Stream nitrate levels in a small catchment in south west England over a period of 35 years (1970–2005)

This study considers a 35‐year record of streamwater nitrate concentration in a small agricultural catchment in south west England (Slapton Wood). The study revisits earlier work to assess whether upward trends have been maintained and how the controls upon streamwater concentration have been altered. The study has shown that (1) the catchment has reached a new position of equilibrium and increases in nitrate concentration have lessened; (2) the occurrence of severe drought in the record means that records of less than a decade are misleading and only long‐term records can illustrate changes of state; (3) the change of state observed in the catchment is illustrated in the switching of long‐term memory effects from a negative to a positive annual memory and (4) several significant long‐term impulsivity relationships with rainfall that become insignificant over the course of the study period. The study shows the importance of long‐term records in understanding changes in state in catchments and understanding the time constants of a range of driving processes. Copyright © 2009 John Wiley & Sons, Ltd.     

Carbon dioxide dynamics in rivers and coastal waters of the “big island” of Hawaii,USA, during baseline and heavy rain conditions

The distributions of the partial pressure of carbon dioxide (pCO₂) and total alkalinity (TA) were examined for a 6-month period in the Wailuku and Wailoa rivers and coastal waters of Hilo Bay on the west coast of the Island of Hawaii, USA. Main results for the largest and turbulent Wailuku River show in the watershed an oversaturation in CO₂ with respect to atmospheric equilibrium and a CO₂ undersaturation in the estuary. In the Wailoa river-estuary system, extremely high pCO₂ values ranging from 1500 to 10500 ppm were measured with significant shifts in pCO₂ from drought to flood period. In the two rivers, water residence time, groundwater inputs and occasional flood events are the predominant drivers of the spatial and temporal patterns in the distribution of pCO₂. In Hilo Bay, CO₂ oversaturation dominates and the bay was a source of CO₂ to the atmosphere during the study period. TA is conservative along the salinity gradient, indicating calcification in the bay is not a significant source of CO₂ to the atmosphere.     

The evolution of the water distribution in a viscous protoplanetary disk

Astronomical observations have shown that protoplanetary disks are dynamic objects through which mass is transported and accreted by the central star. This transport causes the disks to decrease in mass and cool over time, and such evolution is expected to have occurred in our own solar nebula. Age dating of meteorite constituents shows that their creation, evolution, and accumulation occupied several Myr, and over this time disk properties would evolve significantly. Moreover, on this timescale, solid particles decouple from the gas in the disk and their evolution follows a different path. It is in this context that we must understand how our own solar nebula evolved and what effects this evolution had on the primitive materials contained within it. Here we present a model which tracks how the distribution of water changes in an evolving disk as the water-bearing species experience condensation, accretion, transport, collisional destruction, and vaporization. Because solids are transported in a disk at different rates depending on their sizes, the motions will lead to water being concentrated in some regions of a disk and depleted in others. These enhancements and depletions are consistent with the conditions needed to explain some aspects of the chemistry of chondritic meteorites and formation of giant planets. The levels of concentration and depletion, as well as their locations, depend strongly on the combined effects of the gaseous disk evolution, the formation of rapidly migrating rubble, and the growth of immobile planetesimals. Understanding how these processes operate simultaneously is critical to developing our models for meteorite parent body formation in the Solar System and giant planet formation throughout the galaxy. We present examples of evolution under a range of plausible assumptions and demonstrate how the chemical evolution of the inner region of a protoplanetary disk is intimately connected to the physical processes which occur in the outer regions.     

Aircraft observations of Venus' near-infrared reflection spectrum: Implications for cloud composition

We have obtained measurements of Venus' reflection spectrum in the 1.2 to 4.1-μm spectral region from a NASA-Ames operated Lear jet. This was accomplished by observing both Venus and the sun with a spectrometer that contained a circular, variable interference filter, whose effective spectral resolution was 2%. The aircraft results were compared with computer generated spectra of a number of cloud candidates. The only substance which gave an acceptable match to the profile of Venus' strong 3-μm absorption feature, was a water solution of sulfuric acid, that had a concentration of 75% or more H₂SO₄ by weight. However, our spectra also show a modest decline in reflectivity from 2.3 μm towards 1.2-μm wavekength, which is inconsistent with the flat spectrum of sulfuric acid in this spectral region. We hypothesize that this decline is due to impurities in the sulfuric acid droplets.We also compared our list of cloud candidates with several other observed properties of the Venus clouds. While this comparison does not provide as unique an answer as did our analysis of the 3-μm band, we find that, in agreement with the results of Young (1973) and Sill (1973), concentrated sulfuric acid solutions are compatible with these additional observed properties of the Venus clouds. We conclude that the visible cloud layer of Venus is composed of sulfuric acid solution droplets, whose concentration is 75% H₂SO₄, or greater, by weight.     

Origin of the moon by tidal capture and some geophysical consequences

Of the many proposed modes of origin of the Moon, some violate physical laws; many are in conflict with observations; all are improbable. Perhaps the least improbable - based on recent tidal theory calculations and on the interpretation of lunar rock data - is capture of the Moon as it passed near the Earth in adirect (prograde) orbit, shortly after the formation of Moon and Earth, about 4.5 billion years ago. (Capture of the Moon from an initiallyretrograde orbit which had been proposed some years ago, leads to physically unacceptable consequences.) The effects of capture on the Earth would have been cataclysmic, leading to intensive heating of its interior, to volcanism, and to the immediate formation of an atmosphere and hydrosphere. Thus capture of a Moon may have given rise to the unique properties of the Earth (in the Solar System) and to the early evolution of life, about 3.5 billion years ago.Presented at the NATO Advanced Study Institute on Lunar Studies in Patras, Greece, September, 1971.     

Note on the number and origin of apollo asteroids

Fifteen Apollo, or Earth-crossing, asteroids are now recognized, and their orbital elements tabulated here. None has been accidentally rediscovered, a circumstance that leads to the 50% probability that the total number equals or does not exceed 100 to absolute magnitude 18, or above a diameter of roughly 1 km. Physical observations, orbital characteristics, and associated meteor streams provide clues as to whether the Apollo asteroids are truly minor planets or moribund cometary nuclei. A definitive answer as to the origin of the Apollo asteroids is yet to be found, but a short discussion of the status of the problem is presented.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April, 1973.     

Further evidence for a complex limb structure in the solar radial brightness distribution at mm wavelengths

A computer program to convolve numerically any azimuthally symmetric, solar radial brightness distribution with standard antenna patterns of small half power beamwidths has been used to find a solar brightness distribution which is a good fit to the eclipse curve obtained during the 7 March 1970 partial solar eclipse with the NRAO 36-ft antenna at 3.5 mm. This brightness distribution is compared with the brightness distribution at 3.2 mm determined by the Pennsylvania State University Radio Astronomy Observatory group during the same eclipse but observed from Mexico where totality occurred. The two brightness distributions are very similar in shape, showing a double peak near the limb, but differing slightly in the positions of the peaks.