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11.
12.
Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties 总被引:1,自引:0,他引:1
Elena Piñero Eulàlia Gràcia Francisca Martínez-Ruiz Juan Cruz Larrasoaña Alexis Vizcaino Gemma Ercilla 《Geo-Marine Letters》2007,27(2-4):279-288
Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process
that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing
sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics
can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously
cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy
and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean
Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have
compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed
samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean
grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due
to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs
indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge
could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples
from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value
than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting
that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers.
The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect
to the other samples from the southern Hydrate Ridge. 相似文献
13.
14.
ABSTRACT This study investigated the impact of pastoral land use and nutrient and fine sediment inputs on Microcoleus autumnalis and filamentous algae-dominated mats, and benthic chlorophyll-a in streams (lower North Island, New Zealand). Surveying and sampling was undertaken monthly at 61 sites spanning a wide gradient in catchment cover and environmental conditions. Two boosted regression tree models were built. The first models included pastoral land cover and five environmental variables as predictors. In the second model pastoral land cover was replaced by nutrient/sediment data. The abundance of the two mat types and chlorophyll-a increased when pastoral land cover was between 20% and 70% (model 1). Replacement of pastoral land cover by nutrient/sediment data (model 2) slightly improved the model fit for all three periphyton variables. Microcoleus autumnalis-dominant mats increased with dissolved inorganic nitrogen concentrations up to ca. 0.6?mg?L?1, and in streams with more frequent flushes. In contrast, filamentous algal-dominated mats increased with turbidity, and in streams with less frequent flushes. Chlorophyll-a generally followed the response of the dominant periphyton type. Increased knowledge on responses of specific periphyton types, rather than total biomass, to environmental variables is essential to guide effective management strategies. 相似文献
15.
Changing grading of soil: effect on critical states 总被引:6,自引:3,他引:3
Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles
leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine
material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical
states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the
dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state
conditions as the grading changes. 相似文献
16.
An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H2S/HS–/SO
inf4
sup2–
. The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H2S+HH–=Au(HS)
2
–
+1/2H2 (K14); PtS+HS–+H+=Pt (HS)
2
0
(K15); PdS+HS–+H+=Pd (HS)
2
0
(K16); PtS2+H2=Pt (HS)
2
0
(K21).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H2 gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H2 at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits. 相似文献
17.
Graham Ryder Douglas B. Stoeser Ursula B. Marvin Janice F. Bower John A. Wood 《Earth, Moon, and Planets》1975,14(3-4):327-357
Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y. 相似文献
18.
19.
L. Vočadlo K. S. Knight G. D. Price I. G. Wood 《Physics and Chemistry of Minerals》2002,29(2):132-139
The thermal expansion and crystal structure of FeSi has been determined by neutron powder diffraction between 4 and 1173?K. No evidence was seen of any structural or magnetic transitions at low temperatures. The average volumetric thermal expansion coefficient above room temperature was found to be 4.85(5)?×?10?5?K?1. The cell volume was fitted over the complete temperature range using Grüneisen approximations to the zero pressure equation of state, with the internal energy calculated via a Debye model; a Grüneisen second-order approximation gave the following parameters: θD=445(11)?K, V 0=89.596(8)?Å3, K 0′=4.4(4) and γ′=2.33(3), where θD is the Debye temperature, V 0 is V at T=0?K, K 0′ is the first derivative with respect to pressure of the incompressibility and γ′ is a Grüneisen parameter. The thermodynamic Grüneisen parameter, γth, has been calculated from experimental data in the range 4–400?K. The crystal structure was found to be almost invariant with temperature. The thermal vibrations of the Fe atoms are almost isotropic at all temperatures; those of the Si atoms become more anisotropic as the temperature increases. 相似文献
20.
Robert H Wood 《Geochimica et cosmochimica acta》2002,66(24):4365