Petrology of lavas from the Puu Oo eruption of Kilauea Volcano: III. The Kupaianaha episode (1986–1992)

 The Puu Oo eruption has been remarkable in the historical record of Kilauea Volcano for its duration (over 13 years), volume (>1 km³) and compositional variation (5.7–10 wt.% MgO). During the summer of 1986, the main vent for lava production moved 3 km down the east rift zone and the eruption style changed from episodic geyser-like fountaining at Puu Oo to virtually continuous, relatively quiescent effusion at the Kupaianaha vent. This paper examines this next chapter in the Puu Oo eruption, episodes 48 and 49, and presents new ICP-MS trace element and Pb-, Sr-, and Nd-isotope data for the entire eruption (1983–1994). Nearly aphyric to weakly olivine-phyric lavas were erupted during episodes 48 and 49. The variation in MgO content of Kupaianaha lavas erupted before 1990 correlates with changes in tilt at the summit of Kilauea, both of which probably were controlled by variations in Kilauea's magma supply rate. These lavas contain euhedral olivines which generally are in equilibrium with whole-rock compositions, although some of the more mafic lavas which erupted during 1990, a period of frequent pauses in the eruption, accumulated 2–4 vol.% olivine. The highest forsterite content of olivines (∼85%) in Kupaianaha lavas indicates that the parental magmas for these lavas had MgO contents of ∼10 wt.%, which equals the highest observed value for lavas during this eruption. The composition of the Puu Oo lavas has progressively changed during the eruption. Since early 1985 (episode 30), when mixing between an evolved rift zone magma and a more mafic summit reservoir-derived magma ended, the normalized (to 10 wt.% MgO) abundances of highly incompatible elements and CaO have systematically decreased with time, whereas ratios of these trace elements and Pb, Sr, and Nd isotopes, and the abundances of Y and Yb, have remained relatively unchanged. These results indicate that the Hawaiian plume source for Puu Oo magmas must be relatively homogeneous on a scale of 10–20 km³ (assuming 5–10% partial melting), and that localized melting within the plume has apparently progressively depleted its incompatible elements and clinopyroxene component as the eruption continued. The rate of variation of highly incompatible elements in Puu Oo lavas is much greater than that observed for Kilauea historical summit lavas (e.g., Ba/Y 0.09 a^–1 vs ∼0.03 a^–1). This rapid change indicates that Puu Oo magmas did not mix thoroughly with magma in the summit reservoir. Thus, except for variable amounts of olivine fractionation, the geochemical variation in these lavas is predominantly controlled by mantle processes. Received: 8 March 1996 / Accepted: 30 April 1996     

Electromagnetic mapping of electrical conductivity beneath the Columbia basalts1

Sedimentary rocks beneath the Columbia River Basalt Group are recognized as having potential for oil and gas production, but the overlying layered basalts effectively mask seismic reflections from the underlying sediments. Four electromagnetic (EM) methods have been applied on profiles crossing Boylston Ridge, a typical east–west trending anticline of the Yakima Fold Belt, in an attempt to map the resistivity interface between the basalts and the sediments and to map variations in structure and resistivity within the sediments. The EM surveys detected strong variations in resistivity within the basalts, and in particular the continuous magnetotelluric array profiling (EMAP) revealed resistivity lows beneath the surface anticlines. These low resistivity zones probably coincide with fracturing in the core of the anticlines and they appear to correlate well with similar zones of low seismic velocity observed on a nearby seismic profile. The controlled-source EM surveys (in-loop transient, long-offset transient, and variable-offset frequency-domain) were designed in anticipation of relatively uniform high resistivity basalts, and were found to have been seriously distorted by the intrabasalt conductors discovered in the field. In particular, the resistivity sections derived from 1D inversions were found to be inconsistent and misleading. The EMAP survey provided the most information about the subsurface resistivity distribution, and was certainly the most cost-effective. However, both controlled-source and EMAP surveys call for accurate 2D or 3D inversion to accommodate the geological objectives of this project.     

Late Quaternary sediment dating and quantification of lateral sediment redistribution applying230Thex: a study from the eastern Atlantic sector of the Southern Ocean

High-resolution records of the natural radionuclide²³⁰Th were measured in sediments from the eastern Atlantic sector of the Antarctic circumpolar current to obtain a detailed reconstruction of the sedimentation history of this key area for global climate change during the late Quaternary. High-resolution dating rests on the assumption that the²³⁰Th_ex flux to the sediments is constant. Short periods of drastically increased sediment accumulation rates (up to a factor of 8) were determined in the sediments of the Antarctic zone during the climate optima at the beginning of the Holocene and the isotope stage 5e. By comparing expected and measured accumulation rate of²³⁰Th_ex, lateral sediment redistribution was quantified and vertical particle rain rates originating from the surface water above were calculated. We show that lateral contributions locally were up to 6.5 times higher than the vertical particle rain rates. At other locations only 15% of the expected vertical particle rain rate were deposited.     

Stress orientations found in north-east Germany differ from the West European trend

Knowledge about the acting stresses is of crucial importance for understanding the tectonics of a region. Data about the stress field in north-eastern Germany used to be very rare. In general, it was assumed that the orientation of the larger horizontal principal stress (S_H) is similar to that found for western Germany and central West-Europe, i.e. NW–SE. To check this, several borehole logs of the late 1980s were analysed for information on the principal horizontal stress orientations: they include Four-Arm-Dipmeter and borehole televiewer data from 15 boreholes. The depth range of our stress results reaches from 1500 to 6700 m. They were compared to a few other data, especially from hydraulic fracturing, and to recent findings on the stresses in the Northwest German basin. In contrast to expectation, S_H derived from breakout orientations below the salt layers displayed N to NE orientation. The latter was found at 10 locations spread over the NE-German basin from Berlin to the Baltic sea, from the Polish border to the former border between East and West Germany. Moreover, this stress rotation in the subsaline formations seems to be the continuation of a trend found in the NW German basin.     

A structural phase-transition in K(Mg1−xCux)F3 perovskite

A complete solid-solution series between cubic (Pm 3 m) KMgF₃ and tetragonal (I4/mcm) KCuF₃ was synthesized at 730–735 °C in an inert atmosphere. X-ray powder-diffraction at room temperature shows that the transition between the cubic and tetragonal perovskite structures in the series K (Mg_1?xCu_x) F₃ occurs at x ～ 0.6. Rietveld structure-refinements were done for selected compositions. In the cubic phase, all parameters are linear with composition up to the transition point. At the transition point, there is a strong discontinuity in the cell volume; this is strongly anisotropic with expansion along the a axes and contraction along the c axis due to a pronounced axial elongation of the (Mg, Cu) F₆ octahedron that increases with increasing Cu content. The phase transition is first-order, with a discontinuity of ≈2% in the symmetry-breaking strain at x_C. It is proposed that the phase transition in K (Mg, Cu) F₃ is due to the onset of the cooperative Jahn-Teller effect. Compositional relationships for lattice vibrations in this solid solution were established using thin-film infrared spectroscopy. A phase transition occurring above 60 mole % KCuF₃ is indicated by the appearance of one of the two modes expected for the tetragonal phase; the weaker mode is not resolved below 80 mole % KCuF₃. Modes common to both structures vary smoothly and continuously across the binary; however, frequencies do not depend linearly on composition, nor is mode-softening discernable. Two-mode behaviour is observed only for the bending motion of the cubic phase, because this peak alone has non-overlapping end-member components.     

On wind shear at fronts and inversions

Summary In the past, experimental investigations as well as theoretical considerations have shown that within fronts and inversions wind shear and vertical temperature gradient adjust in such a way that the Richardson number is at its critical value. Results from aircraft measurements now suggest that the shear within moving cold fronts, warm fronts and inversions shows different behaviour because of the different mechanisms controlling the Richardson numbers. This leads to higher Richardson numbers, and therefore to lower amounts of wind shear within moving cold fronts when compared to warm fronts and inversions.With 9 Figures     

Evolving planning systems in Madrid,Rome, and Athens

Although possessing ancient and distinguished histories, the recent urbanization and planning approaches of Madrid, Rome and Athens are relatively unknown to English-speaking planners and urban geographers. This paper reviews the development of each city from the mid-19th century to the present. Special attention is given to the planning instruments developed in each city to guide growth. Each city experienced rapid growth over the past century because of its capital city functions. As a result of strong growth pressures, city planning policies were frequently subverted by private sector interests. Only in the latter part of the 20th century have planning measures become effective in controlling and directing urban growth.     

Dielectric anisotropy as a petrofabric indicator

A sensitive instrument for measurement of the angular dependence of dielectric constant in a rotating rock specimen is described and the precautions necessary to obtain meaningful results are summarized. An important problem is the choice of length/diameter ratio for cylindrical specimens, so that complete three-dimensional information can be obtained from a single specimen; this ratio averages 0.86, but is found to be a function of dielectric constant and of electrode geometry. The measurements reported here have been concerned with weakly anisotropic rocks which lack visible fabrics, especially sandstones and basalts. A sandstone was used in a study of the statistical “noise” or scatter in anisotropy axes of a set of 52 similar specimens. The anisotropy was found to be much greater than expected from the finite numbers of grains in a sample. It is concluded that, in spite of careful drying of specimens, the anisotropy is dominated by thin grain coatings which have very high dielectric constants or may even be conducting. A basalt has been found in which the dielectric and magnetic anisotropies have different axes, apparently reflecting different grain alignment events in the history of the rock. However, this is the only example that has been found in which all of the information obtainable from dielectric anisotropy could not have been obtained more easily from magnetic anisotropy.     

The use of the specific interaction model to estimate the partial molal volumes of electrolytes in seawater

The specific interaction model has been used to determine the partial molal volume of electrolytes in 0.725 m NaCl and 35‰ salinity seawater solutions at 25°C. The partial molal volumes of electrolytes (MX) were estimated at a given ionic strength (I) from

$\text{V}\text{(}\text{MX}\text{) =}\text{V}{}^0\text{(}\text{MX}\text{) +}\text{S}{}_{\mathrm{v}}\text{I}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(1 + I}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}\text{+ v}{}_{\mathrm{M}}\text{∑}\text{X}\text{B}{}_{\mathrm{<mtext>MX</mtext>}}\text{[X] + v}{}_{\mathrm{X}}\text{∑}\text{M}\text{B}{}_{\mathrm{<mtext>MX</mtext>}}\text{[X]}$

, where S_V is the Debye-Hückel limiting law slope, v_i is the number of ions i formed when MX dissociated, [i] is the total molality of ion i and B_MX is a specific interaction parameter that varies slowly with ionic strength. The values of $\text{V}\text{(}\text{MX}\text{)}$ estimated by using this equation were found to agree very well with experimental values in NaCl and seawater providing there are not strong interactions between M and X. For electrolytes that form ion pairs (i.e. MX°) corrections must be made. Methods are discussed for making these corrections.