Groundwater processes and sedimentary uranium deposits

 Hydrologic processes are fundamental in the emplacement of all three major categories of sedimentary uranium deposits: syngenetic, syndiagenetic, and epigenetic. In each case, the basic sedimentary uranium-enrichment cycle involves: (1) leaching or erosion of uranium from a low-grade provenance; (2) transport of uranium by surface or groundwater flow; and (3) concentration of uranium by mechanical, geochemical, or physiochemical processes. Although surface flow was responsible for lower Precambrian uranium deposits, groundwater was the primary agent in upper Precambrian and Phanerozoic sedimentary uranium emplacement. Meteoric or more deeply derived groundwater flow transported uranium in solution through transmissive facies, generally sands and gravels, until it was precipitated under reducing conditions. Syndiagenetic uranium deposits are typically concentrated in reducing lacustrine and swamp environments, whereas epigenetic deposits accumulated along mineralization fronts or tabular boundaries. The role of groundwater is particularly well illustrated in the bedload fluvial systems of the South Texas uranium province. Upward migration of deep, reducing brines conditioned the host rock before oxidizing meteoric flow concentrated uranium and other secondary minerals. Interactions between uranium-transporting groundwater and the transmissive aquifer facies are also reflected in the uranium mineralization fronts in the lower Tertiary basins of Wyoming. Similar relationships are observed in the tabular uranium deposits of the Colorado Plateau. Received, May 1998 · Revised, July 1998 · Accepted, September 1998     

Pulsar braking indices revisited

Using the standard equation for the slowdown of a neutron star, we derive a formula for the braking index via integration rather than the conventional differentiation. The new formula negates the need to measure the second time derivative of the rotation frequency, ν¨ . We show that the method gives similar braking indices for PSR B1509−58 and the Crab pulsar to those already in the literature. We point out that our method is useful for obtaining the braking indices of moderate-aged pulsars without the need for long, phase-connected timing solutions. We applied the method to 20 pulsars and discuss the implications of the results. We find that virtually all the derived braking indices are dominated by the effects of (unseen) glitches, the recovery from which corrupts the value of ν˙ . However, any real, large, positive braking index has implications for magnetic field decay and offers support to recent models of pulsar evolution.     

Cenozoic evolution of sediment accumulation in deltaic and shore-zone depositional systems, Northern Gulf of Mexico Basin

Paleogeographic and volumetric lithofacies mapping of 18 Cenozoic genetic sequences within the Northern Gulf of Mexico Basin quantifies the proportional sequestering of sediment within wave-dominated shore-zone vs. deltaic systems through time. Three long-term depositional phases are revealed by plots, based on paleogeographic and sediment isochore maps, of total shore-zone system area and volume to total delta system area and volume (SZ/D). (1) SZ/D area and volume ratios are highly variable in Paleocene through Eocene sequences. However, typical volume ratios for major genetic sequences (Upper, Middle, and Lower Wilcox; Queen City (QC), and Yegua) range between 0.2 and 0.6. Minor sequences (Sparta (SP), Jackson (JS)), which record very low rates and volumes of sediment accumulation, have the greatest variability in their ratios. (2) Oligocene and Miocene sequences display consistently high proportions of shore-zone sediment. SZ/D area ratios range from 0.6 to 1.0, and volume ratios cluster between 0.4 and 0.8. (3) A substantial late Neogene decrease in SZ/D ratios is presaged in the late Miocene sequence. Pliocene and Pleistocene sequences are uniformly characterized by very low ratios of <0.2. Consistently high Oligocene–Miocene ratios reflect a post-Eocene period of strong E–W climate gradient across the Northern Gulf margin. Shore-zone volume displays no correlation to overall rate of sediment supply. The late Neogene decrease in proportional shore-zone system importance corresponds to development of the West Antarctic and Northern Hemisphere ice sheets and related increase in amplitude and frequency of glacioeustatic sea level cycling.     

Evaluation of toxicity in tributaries of the Mersey estuary using the isopod Asellus aquaticus (L.)

Increasing numbers of industrial, agricultural and natural chemicals are present in sewage effluent and are known to elicit toxic effects in laboratory exposures, but little is known of their combined sub-lethal effect in the field. In this study, a combination of esterase activity and ventilation rate assays was performed to determine the neurological and physiological function of the freshwater crustacean Asellus aquaticus (L.) at sites above and below a sewage treatment works (STW). Cholinesterase and carboxylesterase activities were significantly inhibited (n=8, P<0.05) and ventilation rates increased (n=8, P=0.0001) in A. aquaticus at STW sites compared to those from reference sites, indicating a decrease in neurological and physiological function. The ecological relevance of these findings for the population dynamics of the organisms in the field is discussed.     

A numerical investigation of magnetic field generation in a flow with chaotic streamlines

Abstract

High resolution numerical simulations extending those of Arnold and Korkina (1983) reveal the existence of at least two windows for kinematic dynamo action in a spatially periodic flow with chaotic streamlines. These occur at moderate magnetic Reynolds number R (8–18) and at high R (27 to 200 or more).     

Biomarkers in environmental and human health risk assessment

Marine pollution is a major threat to human and environmental health. Given the complexity of function of marine and coastal ecosystems, it is unlikely that a balanced view of the nature and extent of risk will easily be achieved if human and environmental risk assessments continue to be conducted in isolation. Here, the integration of assessment protocols is advocated as a holistic means of improving risk management. Biomarkers can provide the common conceptual framework and measurable endpoints necessary for successful integration. Examples are given of the ways in which suites of biomarkers encompassing molecular change, cellular pathology and physiological impairment can be developed and adapted for human and ecological scenarios. By placing a greater emphasis on the health status of impacted biota, it is more likely that risk assessment will develop the efficiency, reliability and predictive power to adapt to the unforeseen environmental threats that are an inevitable consequence of human development and global change.     

Method for assessing the chronic toxicity of marine and estuarine sediment-associated contaminants using the amphipod Corophium volutator

Acute sediment toxicity tests do not test key life stage events such as moulting and reproduction and therefore do not reveal the longer-term effects of contaminant exposure. A laboratory method is described for determining the chronic toxicity of contaminants associated with whole sediments. The test is conducted using neonates of the estuarine amphipod Corophium volutator at 15 degrees C, salinity 25 psu and a 12 h light:12 h dark photoperiod. The endpoints are survival and growth after 28 days and survival, growth and reproduction of amphipods upon termination of test i.e. reproduction within all control vessels (ca 75 days). The sediment chronic toxicity test was used to investigate the effects of sediments spiked with environmentally relevant preparations of slightly weathered Alaskan North Slope crude oil, including a water-accommodated-fraction (WAF) and a chemically-dispersed (Corexit 9527) WAF. Sediment oil concentrations were quantified using ultra-violet fluorescence. The amphipods exposed to chemically dispersed oil had higher mortality and lower growth rates than control-, Corexit 9527- and WAF-exposed organisms, resulting in reduced reproduction. The described method supplements the standard acute sediment test and would be particularly useful when long-term ecological effects are suspected but acute tests reveal no significant mortality. The sediment chronic test reported herein has shown that sediment that was not evidently toxic during 10-day acute tests could have population-level effects on sediment-dwelling amphipods.     

Hydrological change in the central interior of British Columbia,Canada: diatom and pollen evidence of millennial-to-centennial scale change over the Holocene

Diatom-based inferences of post-glacial hydrological change from a sedimentary record from Felker Lake, British Columbia, show millennial-scale pacing of climate over the past approximately 11670 calendar years with change at ca. 8140 cal. year BP, ca. 6840 cal. year BP, ca. 5700 cal. year BP, and ca. 2230 cal. year BP. Early postglacial diatom assemblages are dominated by fragilaroid taxa, suggesting that cool and moist climate conditions and relatively high lake levels prevailed at this time. Early Holocene warming near ca. 8140 cal. year BP promoted Cyclotella bodanica var. lemanica, a fall bloomer competitive in limnological conditions associated with warmer water and stratified conditions. Short-lived peaks of Stephanodiscus parvus/minutulus between ca. 6340 cal. year BP and ca. 5860 cal. year BP indicate periodic increases in nutrient availability and prolonged mixing likely associated with long cool and moist spring seasons. The diatom-inferred depth of Felker Lake increased during the mid-Holocene to reach a record high-stand at ca. 5860 cal. year BP. Large changes in hydrological variability and terrestrial vegetation at Felker Lake occurred after ca. 2230 cal. year BP when high-amplitude centennial-scale fluctuations in diatom-inferred lake depth and salinity are observed. Change is first documented in terrestrial vegetation at this time by a shift from open Pinus parklands to a landscape that periodically supported populations of Cupressaceae. Three record low-stand high-salinity events are reconstructed between ca. 1910 cal. year BP and ca. 1800 cal. year BP, ca. 1030 cal. year BP and ca. 690 cal. year BP, and ca. 250 cal. year BP and ca. 140 cal. year BP. The low lake-level episode of ca. 1030 cal. year BP–ca. 690 cal. year BP is coeval with the Medieval Warm Period (ca. 1000 cal. year BP–ca. 600 cal. year BP), a period of intense drought in western North America. Post-glacial hydrological change at Felker Lake is coherent with regional, hemispherical, and global paleoclimate events, suggesting that millennial-and centennial-scale shifts in water availability are a persistent feature of the climate of western North America.