Dissociation constants of protonated methionine species in seawater media

The dissociation constants (pK₁ and pK₂) for methionine have been measured in artificial seawater as a function of salinity (S = 5 to 35) and temperature (5 to 45 °C). The seawater pK₂ values were lower than the values in NaCl at the same ionic strength while the pK₁ values in seawater were lower only at S = 35. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been used to determine the formation of Mg²⁺ complexes and Pitzer interaction parameters for Mg²⁺ with methionine. The seawater model with the interaction parameters accounts for the differences between the value of pK₁ and pK₂ between NaCl and seawater. This study demonstrates that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids.     

Crystallization of melilite from CMAS-liquids and the formation of the melilite mantle of Type B1 CAIs: Experimental simulations

Type B CAIs are subdivided into B1s, with well-developed melilite mantles, and B2s, with randomly distributed melilite. Despite intensive study, the origin of the characteristic melilite mantle of the B1s remains unclear. Recently, we proposed that formation of the melilite mantle is caused by depletion of the droplet surface in volatile magnesium and silicon due to higher evaporation rates of volatile species compared to their slow diffusion rates in the melt, thus making possible crystallization of melilite at the edge of the CAI first, followed by its crystallization in the central parts at lower temperatures. Here, we present the results of an experimental study that aimed to reproduce the texture observed in natural Type B CAIs. First, we experimentally determined crystallization temperatures of melilite for three melt compositions, which, combined with literature data, allowed us to find a simple relationship between the melt composition, crystallization temperature, and composition of first crystallizing melilite. Second, we conducted a series of evaporation and cooling experiments exposing CAI-like melts to gas mixtures with different oxygen fugacities (f_O2). Cooling of the molten droplets in gases with logf_O2?IW-4 resulted in crystallization of randomly distributed melilite, while under more reducing conditions, melilite mantles have been formed. Chemical profiles through samples quenched right before melilite started to crystallize showed no chemical gradients in samples exposed to relatively oxidizing gases (logf_O2?IW-4), while the near-surface parts of the samples exposed to very reducing gases (logf_O2?IW-7) were depleted in volatile MgO and SiO₂, and enriched in refractory Al₂O₃. Using these experimental results and the fact that the evaporation rate of magnesium and silicon from CAI-like melts is proportional to , we estimate that Type B1 CAIs could be formed by evaporation of a partially molten precursor in a gas of solar composition with . Type B2 CAIs could form by slower evaporation of the same precursors in the same gas with .     

Kinetic isotopic fractionation during diffusion of ionic species in water

Experiments specifically designed to measure the ratio of the diffusivities of ions dissolved in water were used to determine . The measured ratio of the diffusion coefficients for Li and K in water (D_Li/D_K = 0.6) is in good agreement with published data, providing evidence that the experimental design being used resolves the relative mobility of ions with adequate precision to also be used for determining the fractionation of isotopes by diffusion in water. In the case of Li, we found measurable isotopic fractionation associated with the diffusion of dissolved LiCl (D_⁷Li/D_⁶Li=0.99772±0.00026). This difference in the diffusion coefficient of ⁷Li compared to ⁶Li is significantly less than that reported in an earlier study, a difference we attribute to the fact that in the earlier study Li diffused through a membrane separating the water reservoirs. Our experiments involving Mg diffusing in water found no measurable isotopic fractionation (D_²⁵Mg/D_²⁴Mg=1.00003±0.00006). Cl isotopes were fractionated during diffusion in water (D_³⁷Cl/D_³⁵Cl=0.99857±0.00080) whether or not the co-diffuser (Li or Mg) was isotopically fractionated. The isotopic fractionation associated with the diffusion of ions in water is much smaller than values we found previously for the isotopic fractionation of Li and Ca isotopes by diffusion in molten silicate liquids. A major distinction between water and silicate liquids is that water surrounds dissolved ions with hydration shells, which very likely play an important but still poorly understood role in limiting the isotopic fractionation associated with diffusion.     

Assessing the effects of Irgarol 1051 on marine phytoplankton populations in Key Largo Harbor, Florida

The antifouling boosting agent Irgarol 1051 is a strong inhibitor of the photosystem II (PSII) with high efficiency/toxicity towards algae. However, because some phytoplankton species are more sensitive to Irgarol than others, its persistent release into the environment could result in adverse changes in the phytoplankton community structure at heavily impacted sites such as marinas. Continuous monitoring in the Florida Keys showed Irgarol concentrations of up to 635 ngL(-1) in the canal system leading to Key Largo Harbor Marina (KLH) with a sharp decrease in concentration at stations offshore from the mouth of the canal. Preliminary phytoplankton community assessments from surface water samples collected in KLH between February and August 2004 showed changes in several phytoplankton species in concordance with the increase of the herbicide concentrations. Typical responses include an increase in the abundance of eukaryotes and Cryptomonas sp. as Irgarol concentrations increase.     

Submillimeter Wave Astronomy Satellite observations of Comet 9P/Tempel 1 and Deep Impact

On 4 July 2005 at 5:52 UT the Deep Impact mission successfully completed its goal to hit the nucleus of 9P/Tempel 1 with an impactor, forming a crater on the nucleus and ejecting material into the coma of the comet. NASA's Submillimeter Wave Astronomy Satellite (SWAS) observed the ₁₁₀-₁₀₁ ortho-water ground-state rotational transition in Comet 9P/Tempel 1 before, during, and after the impact. No excess emission from the impact was detected by SWAS and we derive an upper limit of 1.8×¹⁰⁷ kg on the water ice evaporated by the impact. However, the water production rate of the comet showed large natural variations of more than a factor of three during the weeks before and after the impact. Episodes of increased activity with alternated with periods with low outgassing (). We estimate that 9P/Tempel 1 vaporized a total of N∼4.5×¹⁰³⁴ water molecules (∼1.3×¹⁰⁹ kg) during June-September 2005. Our observations indicate that only a small fraction of the nucleus of Tempel 1 appears to be covered with active areas. Water vapor is expected to emanate predominantly from topographic features periodically facing the Sun as the comet rotates. We calculate that appreciable asymmetries of these features could lead to a spin-down or spin-up of the nucleus at observable rates.     

Mesoscale raised rim depressions (MRRDs) on Earth: A review of the characteristics,processes, and spatial distributions of analogs for Mars

Fields of mesoscale raised rim depressions (MRRDs) of various origins are found on Earth and Mars. Examples include rootless cones, mud volcanoes, collapsed pingos, rimmed kettle holes, and basaltic ring structures. Correct identification of MRRDs on Mars is valuable because different MRRD types have different geologic and/or climatic implications and are often associated with volcanism and/or water, which may provide locales for biotic or prebiotic activity. In order to facilitate correct identification of fields of MRRDs on Mars and their implications, this work provides a review of common terrestrial MRRD types that occur in fields. In this review, MRRDs by formation mechanism, including hydrovolcanic (phreatomagmatic cones, basaltic ring structures), sedimentological (mud volcanoes), and ice-related (pingos, volatile ice-block forms) mechanisms. For each broad mechanism, we present a comparative synopsis of (i) morphology and observations, (ii) physical formation processes, and (iii) published hypothesized locations on Mars. Because the morphology for MRRDs may be ambiguous, an additional tool is provided for distinguishing fields of MRRDs by origin on Mars, namely, spatial distribution analyses for MRRDs within fields on Earth. We find that MRRDs have both distinguishing and similar characteristics, and observation that applies both to their mesoscale morphology and to their spatial distribution statistics. Thus, this review provides tools for distinguishing between various MRRDs, while highlighting the utility of the multiple working hypotheses approach.     

Superorbital variability in hard X-rays

We present the results of a study with the Swift Burst Alert Telescope in the 14–195 keV range of the long-term variability of five low-mass X-ray binaries with reported or suspected superorbital periods – 4U 1636−536, 4U 1820−303, 4U 1916−053, Cyg X-2 and Sco X-1. No significant persistent periodic modulation was detected around the previously reported periods in the 4U 1916−053, Cyg X-2 or Sco X-1 light curves. The ∼170-d period of 4U 1820−303 was detected up to 24 keV, consistent with variable accretion due to the previously proposed triple system model. The ∼46-d period in 4U 1636−536 was detected up to 100 keV, with the modulation in the low- and high-energy bands found to be phase shifted by ∼180° with respect to each other. This phase shift, when taken together with the near-coincident onset of the ∼46-d modulation and the low/hard X-ray state, leads us to speculate that the modulation could herald transient jet formation.     

Satellite kinematics – II. The halo mass–luminosity relation of central galaxies in SDSS

The kinematics of satellite galaxies reflect the masses of the extended dark matter haloes in which they orbit, and thus shed light on the mass–luminosity relation (MLR) of their corresponding central galaxies. In this paper, we select a large sample of centrals and satellites from the Sloan Digital Sky Survey and measure the kinematics (velocity dispersions) of the satellite galaxies as a function of the r -band luminosity of the central galaxies. Using the analytical framework presented in More, van den Bosch & Cacciato, we use these data to infer both the mean and the scatter of the MLR of central galaxies, carefully taking account of selection effects and biases introduced by the stacking procedure. As expected, brighter centrals on average reside in more massive haloes. In addition, we find that the scatter in halo masses for centrals of a given luminosity,  σ_{log  M}   , also increases with increasing luminosity. As we demonstrate, this is consistent with  σ_{log  L}   , which reflects the scatter in the conditional probability function   P ( L _c| M )  , being independent of halo mass. Our analysis of the satellite kinematics yields  σ_{log  L} = 0.16  ±  0.04  , in excellent agreement with constraints from clustering and group catalogues, and with predictions from a semi-analytical model of galaxy formation. We thus conclude that the amount of stochasticity in galaxy formation, which is characterized by  σ_{log  L}   , is well constrained, independent of halo mass and in a good agreement with current models of galaxy formation.     

The correlation of star formation quenching with internal galaxy properties and environment

We investigate the correlation of star formation quenching with internal galaxy properties and large-scale environment (halo mass) in empirical data and theoretical models. We make use of the halo-based group catalogue of Yang and collaborators, which is based on the Sloan Digital Sky Survey. Data from the Galaxy evolution explorer are also used to extract the recent star formation rate. In order to investigate the environmental effects, we examine the properties of 'central' and 'satellite' galaxies separately. For central galaxies, we are unable to conclude whether star formation quenching is primarily connected with halo mass or stellar mass, because these two quantities are themselves strongly correlated. For satellite galaxies, a nearly equally strong dependence on halo mass and stellar mass is seen. We make the same comparison for five different semi-analytic models based on three independently developed codes. We find that the models with active galactic nuclei feedback reproduce reasonably well the dependence of the fraction of central red and passive galaxies on halo mass and stellar mass. However, for satellite galaxies, the same models badly overproduce the fraction of red/passive galaxies and do not reproduce the empirical trends with stellar mass or halo mass. This satellite overquenching problem is caused by the too-rapid stripping of the satellites' hot gas haloes, which leads to rapid strangulation of star formation.