Methods of Hierarchical Control of Water Quality Taking into Account Manipulations of the Center and Countermoves of Enterprises

Methods of hierarchical control including manipulations of a Center and the countermove of enterprises are considered using as an example a dynamic two-level model of river water quality control in the presence of point pollution sources and in the absence of nonpoint sources.     

萨拉乌苏河流域萨拉乌苏组砂丘砂沉积特征

The Salawusu Formation of Milanggouwan section in Salawusu River Valley includes 7 layers of paleo-mobile dune sands, and 4 layers of paleo-fixed and semi-fixed dune sands. Their structures have been observed and their grain size, surface textural features and several main chemical elements have been analyzed. The results showed that： 1） Some of the aeolian structural characteristics of these dune sands are similar to that of the recent dune sands. 2） They are also similar to the recent dune sands in grain size components, and parameters of Mz,σ, Sk and Kg, as well as in several main chemical components. 3） The scattergrams of Mz-σ and SiO2-Al2O3＋TOFE and the probability curves of grain size showed that these paleo-dune sands are different from paleosols and fluvio-lacustrine facies, but are consistency with recent dune sands. 4） Quartz sands have well roundness and surface textural features such as dish-shaped pits, crescent-shaped pits, pockmarked pits, upturned cleavage plates, siliceous precipitates and siliceous crevasses, indicating that they had been carried for a long time by the wind. As the 11 layers of paleo-dune sands possess the aeolian characteristics in structure, grain size, surface textural features and chemical elements, the origin of their formation should be attributed to eolation.     

New P–T constraints on the Tamayen glaucophane‐bearing rocks,eastern Taiwan: Perple_X modelling results and geodynamic implications

New pseudosection modelling was applied to better constrain the P–T conditions and evolution of glaucophane‐bearing rocks in the Tamayen block of the Yuli belt, recognized as the world's youngest known blueschist complex. Based on the predominant clinoamphibole, textural relationships, and mineral compositions, these glaucophane‐bearing high‐P rocks can be divided into four types. We focused on the three containing garnet. The chief phase assemblages are (in decreasing mode): amphibole + quartz + epidote + garnet + chlorite + rutile/titanite (Type‐I), phengite + amphibole + quartz + garnet + chlorite + epidote + titanite + biotite + magnetite (Type‐II), and amphibole + quartz + albite + epidote + garnet + rutile + hematite + titanite (Type‐III). Amphibole exhibits compositional zoning from core to rim as follows: glaucophane → pargasitic amphibole → actinolite (Type‐I), barroisite → Mg‐katophorite/taramite → Fe‐glaucophane (Type‐II), glaucophane → winchite (Type‐III). Using petrographic data, mineral compositions and Perple_X modelling (pseudosections and superimposed isopleths), peak P–T conditions were determined as 13 ± 1 kbar and 550 ± 40 °C for Type‐I, 10.5 ± 0.5 kbar and 560 ± 30 °C for Type‐II (thermal peak) and 11 ± 1 kbar and 530 ± 30 °C for Type‐III. The calculations yield higher pressures and temperatures than previously thought; the difference is ~1–6 kbar and 50–200 °C. The three rock types record similar P–T retrograde paths with clockwise trajectories; all rocks followed trajectories with substantial pressure decrease under near‐isothermal conditions (Type‐I and Type‐III), with the probable exception of Type‐II where decompression followed colder geotherms. The P–T paths suggest a tectonic environment in which the rocks were exhumed from maximum depths of ~45 km within a subduction channel along a relative cold geothermal gradient of ~11–14 °C km^?1.     

Thermal expansion and high-temperature P21/c–C2/c phase transition in clinopyroxene-type LiFeGe2O6 and comparison to NaFe(Si,Ge)2O6

A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) ų, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe³⁺Ge₂O₆, monoclinic s.g. P2₁/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?³, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P2₁/c to C2/c at a transition temperature T _tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T _tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T _tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P2₁/c expands more than the C2/c phase. The evolution of Q ² (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe a jump of Q ₀² = 0.538(2) at T _tr, with T _c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe³⁺Si₂O₆) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P2₁/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron. The tetrahedra behave as rigid units with neither a significant change of volume at T > T _tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T _tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This deformation is related to a strong change by 51.4° at T _tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)° to 194.7(6)°]. The A-chain is S-rotated at T < T _tr [206.8(5)° at 703 K] and extends by 12° at the transition.     

Experimental study of eclogite melting with participation of the H<Subscript>2</Subscript>O-CO<Subscript>2</Subscript>-KCl fluid at 5 GPa

In order to model the processes of formation of the highly alkaline (potassic) melts during the partial melting of the eclogite nodules in kimberlites, experiments on the melting of the model and natural eclogites in presence of the H₂O-CO₂ and H₂O-CO₂-KCl fluids at 5 GPa and 1200 and 1300°C are performed. A comparative analysis of the phase relations in the systems with H₂O-CO₂ and H₂O-CO₂-KCl demonstrate that KCl in the fluid equilibrated with eclogites intensifies their melting. It is related to both high Cl concentration in the forming silicate melt (2.0–5.5 wt %) and its enrichment in K₂O owing to the K-Na exchange reactions with the immiscible chloride melt. Because of these reactions, the K₂O/Cl ratio in the melts increases with the KCl content in the system and reaches 2.5–3.5 in the silicate melts coexisting with the immiscible chloride liquid. However, the ratio KCl/(H₂O + CO₂ + KCl) in the fluid does not influence on the ratio K₂O/Cl in the melts. Thus, the solubility KCl in the melts, apparently, does not depend on presence of the H₂O-CO₂ fluid, at least, within the concentration range used in the experiments (up to 20 wt %). The experiments show that the deliberated chloride liquid is necessary to form the potassium-rich chlorine-bearing silicate melts during the eclogite melting. It corresponds to the KCl content in the system above 5 wt %.     

Dynamics of Saxothuringian subduction channel/wedge constrained by phase‐equilibria modelling and micro‐fabric analysis

Subduction and exhumation dynamics can be investigated through analysis of metamorphic and deformational evolution of associated high‐grade rocks. The Erzgebirge anticline, which forms at the boundary between the Saxothuringian and Teplá‐Barrandian domains of the Bohemian Massif, provides a useful study area for these processes owing to the occurrence of numerous meta‐basites preserving eclogite facies assemblages, and coesite and diamond bearing quartzofeldspathic lithologies indicating subduction to deep mantle depths. The prograde and retrograde evolution of meta‐basite from the Czech portion of the Erzgebirge anticline has been constrained through a combination of thermodynamic modelling and conventional thermobarometry. Garnet growth zoning indicates that the rocks underwent burial and heating to peak conditions of 2.6 GPa and at least 615 °C. Initial exhumation occurred with concurrent cooling and decompression resulting in the growth of amphibole and zoisite poikiloblasts overgrowing and including the eclogite facies assemblage. The development of clinopyroxene–plagioclase–amphibole symplectites after omphacite and Al‐rich rims on matrix amphibole indicate later heating at the base of the lower crust. Omphacite microstructures, in particular grain size analysis and lattice‐preferred orientations, indicate that the prograde evolution was characterized by a constrictional strain geometry transitioning into plane strain and oblate fabrics during exhumation. The initial constrictional strain pattern is interpreted as being controlled by competing slab pull and crustal buoyancy forces leading to necking of the subducting slab. The transition to plane strain and flattening geometries represents transfer of material from the subducting lithosphere into a subduction channel, break‐off of the dense slab and rebound of the buoyant crustal material.     

Neutral sodium atoms release from the surface of the Moon induced by meteoroid impacts

In this work, we calculate the vapour and neutral Na production rates on the Moon, as due to the impacts of meteoroids in the radius range of 10⁻⁸–0.15 m. We limit our calculations to this size range, since meteoroids with radius larger than 0.15 m have not been found to be important for the production of the exosphere in a time interval comparable with that of the observations.
We have considered a new dynamical model of the flux of meteoroids at the heliocentric distance of the Moon, regarding objects in the radius range of 10⁻²–0.15 m. Instead, the flux of smaller meteoroids (radius range 10⁻⁸–10⁻² m) has been calculated using the two distributions adopted by Cintala and Love & Brownlee.
The results of our model are that (i) the neutral Na production rate is  ∼3–4.9 × 10⁴ atoms cm⁻² s⁻¹  , slightly larger than the previous estimates  (∼2–3 × 10⁴ atoms cm⁻² s⁻¹)  , and (ii) only about 6 per cent of neutral Na is produced by the impacts of meteoroids in the size range 10⁻³–0.15 m, whereas about 94 per cent of the Na comes from the  10⁻⁵–10⁻³ m  size range.     

Response of evapotranspiration and water availability to the changing climate in Northern Eurasia

We introduce a probabilistic framework for vulnerability analysis and use it to quantify current and future vulnerability of the US water supply system. We also determine the contributions of hydro-climatic and socio-economic drivers to the changes in projected vulnerability. For all scenarios and global climate models examined, the US Southwest including California and the southern Great Plains was consistently found to be the most vulnerable. For most of the US, the largest contributions to changes in vulnerability come from changes in supply. However, for some areas of the West changes in vulnerability are caused mainly by changes in demand. These changes in supply and demand result mainly from changes in evapotranspiration rather than from changes in precipitation. Importantly, changes in vulnerability from projected changes in the standard deviations of precipitation and evapotranspiration are of about the same magnitude or larger than those from changes in the corresponding means over most of the US, except in large areas of the Great Plains, in central California and southern and central Texas.     

Unravelling a long-term multi-event thermal record in the cratonic interior of southern Finland through apatite fission track thermochronology

Apatite fission track thermochronology (AFTT) has been applied to the Precambrian basement rocks of southern Finland in an attempt to detect within the long-term thermal history, thermal manifestations in the cratonic interior of tectonic events at the craton margin. The likely subtle magnitude of these manifestations means that AFTT is a useful technique for such a study due to its low temperature sensitivity. A total of 10 samples have been analysed, generating AFTT ages, length statistics and thermal models. Ages range from 313 ± 22 to 848 ± 60 Ma and mean track lengths range from 11.0 ± 1.6 to 13.3 ± 1.8 μm. The data suggests the presence of thermal overprinting of an earlier cooling event. Thermal modelling produces similar results for all samples and typically contains the following major events: (1) two phases of Late-Proterozoic cooling, (2) Late-Silurian re-heating, (3) Cenozoic cooling. The first phase of Late-Proterozoic cooling is interpreted to be due to aulacogen inversion as a result of stress propagation from the collisional tectonics of the Sveconorwegian orogeny. The second phase is discussed in relation to passive margin formation and possible asthenospheric diaper induced relief and exhumation. The Late-Silurian re-heating coincides in time with a proposed Caledonian foreland basin. The Cenozoic cooling is interpreted to represent the latest exposure resulting from North Atlantic Margin formation induced uplift and associated denudation.     

Water renewal estimates for aquaculture developments in the Richibucto estuary,Canada

Water renewal in semi-enclosed coastal areas is crucial for the supply of oxygen and seston and for the removal of organic loadings from finfish or shellfish aquaculture sites. Water renewal depends on hydrodynamic processes and can have a complex spatial distribution due to irregular topographic features. This study describes some physical oceanography observations gathered in the Richibucto estuary, New Brunswick, Canada, and provides an estimate of the spatial distribution of water renewal in the North Arm, a location in the estuary where the largest American oyster (Crassostrea virginica) aquaculture operation in eastern Canada is located. The estuary changes from a well mixed estuary to a partially stratified estuary depending on runoff conditions. Tides are mixed but mainly diurnal due to the nearby presence of the second M₂ amphidromic point in the Gulf of St. Lawrence. Tidal amplitudes vary from 0.3 to 0.6 m and show a slight increase some 35 km upstream. Currents in the main channel can reach over 0.60 m s⁻¹ during ebb and 0.3 m s⁻¹ during flood, with a slack water period of approximately 8 h. Low frequency sea level fluctuations have a range of 0.5 m at the mouth and are coherent within the estuary. Hydrodynamic and advection-dispersion models are used to calculate the spatial distribution of the local renewal time (LRT) in the North Arm for high and low freshwater discharge conditions, using the dissolved tracer method. Results show that the LRT varies from less than 5 d at the downstream end of the North Arm to over 100 d further upstream. When averaged over the entire North Arm, the integral renewal time (IRT) is estimated to vary only from 8 to 21 d depending on the season. The LRT and IRT estimates are major improvements over conventional renewal estimates using tidal prism methods.