The Hellenic ophiolites: eastward or westward obduction of the Maliac Ocean, a discussion

Ophiolitic bodies in the Dinaro-Hellenic mountain belt are among the most important ones in the Peri-Mediterranean Alpine chains. The characteristic feature of this ophiolitic belt is its Middle to Late Jurassic age of obduction. The ophiolitic bodies form two major belts on each side of the Pelagonian zone: an east Pelagonian belt in the Vardarian domain and a Supra-Pelagonian ophiolitic belt (SPO) to the west. The different hypotheses relative to the origin of the SPO present geodynamic evolution models accounting for most of the available data: a mid-Triassic episode of rifting; a Ladinian–Jurassic episode of sea-floor spreading forming notably the Maliac Ocean; a Middle to Late Jurassic convergent period with subduction and obduction episodes, and finally, a late episode of Tertiary compressional deformation responsible for the westward thrusting of the Jurassic ophiolitic nappes over the external zones. Despite many studies dating from the early 1970s, the eastern or western Pelagonian origin of these ophiolites, especially the SPO, is still under dispute. Whatever the adopted hypothesis, we consider that the main SPO bodies (N-Pindos, Vourinos, Othris, Evia, Argolis) have the same origin because of their geographic continuity and of the similarities in their geological characteristics. We propose that this ocean corresponds everywhere to the Maliac Ocean, defined in Othris from the well-preserved sedimentary (oceanic margin) and ophiolitic nappes thrust during the Late Jurassic obduction onto the Pelagonian platform. There is strong evidence for the existence of two deep basins on both sides of the Pelagonian continental ridge during Triassic–Jurassic times. They correspond, respectively, to the Vardar area to the east and the Pindos domain to the west, one of these domains being at the origin of the SPO. The hypothesis of an eastward emplacement of the SPO from the Pindos domain is based mainly on sedimentological data from the margin series and on structural analyses of ophiolitic bodies. However, we conclude the westward obduction of the Maliac Ocean, originating from the Vardar area, to be the best fitting model. This westward model is supported by paleogeographic and structural constraints on regional scale. Notably, the absence of obducted ophiolites in the Jurassic series of the Koziakas units (units attributed to the western Pelagonian margin) and of the Parnassus domain (on the eastern side of the Pindos basin) is difficult to reconcile with an eastward obduction from the Pindos domain. Other observations, such as the distribution of ophiolitic detritus in the internal and external zones, also promote the westward Late Jurassic obduction of the Maliac Ocean. Our preferred model offers a consistent explanation for the mechanism and timing of the emplacement of the SPO, as well as providing insight on the origin and emplacement of the Vardarian ophiolites. Following this hypothesis, there is no need for a clear boundary between the SPO and the west Vardarian ophiolitic bodies as they were obducted from the same oceanic basin and during the same Jurassic tectonic event. In this paper, we develop evidence in favor of the eastern Pelagonian origin for the SPO (our adopted model) and provide discussion on the data supporting the main alternative hypothesis (western origin for the SPO).     

柴达木盆地北缘大柴旦地区古生代花岗岩锆石SHRIMP定年

大柴旦地区是柴北缘古生代超高压带的重要组成部分,与超高压岩石相伴的花岗岩十分发育。这些花岗岩具有两类不同的岩石地球化学特征,Ⅰ类以 Na_2O/K_2O 比值小于1、明显的负 Eu 异常和低 Sr、高 Y 为特征,具有 S-型花岗岩的属性,Ⅱ类以 Na_2O/K_2O 比值大于1、弱负 Eu 异常到正 Eu 异常和高 Sr、低 Y 为特征,具有Ⅰ-型花岗岩的属性,反映了它们的源岩及成因上的差异。锆石 SHRIMP U—Ph 定年结果表明,大柴旦地区花岗岩的年龄可分为三组,第一组年龄为446.3±3.9Ma,第二组年龄分别为408.6±4.4Ma、403.3±3.8Ma、401.8±3Ma,第三组年龄分别为374.5±1.6Ma、372±2.1Ma。结合区域地质特征,我们认为,第一组年龄可能反映了柴达木陆块与中南祁连板块碰撞的时代,第二组年龄可能反映了深俯冲地下的板块由于拆沉而折返的时代,第三组年龄可能反映了碰撞隆起后造山带上不同块体之间的伸展、滑塌的时代。     

Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

中国南京与美国德克萨斯稻田甲烷排放的比较

Field measurements of methane emission from rice paddies were made in Nanjing, China and in Texas, USA, respectively. Soil temperature at approximately 10 cm depth of the flooded soils was automatically recorded. Aboveground biomass of rice crop was measured approximately every 10 days in Nanjing and every other week in Texas. Seasonal variation of soil temperature in Nanjing was quite wide with a magnitude of 15.3℃ and that in Texas was narrow with a magnitude of 2.9℃. Analysis of methane emission fluxes against soil temperature and rice biomass production demonstrated that the seasonal course of methane emission in Nanjing was mostly attributed to soil temperature changes, while that in Texas was mainly related to rice biomass production. We concluded that under the permanent flooding condition, the seasonal trend of methane emission would be determined by the soil temperature where there was a wide variation of soil temperature, and the seasonal trend would be mainly determined by rice biomass production if there are no additional organic matter inputs and the variation of soil temperature over the rice growing season is small.     

Volatile halocarbons released from Arctic macroalgae

Twenty-two different species of Arctic brown, red and green macroalgae, collected in the Kongsfjord at Ny-Ålesund (Spitsbergen), were incubated under polar conditions and investigated for their release of volatile halogenated organic compounds (VHOC). Bromoform, dibromomethane, dibromochloromethane, bromodichloromethane, 1,2-dibromoethane, diiodomethane and chloroiodomethane have been identified and their net releases during incubations were determined. Generally, brown and green macroalgae showed higher VHOC release, while red macroalage had only low release. Bromoform was released in relatively large quantities from all species studied, with the highest release observed from the brown algae Dictyosyphon foeniculaceus (0.3 μg g⁻¹ wet algal weight day⁻¹) and Laminaria saccharina (0.15 μg g⁻¹ wet algal weight day⁻¹), and from the green algae Monostroma arcticum (0.3 μg g⁻¹ wet algal weight day⁻¹) and Blidingia minima (0.27 μg g⁻¹ wet algal weight day⁻¹). Dibromomethane, diiodomethane, dibromochloromethane and 1,2-dibromoethane showed lower net release during the incubations. The net release of chloroiodomethane and bromodichloromethane was very low for the most algae species investigated. Based on the distribution of these algae in the Arctic environment, Dictyosiphon foeniculaceus and Laminaria saccharina may be important sources for VHOC because of high release and high biomass. Release of VHOC could be detected from all parts of the thallus of the macroalga. This may provide some evidence for a possible role of VHOC production as a chemical protection mechanism in algae.     

A global heat and freshwater forcing dataset for ocean models

A global dataset based on the ECMWF Re-Analyses (ERA) is presented that can be used as surface boundary conditions for ocean models with sea-ice components. The definition of these conditions is based on bulk formulae. To study the mean ocean circulation, a mean annual cycle on a daily basis was constructed from ERA for all relevant parameters including wind stress. Continental runoff is considered by using information about the catchment areas of the rivers and about the main drainage basins. The bulk formulae were extended by using sea ice concentration.To estimate meridional heat transports (MHT) and to avoid any drift in ocean model simulations, the heat and fresh water budgets have been closed by applying an inverse procedure to fine-tune the fluxes towards observed transports. To improve the MHTs on the Southern Hemisphere the winds and the short wave radiation at southern higher latitudes should be corrected. Furthermore, tests were performed concerning short wave radiation which was increased in the tropics and decreased in the subsidence zones.The heat and fresh water fluxes are assessed by using a scheme of Macdonald and Wunsch based on hydrographic sections. The net heat fluxes of ERA and of the forcing dataset are consistent with the heat flux divergences and convergences estimated by this scheme except for parts of the South Atlantic and the Indian Ocean sector of the Southern Ocean where none of these datasets is consistent with these estimates. In the subtropical South Indian Ocean the forcing dataset is consistent with these estimates while ERA are not. The flux components of ERA and the forcing dataset were compared to several observational datasets (SRB, SOC, HOAPS, GPCP, and CMAP). For each component, at least one of these datasets (especially HOAPS) supports the effects of the inverse procedure and the bulk formulae almost globally with some regional exceptions: short wave radiation in the tropical oceans and the subtropical North Atlantic, latent heat flux at higher latitudes, and precipitation in the northern North Atlantic.Comparisons to the NCAR/NCEP Re-Analyses (NRA) (versions 1 and 2) and the ECHAM model in place of ERA lead to similar results. In the North Atlantic the net heat fluxes of the model based datasets approach the hydrographic estimate with increasing resolution. Applied to any ocean/sea-ice model and compared to ERA, the forcing dataset would induce only a relative small net sea-surface buoyancy loss.A comparison of the forcing dataset to measurements made using one buoy deployed in the western Pacific warm pool and five buoys deployed in the subduction region of the Northeast Atlantic shows that at the site of the first buoy the net heat fluxes of the forcing dataset are in poorer agreement than those of ERA. At the sites of two subduction buoys both datasets show the same level of agreement within the error bars specified. At the sites of the three remaining subduction buoys the forcing dataset shows a marginal improvement on ERA.