Substorm observations in the early morning sector with Equator-S and Geotail

Data from Equator-S and Geotail are used to study the dynamics of the plasma sheet observed during a substorm with multiple intensifications on 25 April 1998, when both spacecraft were located in the early morning sector (03–04 MLT) at a radial distance of 10–11 R_E. In association with the onset of a poleward expansion of the aurora and the westward electrojet in the premidnight and midnight sector, both satellites in the morning sector observed plasma sheet thinning and changes toward a more tail-like field configuration. During the subsequent poleward expansion in a wider local time sector (20−04 MLT), on the other hand, the magnetic field configuration at both satellites changed into a more dipolar configuration and both satellites encountered again the hot plasma sheet. High-speed plasma flows with velocities of up to 600 km/s and lasting 2–5 min were observed in the plasma sheet and near its boundary during this plasma sheet expansion. These high-speed flows included significant dawn-dusk flows and had a shear structure. They may have been produced by an induced electric field at the local dipolarization region and/or by an enhanced pressure gradient associated with the injection in the midnight plasma sheet.     

Embryo dune development drivers: beach morphology,growing season precipitation,and storms

For development of embryo dunes on the highly dynamic land–sea boundary, summer growth and the absence of winter erosion are essential. Other than that, however, we know little about the specific conditions that favour embryo dune development. This study explores the boundary conditions for early dune development to enable better predictions of natural dune expansion. Using a 30 year time series of aerial photographs of 33 sites along the Dutch coast, we assessed the influence of beach morphology (beach width and tidal range), meteorological conditions (storm characteristics, wind speed, growing season precipitation, and temperature), and sand nourishment on early dune development. We examined the presence and area of embryo dunes in relation to beach width and tidal range, and compared changes in embryo dune area to meteorological conditions and whether sand nourishment had been applied. We found that the presence and area of embryo dunes increased with increasing beach width. Over time, embryo dune area was negatively correlated with storm intensity and frequency. Embryo dune area was positively correlated with precipitation in the growing season and sand nourishment. Embryo dune area increased in periods of low storm frequency and in wet summers, and decreased in periods of high storm frequency or intensity. We conclude that beach morphology is highly influential in determining the potential for new dune development, and wide beaches enable development of larger embryo dune fields. Sand nourishment stimulates dune development by increasing beach width. Finally, weather conditions and non‐interrupted sequences of years without high‐intensity storms determine whether progressive dune development will take place. Copyright © 2017 John Wiley & Sons, Ltd.     

Late Pleistocene outburst floods from Issyk Kul,Kyrgyzstan?

Elevated shorelines and lake sediments surrounding Issyk Kul, the world's second largest mountain lake, record fluctuating lake levels during Quaternary times. Together with bathymetric and geochemical data, these markers document alternating phases of lake closure and external drainage. The uppermost level of lake sediments requires a former damming of the lake's western outlet through the Boam gorge. We test previous hypothesised ice or landslide dam failures by exploring possible links between late Quaternary lake levels and outbursts. We review and recompile the chronology of reported changes in lake site, and offer new ages of abandoned shorelines using ¹⁴C in bivalve and gastropod shells, and plant detritus, as well as sand lenses in delta and river sediments using Infrared Stimulated Luminescence. Our dates are consistent with elevated lake levels between ~45 ka and 22 ka. Cosmogenic ¹⁰Be and ²⁶Al exposure ages of fan terraces containing erratic boulders (>3 m) downstream of the gorge constrain the timing of floods to 20.5–18.5 ka, postdating a highstand of Issyk Kul. A flow‐competence analysis gives a peak discharge of >10⁴ m³ s^–1 for entraining and transporting these boulders. Palaeoflood modelling, however, shows that naturally dammed lakes unconnected to Issyk Kul could have produced such high discharges upon sudden emptying. Hence, although our data are consistent with hypotheses of catastrophic outburst floods, average lake‐level changes of up to 90 mm yr^–1 in the past 150 years were highly variable without any outbursts, so that linking lake‐level drops to catastrophic dam breaks remains ambiguous using sedimentary archives alone. This constraint may readily apply to other Quaternary lakes of that size elsewhere. Nonetheless, our reconstructed Pleistocene floods are among the largest reported worldwide, and motivate further research into the palaeoflood hydrology of Central Asia. Copyright © 2017 John Wiley & Sons, Ltd.     

Strömgren CCD photometry of Globular Clusters

We present results from Strömgren uvby photometry forthe globular clusters M3 and M13, obtained from the Nordic Optical Telescope and the Danish 1.54 m telescope on La Silla obtained as part ofa larger program to investigate cluster ages.     

Dating lava flows of tropical volcanoes by means of spatial modeling of vegetation recovery

The age of past lava flows is crucial information for evaluating the hazards and risks posed by effusive volcanoes, but traditional dating methods are expensive and time‐consuming. This study proposes an alternative statistical dating method based on remote sensing observations of tropical volcanoes by exploiting the relationship between lava flow age and vegetation cover. First, the factors controlling vegetation density on lava flows, represented by the normalized difference vegetation index (NDVI), were investigated. These factors were then integrated into pixel‐based multi‐variable regression models of lava flow age to derive lava flow age maps. The method was tested at a pixel scale on three tropical African volcanoes with considerable recent effusive activity: Nyamuragira (Democratic Republic of Congo), Mt Cameroon (Cameroon) and Karthala (the Comoros). Due to different climatic and topographic conditions, the parameters of the spatial modeling are volcano‐specific. Validation suggests that the obtained statistical models are robust and can thus be applied for estimating the age of unmodified undated lava flow surfaces for these volcanoes. When the models are applied to fully vegetated lava flows, the results should be interpreted with caution due to the saturation of NDVI. In order to improve the accuracy of the models, when available, spatial data on temperature and precipitation should be included to directly represent climatic variation. Copyright © 2017 John Wiley & Sons, Ltd.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.     

Generalization of total least-squares on example of unweighted and weighted 2D similarity transformation

In this contribution it is shown that the so-called “total least-squares estimate” (TLS) within an errors-in-variables (EIV) model can be identified as a special case of the method of least-squares within the nonlinear Gauss–Helmert model. In contrast to the EIV-model, the nonlinear GH-model does not impose any restrictions on the form of functional relationship between the quantities involved in the model. Even more complex EIV-models, which require specific approaches like “generalized total least-squares” (GTLS) or “structured total least-squares” (STLS), can be treated as nonlinear GH-models without any serious problems. The example of a similarity transformation of planar coordinates shows that the “total least-squares solution” can be obtained easily from a rigorous evaluation of the Gauss–Helmert model. In contrast to weighted TLS, weights can then be introduced without further limitations. Using two numerical examples taken from the literature, these solutions are compared with those obtained from certain specialized TLS approaches.     

Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

Tidal response to sea level rise and bathymetric changes in the German Wadden Sea

Ocean Dynamics - Tidally dominated coasts are directly affected not only by projected rise in mean sea level, but also by changes in tidal dynamics due to sea level rise and bathymetric changes. By...     

Analysis of noble gases in water using a quadrupole mass spectrometer in static mode

A quadrupole-based mass spectrometer used in static mode has been employed to determine noble gas concentrations of water samples by isotope dilution. Water samples are degassed and spiked with minor isotopes of each noble gas. After separation of the various gas components, the isotopic ratios are measured in the mass spectrometer. Because a spike is added to each sample, the recovery of each gas component does not have to be quantitative. Equilibration temperatures are calculated from the gas concentrations, based on noble gas solubility data. An accuracy of ±1°C, from the air equilibration temperature, is attainable for air-saturated water samples prepared under controlled conditions in the laboratory. The method has been applied to groundwaters from the London Basin Chalk aquifer. The noble-gas-derived temperatures are consistent with climatic conditions prevailing at the periods of recharge.