Controls on the chemistry of runoff from an upland peat catchment

This study uses 2 years of data from a detailed weekly water sampling programme in a 11·4 km² upland peat catchment in the Northern Pennines, UK. The sampling comprised precipitation, soil‐water samples and a number of streams, including the basin outlet. Samples were analysed for: pH, conductivity, alkalinity, Na, K, Ca, Mg, Fe, Al, Total N, SO₄, Cl and colour. Principal component analysis (PCA) was used to identify end‐members and compositional trends in order to identify controls on the development of water composition. The study showed that the direct use of PCA had several advantages over the use of end‐member mixing analysis (EMMA) as it combines an analysis of mixing and evolving waters without the assumption of having to know the compositional sources of the water. In its application to an upland peat catchment, the study supports the view that shallow throughflow at the catotelm/acrotelm boundary is responsible for storm runoff generation and shows that baseflow is controlled by cation exchange in the catotelm and mixing with a base‐rich groundwater. Copyright © 2003 John Wiley & Sons, Ltd.     

The impact of wave loads and pore-water pressure generation on initiation of sediment transport

The build-up of pore-water pressure by waves can lead to sediment liquefaction and subsequent transport by traction currents. This process was investigated by measuring pore-water pressures both in a field experiment and laboratory wave tank tests. Liquefaction was observed in the wave tank tests. The results suggest that sand is less susceptible than silts to wave-induced liquefaction because of the tendency to partially dissipate pore-water pressures. However, previous studies have determined that pore-water pressures must approach liquefaction before current velocities necessary to initiate transport are reduced. Once liquefaction has occurred more sediment can be transported.     

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.     

An Attempted Explanation for the Discrepancy between Internal and External Errors in Statistical Adjustments

It is shown that underparameterization of models used in statistical adjustments is at least in part responsible for the discrepancies between so-called internal and external rms errors (standard deviations), frequently encountered in derived sets of statistical parameters.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

Principal components in active galactic nuclei variability data and the estimation of the flux contributions from different components

It has been found that the near-infrared flux variations of Seyfert galaxies satisfy relations of the form   F_i ≈α _{i j} +β _{i j} F_j   , where F_i , F_j are the fluxes in filters i and j ; and  α _{i , j} , β _{i , j}   are constants. These relations have been used to estimate the constant contributions of the non-variable underlying galaxies. The paper attempts a formal treatment of the estimation procedure, allowing for the possible presence of a third component, namely non-variable hot dust. In an analysis of a sample of 38 Seyfert galaxies, inclusion of the hot dust component improves the model fit in approximately half the cases. All derived dust temperatures are below 300 K, in the range 540–860 K or above 1300 K. A noteworthy feature is the estimation of confidence intervals for the component contributions: this is achieved by bootstrapping. It is also pointed out that the model implies that such data could be fruitfully analysed in terms of principal components.     

Generation of complete theoretical seismograms for SH—

Summary. We report the initial results of our attempts to obtain theoretical seismograms for direct comparison with the experimental time series obtained with the long-period instruments of the WWSSN. The entire theoretical seismogram, including both body waves and surface waves, can be generated for a spherical, anelastic earth by simple inverse Fourier transformation of the sum of the propagating fundamental and higher-mode surface waves. The key to success in reproducing the WWSSN records involves the number of modes, and the minimum period used in these computations; here we use eight modes and a minimum period of 2 s. Efficient computational algorithms make it possible to handle up to 2000 frequency points for each mode; approximately 200 layers are used to model the radial heterogeneity of the earth; attenuation is treated exactly. Examples are given of the SH theoretical seismograms resulting from dislocation sources buried at various depths in the Earth.