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101.
Abstract— We have measured the titanium isotopic compositions of 23 silicon carbide grains from the Orgueil (CI) carbonaceous chondrites for which isotopic compositions of silicon, carbon, and nitrogen and aluminum‐magnesium systematics had been measured previously. Using the 16 most‐precise measurements, we estimate the relative contributions of stellar nucleosynthesis during the asymptotic giant branch (AGB) phase and the initial compositions of the parent stars to the compositions of the grains. To do this, we compare our data to the results of several published stellar models that employ different values for some important parameters. Our analysis confirms that s‐process synthesis during the AGB phase only slightly modified the titanium compositions in the envelopes of the stars where mainstream silicon carbide grains formed, as it did for silicon. Our analysis suggests that the parent stars of the >1 μm silicon carbide grains that we measured were generally somewhat more massive than the Sun (2–3 M⊙) and had metallicities similar to or slightly higher than solar. Here we differ slightly from results of previous studies, which indicated masses at the lower end of the range 1.5–3 M⊙ and metallicities near solar. We also conclude that models using a standard 13C pocket, which produces a good match for the main component of s‐process elements in the solar system, overestimate the contribution of the 13C pocket to s‐process nucleosynthesis of titanium found in silicon carbide grains. Although previous studies have suggested that the solar system has a significantly different titanium isotopic composition than the parent stars of silicon carbide grains, we find no compelling evidence that the Sun falls off of the array defined by those stars. We also conclude that the Sun does lie on the low‐metallicity end of the silicon and titanium arrays defined by mainstream silicon carbide grains. 相似文献
102.
103.
Klaus KEIL Timothy J. McCOY Lionel WILSON Jean‐Alix BARRAT Doug RUMBLE Matthias M. M. MEIER Rainer WIELER Gary R. HUSS 《Meteoritics & planetary science》2011,46(11):1719-1741
Abstract– We studied the mineralogy, petrology, and bulk, trace element, oxygen, and noble gas isotopic compositions of a composite clast approximately 20 mm in diameter discovered in the Larkman Nunatak (LAR) 04316 aubrite regolith breccia. The clast consists of two lithologies: One is a quench‐textured intergrowth of troilite with spottily zoned metallic Fe,Ni which forms a dendritic or cellular structure. The approximately 30 μm spacings between the Fe,Ni arms yield an estimated cooling rate of this lithology of approximately 25–30 °C s?1. The other is a quench‐textured enstatite‐forsterite‐diopside‐glass vitrophyre lithology. The composition of the clast suggests that it formed at an exceptionally high degree of partial melting, perhaps approaching complete melting, and that the melts from which the composite clast crystallized were quenched from a temperature of approximately 1380–1400 °C at a rate of approximately 25–30 °C s?1. The association of the two lithologies in a composite clast allows, for the first time, an estimation of the cooling rate of a silicate vitrophyre in an aubrite of approximately 25–30 °C s?1. While we cannot completely rule out an impact origin of the clast, we present what we consider is very strong evidence that this composite clast is one of the elusive pyroclasts produced during pyroclastic volcanism on the aubrite parent body ( Wilson and Keil 1991 ). We further suggest that this clast was not ejected into space but retained on the aubrite parent body by virtue of the relatively large size of the clast of approximately 20 mm. Our modeling, taking into account the size of the clast, suggests that the aubrite parent body must have been between approximately 40 and 100 km in diameter, and that the melt from which the clast crystallized must have contained an estimated maximum range of allowed volatile mass fractions between approximately 500 and approximately 4500 ppm. 相似文献
104.
The surface composition of Europa is of great importance for understanding both the internal evolution of Europa and its putative ocean. The Near Infrared Mapping Spectrometer (NIMS) investigation on Galileo observed Europa and the other Galilean satellites from 0.7 to 5.2 μm with spatial resolution down to a few kilometers during flybys by the spacecraft as it orbited Jupiter. These data have been analyzed and results published over the life of the Galileo mission and afterward. One result was the discovery of hydrated minerals at some locations on Europa and Ganymede. The data are noisy, especially for Europa, due to radiation affecting the NIMS electronics and detectors, and other artifacts are also present. The NIMS data are now being reprocessed using the accumulated knowledge gained over the entire missions to remove noise spikes and compensate for some other defects in the data. We are analyzing these reprocessed data in an attempt to defined better the nature of the hydrate spectral features and improve their interpretation. We report here on analyses of two NIMS reprocessed observations for the 0.7-3-μm region. A revised hydrate spectrum is calculated and mapped in detail across two lineaments. The spectrum shows the expected distorted water features but little or no spectral structure in these features. A narrow, weak spectral feature appears at 1.344 μm, which is weakly correlated with lower albedo. Several other weak features may be present but are difficult to confirm in these limited data sets. The hydrate signature shows the greatest strength within and toward the center of the lineaments, confirming and strengthening the association of the hydrate with these endogenic features. This trend may indicate that the material in the lineaments is youngest toward the center and has more water frost coverage toward the edge. A small, visually dark, circular feature has a spectrum that shows both hydrate and crystalline water ice features and perhaps contains a hydrate different in spectral characteristics and perhaps composition than found in the lineament. 相似文献
105.
Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity 总被引:1,自引:0,他引:1
Azetsu-Scott K Yeats P Wohlgeschaffen G Dalziel J Niven S Lee K 《Marine environmental research》2007,63(2):146-167
Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations. 相似文献
106.
Here we present a crustal folding or buckling mechanism to explain the rootless 3–5 km high Alborz Mountains in northern Iran as well as 10 km of Late Miocene to recent subsidence in the south Caspian basin and 3–6 km of subsidence in the central Iranian basin in the context of the middle Miocene to recent Arabia–Eurasia collision. A key element of the mechanism is the presence of lateral and vertical lithospheric strength contrasts between the north Iranian continental and south Caspian oceanic crusts: when compression from the collision is applied across the region, the strong south Caspian oceanic crust, buried under > 10 km of premiddle Miocene sediment, interacts with the bottom of the mechanically strong continental upper crust of northern Iran, resulting in upward buckling of the continental crust and downward buckling of the oceanic crust. We test this mechanism using a finite-element numerical model with a Maxwell rheology and obtain results that are consistent with the geological and geophysical observations. The observations compiled here and the model results demonstrate the potential for using this region as a natural laboratory for studying the early stages of continent–oceanic collision, including processes like basin inversion, fault localization and, potentially, subduction initiation. 相似文献
107.
Gary Sands 《GeoJournal》2010,75(6):539-552
Canada’s three large city regions—Montréal, Toronto and Vancouver—have been relatively successful in retaining their Manufacturing
bases, while at the same time adding substantial numbers of New Economy job opportunities. Deindustrialization appears to
have occurred primarily in the Montréal CMA (Census Metropolitan Area) and in some smaller communities where motor vehicle
manufacturing was significant. Growth in New Economy jobs has occurred in the larger CMAs; the smaller urban areas have had
little success in attracting these jobs. For the most part, these trends appear to be path dependent: prosperous communities
with substantial proportions of New Economy jobs are likely to remain prosperous and to attract more such jobs. The lack of
significant correlation between Economic Health and the presence of immigrants, same sex couples, performing and visual artists
suggests that local economic development strategies based on these factors may have limited success. 相似文献
108.
Geochemical and mineralogical evidence for Sahara and Sahel dust additions to Quaternary soils on Lanzarote,eastern Canary Islands,Spain 总被引:1,自引:0,他引:1
Daniel R. Muhs James Budahn Gary Skipp Joseph M. Prospero DeAnna Patterson E. Arthur Bettis III 《地学学报》2010,22(6):399-410
Africa is the most important source of dust in the world today, and dust storms are frequent on the nearby Canary Islands. Previous workers have inferred that the Sahara is the most important source of dust to Canary Islands soils, with little contribution from the Sahel region. Soils overlying a late Quaternary basalt flow on Lanzarote, Canary Islands, contain, in addition to volcanic minerals, quartz and mica, exotic to the island’s bedrock. Kaolinite in the soils also likely has an exotic origin. Trace‐element geochemistry shows that the soils are derived from varying proportions of locally derived basalt and African dust. Major‐element geochemistry, clay mineralogy and interpretation of satellite imagery suggest that dust additions to the Canary Islands come not only from the Sahara Desert, but also from the Sahel region. 相似文献
109.
Changes to sediment sources following wildfire in a forested upland catchment,southeastern Australia
Hugh G. Smith Gary J. Sheridan Patrick N. J. Lane Philip J. Noske Henk Heijnis 《水文研究》2011,25(18):2878-2889
Few investigations link post‐fire changes to sediment sources and erosion processes with sediment yield response at the catchment scale. This linkage is essential if downstream impacts on sediment transport after fire are to be understood in the context of fire effects across different forest environments. In this study, we quantify changing source contributions to fine sediment (<63 µm) exported from a eucalypt forest catchment (136 ha) burnt by wildfire. The study catchment is one of a pair of research catchments located in the East Kiewa River valley in southeastern Australia that have been the subject of a research program investigating wildfire effects on runoff, erosion, and catchment sediment/nutrient exports. This previous research provided the opportunity to couple insights gained from a range of measurement techniques with the application of fallout radionuclides 137Cs and 210Pbex to trace sediment sources. It was found that hillslope surface erosion dominated exports throughout the 3·5‐year post‐fire measurement period. During this time there was a pronounced decline in the proportional surface contribution from close to 100% in the first six months to 58% in the fourth year after fire. Over the study period, hillslope surface sources accounted for 93% of the fine sediment yield from the burnt catchment. The largest decline in the hillslope contribution occurred between the first and second years after fire, which corresponded with the previously reported large decline in sediment yield, breakdown of water repellency in burnt soils, substantial reduction in hillslope erodibility, and rapid surface vegetation recovery. Coupling the information on sediment sources with hillslope process measurements indicated that only a small proportion of slopes contributed sediment to the catchment outlet, with material derived from near‐channel areas dominating the post‐fire catchment sediment yield response. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
110.