Chemical forms of chromium in natural water

The interaction of chromium (III) with humic substances obtained from pond sediment was experimentally studied using electrophoresis combined with ultrafiltration. The results show that within the neutral pH range chromium (III) in the presence of humic substances and some organic acids forms uncharged and/or negatively charged organic complexes of various molecular weights. A part of the chromium(III)-humic or -fulvic acid complexes having a negative charge was of lower molecular weight. Chromium (III) spiked in fresh water exists as various soluble anionic and/or uncharged species, and the molecular weights of these anionic complexes correspond to those of chromium(III)-humic and -fulvic complexes. These complexes may remain as stable dissolved forms for 10 days. The significance of the occurrence of chromium(III)-organic complexes in natural water in the geochemical cycle of chromium in the hydrosphere is discussed.     

Seasonal variations of the upper ocean in the western north pacific observed by an argo float

A seasonal evolution of surface mixed layer in the western North Pacific around 24°N between 143°E and 150°E was observed by using an Argo float for more than 9 months, from December 2001 through August 2002. The result showed that the mixed layer deepened gradually in the first two months. It reached its maximum depth of about 130 m at the end of January, after which the mixed layer varied largely and sometimes the pycnocline below the mixed layer was much weakened until the summer mixed layer formed in late April. The thin surface mixed layer was maintained during the rest of the observation period. Heat budget analysis suggests that the vertical and horizontal temperature advections are the two most dominant terms in the heat balance in the upper layer on time scales from a few days to a month. The vertical motions that are possibly responsible for the vertical temperature advection are discussed.     

Oceanic Velocity Microstructure Measurements in the 20th Century

The science of ocean turbulence was started more than 50 years ago by a small research group using a surplus mine-sweeping paravane to measure the velocity and temperature fluctuations in the ocean. The field has grown considerably and measurements are now conducted by researchers in many countries. A wide variety of sophisticated instrument systems are used to profile horizontally and vertically through the marine environment. Here we review the historical development of velocity micro-structure profiles over the past four decades and summarize the basic requirements for successful measurements. We highlight critical technological developments and glance briefly at some of the scientific discoveries made with these instruments. This revised version was published online in August 2006 with corrections to the Cover Date.     

Normal faulting of the Daiichi-Kashima Seamount in the Japan Trench revealed by the Kaiko I cruise, Leg 3

A detailed topographic and geophysical survey of the Daiichi-Kashima Seamount area in the southern Japan Trench, northwestern Pacific margin, clearly defines a high-angle normal fault which splits the seamount into two halves. A fan-shaped zone was investigated along 2–4 km spaced, 100 km long subparallel tracks using narrow multi-beam (Seabeam) echo-sounder with simultaneous measurements of gravity, magnetic total field and single-channel seismic reflection records. Vertical displacement of the inboard half was clearly mapped and its normal fault origin was supported. The northern and southern extensions of the normal fault beyond the flank of the seamount were delineated. Materials on the landward trench slope are displaced upward and to sideways away from the colliding seamount. Canyons observed in the upper landward slope terminate at the mid-slope terrace which has been uplifted since start of subduction of the seamount. Most of the landward slope except for the landward walls aside the seamount comprises only a landslide topography in a manner similar to the northern Japan Trench wall. This survey was conducted on R/V “Jean Charcot” as a part of the Kaiko I cruise, Leg 3, in July–August 1984 under the auspices of the French-Japanese scientific cooperative program.     

Coseismic resistivity steps

A resistivity variometer, which has been operated at a station about 60 km south of Tokyo, recorded eleven resistivity steps in association with earthquake occurrences during a four year period of observation. Comparing these steps to those calculated on the basis of the dislocation theory, it is concluded that the variometer has an enormously high sensitivity or amplification factor amounting to 3 · 10⁴ for small strains of the order of 10⁻⁸–10⁻⁹.Hypothetical strain steps, that would have been observed at a point having an epicentral distance of 100 km, correlate well with earthquakes of magnitudes ranging from 5 to 8. The time required for a step to be completed seems large for a large earthquake although there is considerable scatter in the diagram for the time vs. magnitude relation. Nothing definite has been put forward about the nature of precursory effect observed for a few of the earthquakes.     

Tectonoelectricity

Anomalous earth-current changes in association with an earthquake occurrence have often been reported since the 19th century. Changes reported in classical as well as recent literature are reviewed, although it is hard to say that any physically clear relationship between earth-current changes and earthquakes has been established. Even though a strong correlation between precursory earthcurrent changes and earthquakes has often been reported in the U.S.S.R. and the People's Republic of China in recent years, it appears that a general rule governing the earthquake-related earth-current changes is still very much unknown, partly because of contamination by artificial and natural noise.In contrast to the difficulty in understanding earth-current changes, monitoring of earth-resistivity seems to provide a much clearer means for interpreting geoelectric phenomena in association with tectonic processes in the Earth. Soviet and American work showed that the resistivity decreases to a considerable extent in the focal region prior to an earthquake. Such a change seems to be closely correlated to dilatancy generation in the Earth's crust. This finding doubtless provides an important means for earthquake prediction.An ususual, highly sensitive resistivity variometer, developed by the writer, disclosed that a resistivity change takes place at a teleseismic distance when an earthquake of large and medium magnitude occurs. Many of the resistivity changes thus observed are preceded by a premonitory change, which is supposed to reflect the preliminary rupture at a focal region.     

Seismic microzonation of the greater Bangkok area using microtremor observations

Bangkok, the capital city of Thailand, is located at a remote distance from seismic sources. However, it has a substantial risk from these distant earthquakes due to the ability of the underlying soft clay to amplify ground motions. It is therefore imperative to conduct a detailed seismic hazard assessment of the area. Seismic microzonation of big cities, like Bangkok, provides a basis for site‐specific hazard analysis, which can assist in systematic earthquake mitigation programs. In this study, a seismic microzonation map for the greater Bangkok area is constructed using microtremor observations. Microtremor observations were carried out at more than 150 sites in the greater Bangkok area. The predominant periods of the ground were determined from the horizontal‐to‐vertical (H/V) spectral ratio technique. A microzonation map was then developed for the greater Bangkok area based on the observations. Moreover, the transfer functions were calculated for the soil profile at eight sites, using the computer program SHAKE91, to validate the results from the microtremor analysis. The areas near the Gulf of Thailand, underlaid by a thick soft clay layer, were found to have long natural periods ranging from 0.8s to 1.2s. However, the areas outside the lower central plain have shorter predominant periods of less than 0.4s. The study shows that there is a great possibility of long‐period ground vibration in Bangkok, especially in the areas near the Gulf of Thailand. This may have severe effects on long‐period structures, such as high‐rise buildings and long‐span bridges. Copyright © 2003 John Wiley & Sons, Ltd.     

Textural analysis and flow mechanism of the Donzurubo subaqueous pyroclastic flow deposits

The Donzurubo subaqueous pyroclastic flow deposits deposited in subaqueous environments maintaining high temperatures (about 500°C). Each flow unit of these pyroclastic flow deposits shows some characteristic size distributions in its stratigraphic column. The concentration of pumice at the top clearly defines the top facies of a flow unit. Median diameter (Md Ø) and the averages of the largest ten essential dense debris increase gradually starting from both the top and the bottom of the flow unit. The maximum points of Md Ø and the averages of the largest ten essential dense debris are usually found in the middle zone of each flow unit, but the Md Ø maximum points are generally in a lower position than the averages. Mechanical analyses show that the deposits consist of polymodal populations. They show, on the whole, an asymmetrical distribution, which is mainly due to the absence of the coarser fractions of the main population. The size distribution characteristics and the C-M pattern of the deposits suggest that these subaqueous pyroclastic flow deposits were not originated by homogeneously suspended turbulent flows but by incandescent turbulent flows with layered suspension.     

Temporal variations of the winter mixed layer south of the Kuroshio Extension

A monthly mean time series of the temperature profile in the recirculation gyre south of the Kuroshio Extension has been produced for the period 1971–2007 to examine temporal variations of the winter mixed layer. The winter mixed layer depth (MLD) shows both interannual and decadal variations and is significantly correlated with variation of the mean net surface heat flux in late autumn to early winter. There is also a close relation with the strength of pre-existing subsurface stratification, measured as vertical temperature gradients in the preceding summer. Linear multiple regression analysis shows that a significant fraction of the variations in the winter MLD is explained by the surface heat flux and the strength of the stratification. The contribution of the two factors is comparable.