Early diagenetic recrystallization of Holocene (<3000 years old) peritidal dolomites, Ambergris Cay, Belize

Three peritidal carbonate crusts and associated intercrust sediments (total thickness of ～30cm; aged <3000 years BP) on Ambergris Cay, Belize, contain 32–100% calcian dolomite (δx=72·5% dolomite) ranging in composition from 40 to 46 mol% MgCO₃ (δx=43·3). Dolomite replaced high Mg calcite foraminiferal muds penecontemporaneously with sedimentation, forming partially dolomitized sediments and lithified crusts. Dolomitization probably occurred in normal to moderately evaporated seawater and is apparently continuing at the present. Detailed scanning electron microscope analysis shows a linear increase in mean dolomite crystal size with depth; 0·4 μm near the top of the section to 1·0 μm near the base of the dolomitized section. This size increase is not accompanied by any significant decrease in porosity. Crystal size distributions appear to be log-normal and become increasingly broad and flat with depth. Rietveld X-ray pattern-fitting structure refinements indicate increasing Ca and Mg concentrations on their respective sites (cation ordering) as a function of increasing depth. Most of the ordering occurs within the first 15 cm of the surface. Stoichiometry does not increase with depth indicating no relationship between the Ca/Mg ratio and cation ordering. Strong geochemical trends were observed down-section in the dolomite, including: (1) increasing Mn content (44 to 274 ppm), and (2) decreasing δ¹³C values (?0·9 to ?5·5‰ PDB). Oxygen isotope values range from δ¹⁸O = 1·3‰ PDB in the upper part of the section to 2·6‰ PDB in the lower part of the section and are interpreted to represent two distinct groups of values rather than a continuous trend. Down-section dolomite crystal size increase and shapes of crystal size distributions are consistent with recrystallization via a surface energy-driven dissolution-reprecipitation process (Ostwald ripening). The observed trends in carbon isotopes and Mn content probably result from geochemical re-equilibration during recrystallization and reflect reducing conditions and an isotopically light, organically derived, carbon source. Oxygen isotope compositions probably reflect relict original dolomite values and are a result of decreasing evaporation due to rising sea level.     

An empirical model of aeolian dune lee-face airflow

Airflow data, gathered over dunes ranging from 60-m tall complex-crescentic dunes to 2-m tall simplecrescentic dunes, were used to develop an empirical model of dune lee-face airflow for straight-crested dunes. The nature of lee-face flow varies and was found to be controlled by the interaction of at least three factors (dune shape, the incidence angle between the primary wind direction and the dune brinkline and atmospheric thermal stability). Three types of lee-face flow (separated, attached and deflected along slope, or attached and undeflected) were found to occur. Separated flows, characterized by a zone of low-speed (0–3O% of crestal speed) back-eddy flow, typically occur leeward of steep-sided dunes in transverse flow conditions. Unstable atmospheric thermal stability also favours flow separation. Attached flows, characterized by higher flow speeds (up to 84% of crestal speed) that are a cosine function of the incidence angle, typically occur leeward of dunes that have a lower average lee slope and are subject to oblique flow conditions. Depending on the slope of the lee face, attached flow may be either deflected along slope (lee slopes greater than about 20°), or have the same direction as the primary flow (lee slopes less than about 20°). Neutral atmospheric thermal stability also favours flow attachment. As each of the three types of lee-face flow is defined by a range of wind speeds and directions, the nature of lee-face flow is intimately tied to the type of aeolian depositional process (i.e. wind ripple or superimposed dune migration, grainflow, or grainfall) that occurs on the lee slope and the resulting pattern of dune deposits. Therefore, the model presented in this paper can be used to enhance the interpretation of palaeowind regime and dune type from aeolian cross-strata.     

Mineralogy,petrography, bulk chemical,iodine-xenon,and oxygen-isotopic compositions of dark inclusions in the reduced CV3 chondrite Efremovka

Abstract— We studied the petrography, mineralogy, bulk chemical, I-Xe, and O-isotopic compositions of three dark inclusions (E39, E53, and E80) in the reduced CV3 chondrite Efremovka. They consist of chondrules, calcium-aluminum-rich inclusions (CAIs), and fine-grained matrix. Primary minerals in chondrules and CAIs are pseudomorphed to various degrees by a mixture largely composed of abundant (>95%), fine-grained (>0.2 μm) fayalitic olivine (Fa_35–42) and minor amounts of chlorite, poorly-crystalline Si-Al-rich material, and chromite; chondrule and CAI shapes and textures are well-preserved. Secondary Ca-rich minerals (Ti-andradite, kirschsteinite, Fe-diopside) are common in chondrule pseudomorphs and matrices in E39 and E80. The degree of replacement increases from E53 to E39 to E80. Fayalitic olivines are heavily strained and contain abundant voids similar to those in incompletely dehydrated phyllosilicates in metamorphosed CM and CI chondrites. Opaque nodules in chondrules consist of Ni- and Co-rich taenite, Co-rich kamacite, and wairauite; sulfides are rare; magnetite is absent. Bulk O-isotopic compositions of E39 and E53 plot in the field of aqueously altered CM chondrites, close to the terrestrial fractionation line; the more heavily altered E39 is isotopically heavier than the less altered E53. The apparent I-Xe age of E53 is 5.4 Ma earlier than Bjurböle and 5.7 ± 2.0 Ma earlier than E39. The I-Xe data are consistent with the most heavily altered dark inclusion, E39 having experienced either longer or later alteration than E53. Bulk lithophile elements in E39 and E53 most closely match those of CO chondrites, except that Ca is depleted and K and As are enriched. Both inclusions are depleted in Se by factors of 3–5 compared to mean CO, CV, CR, or CK chondrites. Zinc in E39 is lower than the mean of any carbonaceous chondrite groups, but in E53 Zn is similar to the means in CO, CV, and CK chondrites. The Efremovka dark inclusions experienced various degrees of aqueous alteration, followed by low degree thermal metamorphism in an asteroidal environment. These processes resulted in preferential oxidation of Fe from opaque nodules and formation of Ni- and Co-rich metal, metasomatic alteration of primary minerals in chondrules and CAIs, and the formation of fayalitic olivine and secondary Ca-Fe-rich minerals. Based on the observed similarities of the alteration mineralization in the Efremovka and Allende dark inclusions, we infer that the latter may have experienced similar alteration processes.     

Trapping of sustained turbidity currents by intraslope minibasins

Depositional turbidity currents have filled many intraslope minibasins with sediment creating targets for petroleum exploration. The dynamics of sustained turbidity currents and their depositional characteristics are investigated in a scaled physical model of a minibasin. Each turbidity current deposited a downstream thinning wedge of sediment near the inlet. Farther downstream the turbidity current was ponded by a barrier. The ponded part of the turbidity current was separated from the sediment‐free water above by a relatively sharp, horizontal settling interface indicating highly Froude‐subcritical flow. The very slow moving flow within the ponded zone created conditions for the passive rainout of suspended sediment onto the bed. In the lower part of the ponded zone, the concentration and mean grain‐size of the sediment in suspension tended to be relatively uniform in both the vertical and streamwise directions. As a result, the deposit emplaced in the ponded zone showed only a weak tendency toward downstream fining and was passively draped over the bed in such a way that irregularities in the inerodible bed were accurately reflected. The discharge of suspended sediment overflowing the downstream end of the minibasin was significantly less than the inflow discharge, resulting in basin sediment trapping efficiencies >95%. A simple model is developed to predict the trapping of sediment within the basin based on the relative magnitudes of the input discharge of turbid water and the detrainment discharge of water across the settling interface. This model shows a limiting case in which an intraslope basin captures 100% of the sediment from a ponded turbidity current, even through a succession of sustained flow events, until sediment deposition raises the settling interface above the downstream lip of the minibasin. This same process defines one of the mechanisms for minibasin filling in nature, and, when this mechanism is operative, the trap efficiency of sediment can be expected to be high until the minibasin is substantially filled with sediment.     

Hydrothermal Alteration and Fluid Geochemistry of the Tongonan Geothermal Field, Philippines

Abstract: The alteration mineralogy, the present-day fluid chemistry, and some fluid inclusion data are used to make inferences on the chemical changes that have occurred in the fluids during the history of the Tongonan Geothermal Field. Thermal activity in the Tongonan area began in the Miocene when emplacement of many plutons forming a batholith contact metamorphosed the overlying volcanics to hornblende hornfels assemblages. In the early Pliocene, when tectonic uplift occurred along the Philippine Fault, about 2 mole % of mainly carbon dioxide and sulfur gas was released to a geothermal fluid and condensed in groundwater with geothermal steam. The condensate intensely altered the reservoir rock and formed an acid mineral assemblage, which was overprinted by a later, lower temperature, neutral-pH assemblage. Some chlorite, epidote and illite in the reservoir rock formed at temperatures up to 100°C lower than present-day temperatures possibly during the Plio-Pleistocene uplift period, i.e., the system was heating up. The assemblage garnet-anhydrite formed in fractures from a condensate after the gas had nearly completely separated from the deep, CO₂-rich fluid during vigorous boiling possibly during hydrothermal eruptions. The output of gas to the geothermal fluid decreased, while the salinity (10,000 mg/kg or - 2 wt% NaCl) and the temperature of the geothermal fluid remained nearly constant throughout the Quaternary. When this neutral-pH, alkali chloride fluid boiled, it initially precipitated albite or epidote on the rims then anhydrite at the center of fractures at high temperatures (-250–300°C). At lower temperatures (-150–250°C), adularia or wairakite and later calcite were deposited as the proportion of gas in the steam condensate increased. The origin of solutes is also discussed.