近45 a来中国西北年极端高、低温的变化及对区域性增暖的响应

利用中国西北五省(区)1960-2004年129个台站逐日最低、最高温度资料,从中统计出年极端高温发生频次、年极端低温发生频次、年极端高温强度、年极端低温强度以及年极端高温和低温开始和结束日期,分析了它们近45 a来的变化情况。结果表明:近45 a来中国西北年极端高温发生频次的增加趋势是明显的,而年极端低温发生频次的减少趋势更显著;中国西北近45 a来年极端高温的强度在不断增强,而极端低温的强度在不断减弱;近45 a来中国西北年极端高温开始日期逐渐提前,结束日期逐渐推迟,而年极端低温的开始日期在逐渐推迟,结束日期在逐渐提前;年极端低温发生频次的减少对于西北区域增暖的响应比年极端高温发生频次增加更显著,而年极端低温强度的减弱要比年极端高温强度的增强对西北区域性增暖的响应偏弱,年极端高温发生频次的增加同年极端高温强度的增强对西北区域性增暖的响应程度基本相当。     

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

广州科学城保利林语山庄高边坡支护工程的实践

主要介绍了广州科学城保利林语山庄高边坡支护设计方案与施工方法。支护方案综合采用了锚索、锚杆、抗滑桩、钢管桩、格构梁及挡土墙等多种支护方法，有效地提高了边坡的稳定性。应用有限元方法来验证设计方案的合理性，模拟结果与工程实践基本吻合。     

邻苯二酚螯合树脂的合成及水样中铝的测定

合成并表征了新螯合树脂———邻苯二酚螯合树脂(XAD-2-Catechol),研究了XAD-2-Catechol吸附铝的特性和茜素红-铝的显色反应,在pH4.5的HAc-NaAc缓冲介质中,茜素红和铝(Ⅲ)反应生成红色络合物,λm ax=500 nm,铝的含量在0-50μg/25 mL内符合比耳定律。建立了邻苯二酚螯合树脂分离/富集-茜素红分光光度法测定天然水样中铝的新方法,对水样中铝形态进行测定,结果满意。     

Toxicities of p-nitrotoluenes and their effects on blood corpuscles and ovaries in Crusian carps (Carassius auratus)

p-nitrotoluene is an important organic intermediate widely used in pesticide, foamed plastics, dyestuff and medicine industries. In this paper, Crusian carps (Carassius auratus) were exposed to dilute p-nitrotoluene solutions with different concentrations of 0, 20, 40, 80, 120, 160, 240 and 320 μg/L; the subsequent physiological responses to the chemical were observed, and the variation characteristics of blood corpuscles, ovaries and oocytes were studied by bio-microscopy. Results showed that even very low concentrations of p-nitrotoluene would lead to toxicosis and even the death of Carassius auratus. The bio-microscopic structures revealed that, compared with the compartment of Carassius auratus growing in the p-nitrotoluene-free water (the control group), the lower concentrations of p-nitrotoluene (for example no more than 80 μg/L) would result in the faster disintegration of erythrocytes and the significant enlargement of oocytes, while the higher contents of p-nitrotoluene (no less than 240 μg/L in this case) would inhibit the division of cells and their further growth, even degenerate blood corpuscles and ovaries, suggesting stronger estrogenic activities. The study is financially supported by the Development Foundation of Science and Technology under Shandong Provincial Education Department (No. J05D51).     

政府办公自动化系统建设和应用浅谈

本文简要地介绍了办公自动化的发展过程,分析了其常用的功能、特点,以及内容分类,论述了目前办公自动化系统的技术支撑和实现,并指出政府办公自动化系统在开发和应用中存在的问题和解决思路。对系统的推广使用具有一定的参考意义。     

基于GIS的区域地质编图方法

本文以地理信息系统在小比例尺区域地质编图中的应用为基础,结合《亚洲中部及邻区系列地质图》的编制,详细阐述了应用ArcInfo、MapGis等GIS软件进行数字地质编图的方法.对地理空间数据和专业地质空间数据的编制做了详细介绍,其中包括各种要素制图综合、属性库制作、编码设计、现势资料的补充等.根据数据源的不同,制定了不同的技术路线和工作方法.将来自不同国家的数据源进行数据转换、投影变换和误差校正,转换为统一的数据格式和投影坐标系统.对基于GIS的区域地质编图方法及数据源做了具体分析.     

青海湖地区生态环境动态变化遥感监测

由于青海湖地区的生态环境较为脆弱，且人类活动进一步加剧，人口、资源与环境的矛盾日渐突出，因此，近年来．青海湖及其周边地区的生态环境出现了明显变化，主要表现在水位下降及水域面积减小、草原退化、沙质荒漠化土地面积扩大等。文章采用1975年MSS卫星图像及1987、2000年TM卫星图像作为遥感信息源，并结合地理信息系统方法，旨在查明青海满地区耕地、沙质荒漠化土地和水域等生态环境要素的时空演化规律，为青海湖地区实现资源开发与环境协调发展提供科学依据。监测结果表明，25a来，青海湖地区的耕地及沙质荒漠化土地面积出现明显的扩大，而水域面积出现明显缩小，同时由于湖周各河流土壤侵蚀的加剧，在部分河流入湖处泥沙淤积较为严重，生态环境出现明显恶化。     

单一滑面边坡的非稳定蠕变模型分析

对单一滑面边坡的非稳定蠕变分析是边坡稳定性研究的基础。文中对岩质边坡单一滑面的流变变形机制进行了分析，提出了一种能较好反映这一变形机制的非稳定蠕变模型。特别是描述单一滑面边坡的非稳定蠕变破坏阶段，并对其稳定性进行了讨论。结合一些工程实例进行了对比验证，为滑坡灾害的预测和防治提供依据。     

西部煤炭资源调查评价中遥感技术的应用

通过西部煤炭资源勘查对遥感技术的需求以及煤田地质体的可解译性、遥感技术的实际应用效果分析,论述了西部煤炭资源调查评价中遥感技术的重要作用,提出了今后遥感技术的应用建议.