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161.
The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities and were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of and with temperature are small and, in addition, and are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO2 pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with PCO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C. 相似文献
162.
Chang Ki Kim Martin Stuefer Carl G. Schmitt Andrew Heymsfield Greg Thompson 《Pure and Applied Geophysics》2014,171(8):1963-1982
An ice microphysics parameterization scheme has been modified to better describe and understand ice fog formation. The modeling effort is based on observations in the Sub-Arctic Region of Interior Alaska, where ice fog occurs frequently during the cold season due to abundant water vapor sources and strong inversions existing near the surface at extremely low air temperatures. The microphysical characteristics of ice fog are different from those of other ice clouds, implying that the microphysical processes of ice should be changed in order to generate ice fog particles. Ice fog microphysical characteristics were derived with the NCAR Video Ice Particle Sampler during strong ice fog cases in the vicinity of Fairbanks, Alaska, in January and February 2012. To improve the prediction of ice fog in the Weather Research and Forecasting model, observational data were used to change particle size distribution properties and gravitational settling rates, as well as to implement a homogeneous freezing process. The newly implemented homogeneous freezing process compliments the existing heterogeneous freezing scheme and generates a higher number concentration of ice crystals than the original Thompson scheme. The size distribution of ice crystals is changed into a Gamma distribution with the shape factor of 2.0, using the observed size distribution. Furthermore, gravitational settling rates are reduced for the ice crystals since the crystals in ice fog do not precipitate in a similar manner when compared to the ice crystals of cirrus clouds. The slow terminal velocity plays a role in increasing the time scale for the ice crystals to settle to the surface. Sensitivity tests contribute to understanding the effects of water vapor emissions as an anthropogenic source on the formation of ice fog. 相似文献
163.
The re-entry phase of a highly eccentric satellite is discussed. Numerical simulations allowing the prediction of the exact date of re-entry of a highly eccentric satellite are exposed.It is shown that under very particular circumstances the life of the satellite can be extended by a few days. The number of final revolutions of the rapidly contracting orbit depends critically on the air density between 70 km and 100 km.Re-entry of the European scientific satellite HEOS-1 predicted for 28 October, 1975 is near such a situation. 相似文献
164.
Current plate motions 总被引:57,自引:0,他引:57
165.
We discuss contradictions existing in the literature in the problem on the stability of collisionless spherical stellar systems,
which are the simplest anisotropic generalization of the well-known polytropic models. On the one hand, calculations of the
growth rates within the framework of a linear stability theory and N-body simulations suggest that these systems should become stable when the parameter s characterizing the degree of anisotropy of the stellar velocity distribution becomes lower than some critical value s
crit > 0. On the other hand, according to Palmer and Papaloizou, the growth rate should be nonzero up to the isotropic limit s = 0. Using our method of determining the eigenmodes of stellar systems, we show that even though the mode growth rates in
weakly radially anisotropic systems of this type are nonzero, they are exponentially small, i.e., decrease as γ ∝ exp(−a/s) when s → 0. For slightly radially anisotropic systems with a finite lifetime, this actually implies stability. 相似文献
166.
CRISM indicates the presence of water ice patches in Richardson crater, located on Mars’ southern polar region at the area of the seasonal ice cap. Numerical simulations suggest that the maximum daytime temperature of the ice at these locations is between 195 and 220 K during local spring. Previous studies suggest that at these temperatures liquid interfacial water could be present. Here, for the first time, we provide an example where the environmental conditions allow for the formation of such liquid films on present day Mars at the southern hemisphere. The upper bound estimated H2O loss during the presence of these water ice patches is approximately 30 μm between Ls = 200 and 220, though it may be as low as 0.1 μm depending on the ambient water vapor. The upper bound value is larger than the expected condensation thickness in autumn; however, it may still be realistic due to CO2 gas jet generated deposition and possible subsequent accumulation on mineral grains. The presence of this interfacial water may have impact on local chemical processes along with astrobiological importance. 相似文献
167.
Wiesław Wiśniewolski Janusz Górczyński Wiesław Madry 《Aquatic Sciences - Research Across Boundaries》1989,51(3):249-259
Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure. 相似文献
168.
169.
170.
G. R. Huguenin A. E. Lilley W. H. McDonough M. D. Papagiannis 《Planetary and Space Science》1964,12(12):1157-1167
Radio noise observations at frequencies of 0·700 Mc and 2·200 Mc were made at altitudes between 3000 and 11,000 km from a Blue Scout Jr. high-altitude rocket probe on 30 July 1963. A steady background flux of (7·5−3+6) × 10−19 W m−2)(c/s)−1 at 0·700 Mc and (1·8+1.0−0.5 × 10−19 W m−2 (c/s)−1 at 2·200 Mc was observed. Assuming a galactic origin of the observed fluxes at both frequencies, the averaged sky brightnesses are b(0·700 Mc) = (6−3+5) × 10−20 W m−2 (c/s)−1 sr−1b(2·200 Mc) = (1.4+1.0−0.5 × 10−20 W m−2 (c/s)−1 sr−1 The observed brightness at 2·200 Mc is in reasonable agreement with the results of other observers. The apparent brightness at 0·700 Mc is, however, greater than was expected from previous observations. An alternative source of the 0·700 Mc flux in the terrestrial exosphere, as well as characteristics of several noise bursts observed during the flight, is briefly discussed. 相似文献