mössbauer spectroscopy.     

Experimental impact cratering: A summary of the major results of the MEMIN research unit

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.     

Diurnal variation of electron density in Saturn’s ionosphere: Model comparisons with Saturn Electrostatic Discharge (SED) observations

Using the Saturn Thermosphere Ionosphere Model (STIM), we present a study of the diurnal variation of electron density, with a focus on comparisons with peak electron densities (N_MAX) inferred from the low-frequency cutoff of radio emission due to lightning in the lower atmosphere, called Saturn Electrostatic Discharges (SEDs). It is demonstrated that photochemistry in Saturn’s ionosphere cannot reproduce the SED-inferred diurnal variation in N_MAX unless additional production and loss sources outside of the current best estimates are considered. Additional explanations of the SED-inferred diurnal variation of N_MAX are presented and analyzed, such as the possibility that the low-frequency cutoff seen in SEDs is due to the presence of sharp low-altitude layers of plasma, as frequently seen in radio occultation measurements. Finally, we outline the observational constraints that must be fulfilled by any candidate explanations of the SED-inferred diurnal variation of N_MAX.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

Fluid entrapment and reequilibration during subduction and exhumation: A case study from the high-grade Nestos shear zone, Central Rhodope, Greece

A fluid inclusion study on metamorphic minerals of successive growth stages was performed on highly deformed paragneisses from the Nestos Shear Zone at Xanthi (Central Rhodope), in which microdiamonds provide unequivocal evidence for ultrahigh-pressure (UHP) metamorphism. The correlation of fluid inclusion density isochores and fluid inclusion reequilibration textures with geothermobarometric data and the relative chronology of micro- and macro-scale deformation stages allow a better understanding of both the fluid and metamorphic evolution along the P–T–d path. Textural evidence for subduction towards the NE is recorded by the orientation of intragranular NE-oriented fluid inclusion planes and the presence of single, annular fluid inclusion decrepitation textures. These textures occur within quartz “foam” structures enclosed in an earlier generation of garnets with prolate geometries and rarely within recrystallized matrix quartz, and reequilibrated both in composition and density during later stages of exhumation. No fluid inclusions pertaining to the postulated ultrahigh-pressure stage for microdiamond-bearing garnet–kyanite–gneisses have yet been found. The prolate shape of garnets developed during the earliest stages of exhumation that is recorded structurally by (L  S) tectonites, which subsequently accommodated progressive ductile SW shearing and folding up to shallow crustal levels. The majority of matrix kyanite and a later generation of garnet were formed during SW-directed shear under plane-strain conditions. Fluid inclusions entrapped in quartz during this stage of deformation underwent density loss and transformed to almost pure CO₂ inclusions by preferential loss of H₂O. Those inclusions armoured within garnet retained their primary 3-phase H₂O–CO₂ compositions. Reequilibration of fluid inclusions in quartz aggregates is most likely the result of recrystallization along with stress-induced, preferential H₂O leakage along dislocations and planar lattice defects which results in the predominance of CO₂ inclusions with supercritical densities. Carbonic fluid inclusions from adjacent kyanite–corundum-bearing pegmatoids and, the presence of shear-plane-parallel fluid inclusion planes within late quartz boudin structures consisting of pure CO₂-fluid inclusions with negative crystal shapes, bear witness of the latest stage of deformation by NE-directed extensional shear.This study shows that the textures of early fluid inclusions that formed already during the prograde metamorphic path can be preserved and used to derive information about the kinematics of subduction that is difficult to obtain from other sources. The textures of early inclusions, together with later generations of unaltered primary and secondary inclusions in metamorphic index minerals that can be linked to specific deformation stages and even P–T conditions, are a welcome supplement for the reconstruction of a rather detailed P–T–d path.     

The meteorite collection sites of Antarctica

Abstract— Antarctic meteorites have been and are being well studied but the potential for glaciological and climatological information in the sites where they are found is only beginning to be realized. To date, meteorite stranding surfaces have been identified only in East Antarctica: (1) The MacKay Glacier/David Glacier region contains the Allan Hills and the Reckling Moraine/Elephant Moraine stranding surfaces. Because the Allan Hills Main Icefield has a large proportion of meteorites with long terrestrial ages, these concentrations of meteorites must have had catchment areas extending well inland, in contrast to the present. Where known, bedrock topography is mesa-like in form and influences ice flow directions. Ice levels at the Allan Hills may have been higher by 50–100 m in the past. Reckling Moraine and Elephant Moraine are located on a long patch of ice running westward from Reckling Peak; the ice appears to be pouring over a bedrock escarpment. (2) In North Victoria Land, ice diverges around Frontier Mountain and flows into a site behind the barrier where ablation occurs extensively. It is proposed that meteorites and rocks were dumped by ice flow at the mouth of a valley in the lee of the mountain at the site where a meltwater pond existed, in a depression produced by ablation. Later, the pond migrated headward along the valley to a point where it is today, leaving a morainal deposit with the meteorites at a higher level. (3) Between the Beardmore and Law Glaciers, ice flows sluggishly into the southwestern margin of the Walcott Névé. Northeastern sections of the Walcott are virtually barren of meteorites. The entering Plateau ice is diverted northward to flow along the base of Lewis Cliff. This flow apparently terminates in an ice tongue protruding into a vast moraine, where a very large concentration of meteorites was found on the ice. This final segment of flowing ice is called the Lewis Cliff Ice Tongue. Meteorite Moraine, a subsidiary occurrence 2 km to the northeast, is also found against morainal deposits. The origin of the moraines and the history of meteorite concentration at this site is the subject of some debate. (4) The Transantarctic Mountains are submerged along one segment many hundreds of km in length by ice flowing off the Polar Plateau. The Thiel Mountains, Pecora Escarpment and Patuxent Range are the only surface indications of the underlying mountains along this interval, and meteorite stranding surfaces are found at each of these sites. Little is yet known about ice dynamics at these sites. (5) The immense Yamato Mountains meteorite stranding surface covers an area of about 4000 km². So far, most meteorites have been recovered in the upper reaches of this blue ice field, where ice flow is slowed by outlying subice barriers of the Yamato Mountains. Individual massifs in this range extend northward over 50 km, and the Yamato Meteorite Icefield loses 1100 m in elevation over this distance. (6) The Sør Rondane Mountains form a barrier to ice flow off the Polar Plateau. The major meteorite stranding surface associated with this barrier is the Nansenisen Icefield, a large ablation area about 50 km upstream of the mountains. The existence of a meteorite stranding surface at this site has not been explained so far. Most meteorite stranding surfaces have been functioning for a long time. They are sites where net ablation of the surface is occurring; the ice at these sites is stagnant or flowing only slowly, and the numbers of meteorites with great terrestrial ages decrease exponentially. Concentration mechanisms operating at these sites involve ablation, direct infall, time, low temperatures, moderate weathering and wind ablation. Detrimental to concentration are ice flow out of the area and extreme weathering. In spite of the fact that the Antarctic Ice Sheet is thought to be over 10 Ma old, we do not find stranding surfaces with meteorites having greater terrestrial ages than 1 Ma. This suggests that stranding surfaces are transient features, affected on a continental scale by possible extreme warming during late Pliocene and on a smaller scale by regional changes that produce differential effects between icefields. The latter effect is suggested by differences in the average terrestrial age of meteorites at different stranding surfaces. In either case, these sites seem to appear as a result of thinning near the edges of the ice sheet, and stratigraphic sequences may be exposed in the ice at stranding surfaces. We review five models for the production of meteorite stranding surfaces: (1) simple deflation of the ice sheet, in which ablation removes great thicknesses of overlying ice, exposing the contained meteorites while allowing direct falls to accumulate, (2) simple accumulation of direct falls on a bare ice surface that is not deflating, (3) ablation of ice trapped against a barrier, in which meteorites accumulate by direct infall while inflowing ice contributes meteorites by ablation discovery, (4) deceleration of ice by a subice barrier, which allows ablation discovery of meteorites in incoming ice and accumulation of other meteorites on the surface by direct infall and (5) stagnation of ice by encounter with an ice mass able to produce an opposing flow vector, in which ablation discovery and direct infall accumulation processes operate to build the meteorite concentration.     

Verteilung ausgewählter toxischer Spurenelemente im Sediment des Breitlingsees bei Brandenburg

Distribution of Selected Toxic Trace Elements in the Sediment of Lake Breitling near Brandenburg. Considerable enrichments of several heavy metals in relation to the local geological background were found in the surface sediments of Lake Breitling (Havel lake system) (Zn: 50-fold, Cd: 25-fold, Cu: 14-fold, Pb: 13-fold), whereas Be, Co and V are remarkably unchanged if the increased clay mineral content in the more recent sediments is considered. – The heavy metal distribution patterns indicate a high percentage of atmospheric input of these elements, and according to geochemical profiles heavy metal deposition has been constant on a high level for years. – Especially the most enriched Zn which was found to some extent NH₄Ac-exchangeable deserves ecotoxic attention.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.