Paleozoic evolution of continental crust in the Beaujolais-Lyonnais area,northeastern part of the Massif Central,France

In the Beaujolais-Lyonnais area of the northeastern Massif Central accretion of continental and possibly oceanic crustal fragments occurred between Cambrian (?) and early Carboniferous time. Three distinct lithotectonic units (terranes?) have been recognized. The southern (Lyonnais-) Unit consists of medium- to high-grade metamorphics and includes eclogites; it formed in the early Paleozoic. The Brévenne-Unit to the north contains low- to medium-grade metamorphic mafic and felsic volcanics and subordinate sedimentary rocks which possibly originated during the early Paleozoic until Devonian time, in a sialic back-arc environment or along an active continental margin. The Beaujolais-Unit is represented by volcanics on the south and predominantly shallow marine clastics and carbonates on the north. It developed in a late Devonian or early Carboniferous ensialic marginal basin. The peak of metamorphism in the Lyonnais-unit (HP/HT) was reached in Silurian time. Subsequent NW-SE to E-W oriented convergence produced mylonitic foliation, structural imbrication of the Lyonnais basement rocks with the Brévenne-Unit and SE-vergent folds accompanied by low- to medium-grade metamorphism. Late Visean to Namurian N-S to NW-SE directed N-vergent thrusting produced tectonic imbrication of the metamorphic northern Brévenne-Unit with the nonmetamorphic Beaujolais-Unit. In the southern Brévenne-Unit and in the Lyonnais-Unit updoming along right-lateral high-angle normal faults was followed by emplacement of voluminous granitic plutons of crustal origin. Late Carboniferous to early Permian crustal thinning in the Beaujolais-Lyonnais area was associated with N-S trending left-lateral strike-slip faults and E-W to NE-SW trending right-lateral strike-slip faults. Basins that developed along these faults contain continental red beds.     

The Permian-Triassic boundary event: a geochemical study of three Chinese sections

Trace elements were determined in two well-documented Chinese Permian-Triassic (P/Tr) boundary sections (Meishan and Shangsi) and in a new section (Liangfenya). Iridium concentrations range from 3 to 87 pg/g, at or below levels in common sedimentary rocks. The results contrast with previous reports of high Ir concentration in the Meishan and Shangsi sections and offer no support to suggestions of a major meteoroid impact at the end of the Permian. A notable feature in each of these widely separated P/Tr sections (500–1500 km) is the existence of 2–5 light-colored clay layers at and near the boundary. These clay layers are strongly enriched in Cs, Zr, Hf, Ta, and Th and depleted in Cr, Co, and Ir, indicating that they are altered ash, apparently from the same massive silicic volcanic eruptions. We estimate the magnitude of these eruptions to be a few thousand km³ of magma, a volume comparable to the great Toba eruption.     

Numerical models for diagenesis and the Neogene Sr isotopic evolution of seawater from DSDP Site 590B

A numerical model for the diagenetic exchange of Sr between carbonates and their pore fluids during sedimentation and compaction has been developed. The model has been applied to data from DSDP Site 590B in order to assess the accuracy with which the Sr isotope record in the carbonate sediment reflects that of seawater. The most important process affecting the Sr in the solid carbonate is exchange with the pore fluid due to solution-reprecipitation, but the concentration or isotopic composition of Sr in the solid itself gives little or no information as to the magnitude of this exchange. The key to determining the rate of exchange is the pore fluid, where the variations of Sr²⁺ and⁸⁷Sr/⁸⁶Sr with depth are very sensitive indicators. The logical structure of applying the model to data from DSDP 590B is to find by successive iteration an ocean history (i.e., the initial⁸⁷Sr/⁸⁶Sr and Sr concentration of each increment of carbonate deposited) and a rate of Sr exchange between pore water and solid carbonate such that the model matches the present Sr concentration and⁸⁷Sr/⁸⁶Sr of both pore water and solid carbonate.Once all the data are matched, the model provides an estimate of the rate of Sr exchange due to solution-reprecipitation and the evolution of⁸⁷Sr/⁸⁶Sr in seawater over the past 20 million years. For DSDP 590B we find that solution-reprecipitation decreases rapidly with depth, from a near surface value of about 10% per million years to about 1% per million years below 200 m. This rate of exchange of Sr results in the carbonates of DSDP 590B preserving an accurate record of the Sr isotopic evolution of the ocean over the past 5 million years, but for ages greater than 5 million years the⁸⁷Sr/⁸⁶Sr ratio of the carbonate is systematically displaced from that of the seawater in which it was deposited. The maximum difference is of order 5 × 10⁻⁵.     

Approaches to dynamic equilibrium in theoretical simulations of slope development

The model SLOP3D is used to identify characteristic aspects of slope development under different conditions. A series of slopes along the Kall valley in the northern Eifel is reproduced by a developmental sequence of model slopes. The spatial and temporal variations of the components of slope development systems (relief, slope form, weathering rates, denudation rates) are discussed by means of mass movement and wash denudation models. The negative feedbacks between system components create a tendency towards the establishment of a dynamic equilibrium which is reached, however, only if the endogenic and exogenic conditions remain constant for the required relaxation time. The latter is shown to be a function of slope length, of the rate of uplift, of the denudational process type, and of the intensity of exogenic inputs (e.g. precipitation). Varying rock resistance leads to the development of shield inselbergs only if the rate of denudation becomes higher than the maximum possible weathering rate of the resistant bedrock.     

Simple models for trace element fractionation during melt segregation

A dynamical calculation for melt segregation from a deformable matrix is used as a framework for studying chemical fractionation during melting and melt migration. The chemical aspects of the problem are modelled in terms of modal melting and local diffusive equilibrium, allowing for the use of unchanging distribution coefficients. The chemical properties of the melt segregated is a synthetic data set that is used to test how well simple equations for perfect equilibrium partial melt and perfect fractional partial melt recover the actual degree of melting and original source composition. The general conclusion is that either equation does quite well (to within a factor generally less than 2) even when the physical situation is quite different from that required for deriving these simple relations between degree of melting, distribution coefficient and magma composition. In terms of the apparent source composition as inferred from the properties of the segregated melt, the typical result is to find a source enriched in the more incompatible elements, which could easily be misinterpreted as requiring metasomatic alteration.     

The Grüneisen parameter at high pressure: a molecular dynamical study

The method of molecular dynamics is used to calculate values for the thermal Grüneisen parameter, γ, for a face-centred cubic crystal with several simple central force atomic potential functions at three compressions for comparison with free volume and acoustic γ formulations. Neither is found to agree with the computer experiments. A defect in the free-volume formula for γ is shown to arise from the assumption that motions of neighbouring atoms in a crystal at high temperature are uncorrelated whereas the computer models demonstrate a 25–35% correlation of in-line motions and 5% correlation of transverse motions. The formula can be modified to allow for the empirically observed correlations, but it is concluded that there are still difficulties in analytical approaches to equation-of-state studies of the Earth's deep interior and that the computer modelling method of molecular dynamics has important advantages.