Perfluorinated alkyl acids in water, sediment and wildlife from Sydney Harbour and surroundings

Perfluorinated alkyl compounds (PFCs) including perfluorooctane sulphonate (PFOS) and perfluorooctanoate (PFOA) were measured in environmental samples collected from around Homebush Bay, an urban/industrial area in the upper reaches of Sydney Harbour and Parramatta River estuary. Water, surface sediment, Sea Mullet (Mugil cephalus), Sydney Rock Oyster (Saccostrea commercialis) and eggs of two bird species; White Ibis (Threskiornis molucca), and Silver Gull (Larus novaehollandiae) were analysed. In most samples PFOS was the dominant PFC. Geometric mean PFOS concentrations were 33 ng/g ww (wet weight) in gull eggs, 34 ng/g ww in ibis eggs, and 1.8 ng/g ww and 66 ng/g ww in Sea Mullet muscle and liver, respectively. In sediment the PFOS geometric mean was 1.5 ng/g, in water average PFOS and PFOA concentrations ranged from 7.5 to 21 ng/L and 4.2 to 6.4 ng/L, respectively. In oysters perfluorododecanoic acid was most abundant, with a geometric mean of 2.5 ng/g ww.     

A suburban sediment budget: Coarse-grained sediment flux through hillslopes,stormwater systems and streams

Sediment in urban stormwater systems creates a significant maintenance burden, while a lack of coarse-grained bed sediment in streams limits their ecological value and geomorphic resilience. Gravel substrates, for example, provide benthic habitat yet are often scoured from the channel bed only to end up in a detention basin or treatment wetland. This dual problem of both ‘too much’ and ‘too little’ coarse-grained sediment reflects a watershed sediment budget that is profoundly altered. We developed a conceptual urban coarse-grained (>0.5 mm) sediment budget across three domains: hillslopes (urban land surfaces), the built stormwater network and stream channels. We then quantified key sources, sinks and storages for a suburban case study, using a combination of hillslope and in-channel monitoring, and interrogation of local government records. Around 36% of the sediment supplied to the stormwater network reached the catchment outlet, a level of sediment delivery much higher than observed in similar-sized natural catchments. The remainder was deposited in the sediment cascade and either stored, or extracted and removed from the catchment (e.g. material deposited in sediment ponds and gross pollutant traps). Conventional urban drainage networks are characterized by high hillslope sediment supply and low storage, resulting in efficient sediment delivery. Channel erosion, deposition in (and extraction from) pipes and channels, and floodplain deposition are small compared to sediment transport through the cascade. An understanding of the sediment budget of urban headwater catchments can provide stormwater and waterway managers with the information they need to address specific sediment problems such as sedimentation in stormwater assets and geomorphic recovery of urban streams. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Regional analysis of bedrock stream long profiles: evaluation of Hack's SL form,and formulation and assessment of an alternative (the DS form)

The equilibrium form of the fluvial long profile has been used to elucidate a wide range of aspects of landscape history including tectonic activity in tectonic collision zones, and in continental margin and other intraplate settings, as well as other base‐level changes such as due to sealevel fluctuations. The Hack SL form of the long profile, which describes a straight line on a log–normal plot of elevation (normal) versus distance (logarithmic), is the equilibrium long profile form that has been most widely used in such studies; slope–area analysis has also been used in recent years. We show that the SL form is a special case of a more general form of the equilibrium long profile (here called the DS form) that can be derived from the power relationship between stream discharge and downstream distance, and the dependence of stream incision on stream power. The DS form provides a better fit than the SL form to river long profiles in an intraplate setting in southeastern Australia experiencing low rates of denudation and mild surface uplift. We conclude that, if an a priori form of the long profile is to be used for investigations of regional landscape history, the DS form is preferable. In particular, the DS form in principle enables equilibrium steepening due to an increase in channel substrate lithological resistance (parallel shift in the DS plot) to be distinguished from disequilibrium steepening due to long profile rejuvenation (disordered outliers on the DS plot). Slope–area analysis and the slope–distance (DS) approach outlined here are complementary approaches, reflecting the close relationship between downstream distance and downstream catchment area. Copyright © 2006 John Wiley & Sons, Ltd.     

Desorption-diffusion model and lost gas quantity estimation of coalbed methane from coal core under drilling fluid medium

The differences of coalbed methane(CBM) desorption-diffusion from coal drilling-core under various drilling fluid medium are not considered in the present calculating methods of lost CBM quantity,which leads possibly to the inaccuracy of CBM quantity in coal seam.Here we took the desorption of CBM from coal core under drilling fluid medium as a pressure-swing process,and based on the Langmuir equation and Fick-first law,established the desorption-diffusion model and numerical modeling method of lost gas(inc...     

A multi-hazard historical catalogue for the city-island-state of Malta (Central Mediterranean)

The city-island-state of Malta is traditionally viewed as a low-hazard country with the lack of a long historical catalogue of extreme events and their impacts acting as an obstacle to formulating evidence-based policies of disaster risk reduction. In this paper, we present the first multi-hazard historical catalogue for Malta which extends from the Miocene to 2019 CE. Drawing on over 3500 documents and points of reference, including historical documentary data, official records and social media posts, we identify at least 1550 hazard events which collectively have caused the loss of at least 662 lives. Recognising that historical materials relating to Malta are complicated by the presence of a strong temporal bias, we establish a four-point reliability indicator and apply this to each of the 1065 recordings, with the result that some 79% show a high degree of reliability. For an island state where there are significant gaps in the knowledge and understanding of the environmental extremes and their impacts over time, this paper addresses and fills these gaps in order to inform the development of public-facing and evidence-based policies of disaster risk reduction in Malta.

     

Evidence of diverse depletion and metasomatic events in harzburgite–lherzolite mantle xenoliths from the Iberian plate (Olot, NE Spain): Implications for lithosphere accretionary processes

Mantle xenoliths from the Olot volcanic district (NE Spain) comprise a bi-modal suite consisting of protogranular spinel lherzolites (cpx 12–14%) sometimes with pargasitic amphibole, and highly refractory spinel harzburgites (cpx ≤ 1%) with coarse-grained granular textures. The lherzolites range from slightly depleted to moderately LREE-enriched with flat HREE patterns between 1.5 and 2.7 × chondrite (Ch). In contrast, the harzburgites are extremely depleted in HREE (down to 0.2 × Ch) and strongly LREE-enriched (La_N/Yb_N = 12.3–17.2). LA-ICP-MS analyses of clinopyroxene and amphibole of the lherzolites highlight variable degrees of LREE depletion (HREE up to 13 × Ch, La_N/Yb_N down to 0.01), with the exception of a single sample in which both clinopyroxene and amphibole are LREE-enriched (La_N/Yb_N up to 19). In the harzburgites, clinopyroxenes display totally different REE distributions, characterized by extreme HREE depletion (down to 0.4 × Ch) and upward convex positively fractionated middle-light REE patterns (Nd_N/Yb_N up to 20.7 × Ch; La_N/Yb_N up to 12 × Ch). Sr–Nd–Hf isotopic data for both whole-rocks and cpx separates, coherently indicate depleted mantle (DM) compositions for the lherzolites (εSr = − 15 to − 26, εNd = + 9 to + 17, εHf = + 18 to + 68) and enriched mantle (EM) compositions for the harzburgites (εSr = − 10 to + 36, εNd = − 1 to − 6, εHf = + 3 to + 8). Modelling of the clinopyroxene REE data and isotopic systematics suggest that some lherzolites were affected by pre-Paleozoic (0.6–1 By) low-degree partial melting processes, while others probably reflect some extent of refertilization of the mantle protolith by metasomatizing melts similar to the Triassic rift-related tholeiites reported from several Pyrenean localities. The harzburgites represent extreme refractory residua, resulting from a complex depletion history due to multistage melt extraction as often observed in the cratonic mantle. The distinctive REE patterns and isotopic systematics of their clinopyroxenes suggest that the harzburgites were formed by the interaction of an ultra-depleted peridotite matrix with highly alkaline basic melts similar in composition to the Permo-Triassic alkaline lamprophyres which are widespread within the Iberian plate. Lherzolites possibly represent younger lithosphere (accreted asthenosphere?) up-lifted and juxtaposed to the older subcontinental lithospheric mantle (harzburgites) during the post-Variscan rifting of the Iberian margin. These two genetically different, but adjoining, mantle domains intimately mingled along the northern Iberian margin during the subsequent plate convergence processes, leading to the close association of harzburgites and lherzolites observed in the Olot mantle xenoliths and in some Pyrenean peridotite massifs.     

Late Pleistocene and Holocene coastal palaeoeconomies: A reconsideration of the molluscan evidence from northern Spain

The worldwide increase in shell midden deposits on coastlines during the Holocene has been variously explained as the result of human population growth, economic intensification, changes in the visibility of midden deposits with changes in sea level, or climatic and environmental changes. Since coastlines are relatively unstable in geological and ecological terms, and since many archaeological sequences span periods of major climatic change, a critical issue is the ability to disentangle palaeoenvironmental from cultural and anthropogenic effects. We draw on a case study from the cave sequences of northern Spain to illustrate the problems and possibilities of palaeoeconomic and palaeoenvironmental interpretation, using studies of palaeogeographical context and analysis of abundance, taxonomic representation, ecological tolerances, size, growth structures, and other physical and chemical characteristics of the molluscs themselves. We demonstrate that the dominant, but by no means exclusive, factor in archaeologically visible long‐term changes in shell‐gathering behavior is environmental change rather than cultural change. © 2003 Wiley Periodicals, Inc.     

The West Spitsbergen Fold Belt: The result of Late Cretaceous-Palaeocene Greenland-Svalbard convergence?

The West Spitsbergen Fold Belt, together with the Eurekan structures of northern Greenland and Ellesmere Island, are suggested to be the result of Late Cretaceous-Palaeocene intracontinental compressional tectonics. The Late Palaeozoic –Mesozoic rocks of western Spitsbergen are characterized by near-foreland deformation with ramp-flat, top-to-the east thrust trajectories, whereas structurally higher nappes involving Caledonian complexes are typified by more listric thrusts and mylonite zones. A minimum of 40 km of shortening is estimated for the northern part of the West Spitsbergen Fold Belt. The axial trends in the West Spitsbergen and the North Greenland Eurekan fold belts parallel the principal fault zones which accommodated the separation of Greenland and Svalbard after Chron 25/24. In northern Greenland, north directed Eurekan thrusts associated with mylonites and cleavage formation represent at least 10 km of shortening. Between 50 and 100 km of shortening is estimated for the markedly arcuate Eurekan Fold Belt of Ellesmere Island, but the principal tectonic transport is eastwards. Kinematic reconstructions suggest that Svalbard was linked to North America before the opening of the Eurasian Basin and Norwegian — Greenland Sea. In the Late Cretaceous — Palaeocene interval, the relative motion between Greenland and North America was convergent across the Greenland — Svalbard margin, giving rise to the West Spitsbergen Fold Belt and the Eurekan structures of North Greenland.