Iron(II) oxide determination in rocks and minerals

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.     

X-ray intensity-hardness correlation and deep IR observations of the anomalous X-ray pulsar 1RXS J170849-400910

We report here on X-ray and IR observations of the Anomalous X-ray Pulsar (AXP) 1RXS J170849-400910. First, we report on new XMM-Newton, Swift-XRT and Chandra observations of this AXP, which confirm the intensity–hardness correlation observed in the long term X-ray monitoring of this source. These new X-ray observations show that the AXP flux is rising again, and the spectrum hardening. If the increase of the source intensity is indeed connected with the glitches and a possible bursting activity, we expect this source to enter in a bursting active phase around 2006–2007. Second, we report on deep IR observations of 1RXS J170849-400910, taken with the VLT-NACO adaptive optics, showing that there are many weak sources consistent with the AXP position. Neither star A or B, as previously proposed by different authors, might yet be conclusively recognised as the IR counterpart of 1RXS J170849-400910. Third, using Monte Carlo simulations, we re-address the calculation of the significance of the absorption line found in a phase-resolved spectrum of this source, and interpreted as a resonant scattering cyclotron feature.     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

A Segment-Based Speckle Filter Using Multisensoral Remote Sensing Imagery

In the proposed approach, the well-known enhanced Lee filter is modified to allow the integration of feature outlines-previously extracted from segmented optical images. The filter is applied to several ENVISAT ASAR images that cover urban, agricultural, and forest areas during different plant phenological stages. The performance of this segment-based speckle filter is compared to those of other filters using ratio images, visual interpretation, and statistical indexes. The approach reduces the loss of radiometry and spatial information. It performs comparable to more complex methods and outperforms common techniques