华南五峰组-龙马溪组黑色岩系时空展布的主控因素及其启示

在回顾五峰组-龙马溪组两个地层单位沿革并重申其定义与划分基础上,重建了华南五峰组-龙马溪组及其相关地层序列的区域地层框架.根据这一框架中奥陶-志留纪黑色笔石岩系的穿时性、以及相关地层序列纵向演化特征与岩石圈板块挠曲模式的联系,结合所发现钾质斑脱岩源岩的板块汇聚背景,以及该阶段海平面升降与黑色岩系对应关系,提出控制该阶段华南黑色岩系的时空展布格局的主要因素有两个,即该阶段自南东向北西的华夏地块与扬子地块幕式汇聚过程所产生的岩石圈板块挠曲-周缘前陆盆地的同向迁移,以及该阶段两次全球性的三级海平面变化快速上升阶段所导致的缺氧及欠补偿水体.本文认为,要在华南奥陶-志留纪(包括其他断代)寻找其他可能的烃源岩层位,可能要首先考虑类似背景下这两种因素综合作用所导致的快速沉降及深水缺氧的沉积环境.     

A petrogenetic grid for pelitic schists in the system SiO2-Al2O3-FeO-MgO-K2O-H2O

A quantitative petrogenetic grid for pelitic schists in the system KFMASH that includes the phases garnet, chlorite, biotite, chloritoid, cordierite, staurolite, talc, kyanite, andalusite, sillimanite, and pyrophyllite (with quartz, H₂O and muscovite or K-feldspar in excess) is presented. The grid is based on thermodynamic data of Berman et al. (1985) and Berman (1988) for endmember KFASH and KMASH equilibria and natural Fe-Mg partitioning for the KFMASH system. Calculation of P-T slopes and the change in Fe/(Fe+Mg) along reactions in the KFMASH system were made using the Gibbs method. In addition, the effect on the grid of MnO and CaO is evaluated quantitatively. The resulting grid is consistent with typical Buchan and Barrovian parageneses at medium to high grades. At low grades, the grid predicts an extensive stability field for the paragenesis chloritoid+biotite which arises because of the unusual facing of the reaction chloritoid+biotite + quartz+H₂O = garnet+chlorite+muscovite, which proceeds to the right with increasing T in the KFMASH system. However, the reaction proceeds to the left with increasing T in the MnKFASH system so the assemblage chloritoid + biotite is restricted to bulk compositions with high Fe/(Fe+Mg+Mn). Typical metapelites will therefore contain garnet+chlorite at low grades rather than chloritoid + biotite.     

Lower Carboniferous post-orogenic granites in central-eastern Sierra de Velasco,Sierras Pampeanas,Argentina: U–Pb monazite geochronology,geochemistry and Sr–Nd isotopes

The central-eastern part of the Sierra de Velasco (Sierras Pampeanas, NW Argentina) is formed by the large Huaco (40 × 30 km) and Sanagasta (25 × 15 km) granite massifs and the small La Chinchilla stock (2 × 2 km). The larger granites intrude into Ordovician metagranitoids and crosscut Devonian (?) mylonitic shear zones, whereas the small stock sharply intrudes into the Huaco granite. The two voluminous granites are biotitic-muscovitic and biotitic porphyritic syeno- to monzogranites. They contain small and rounded tonalitic and quartz-dioritic mafic microgranular enclaves. The small stock is an equigranular, zinnwaldite- and fluorite-bearing monzogranite. The studied granites are silica-rich (SiO₂ >70%), potassium-rich (K₂O >4%), ferroan, alkali-calcic to slightly calk-alkalic, and moderately to weakly peraluminous (A/CNK: 1.06–1.18 Huaco granite, 1.01–1.09 Sanagasta granite, 1.05–1.06 La Chinchilla stock). They have moderate to strong enrichments in several LIL (Li, Rb, Cs) and HFS (Nb, Ta, Y, Th, U) elements, and low Sr, Ba and Eu contents. U–Pb monazite age determinations indicate Lower Carboniferous crystallization ages: 350–358 Ma for the Huaco granite, 352.7 ± 1.4 Ma for the Sanagasta granite and 344.5 ± 1.4 Ma for the La Chinchilla stock. The larger granites have similar ?Nd values between ?2.1 and ?4.3, whereas the younger stock has higher ?Nd of ?0.6 to ?1.4, roughly comparable to the values obtained for the Carboniferous San Blas granite (?1.4 to ?1.7), located in the north of the sierra. The Huaco and Sanagasta granites have a mainly crustal source, but with some participation of a more primitive, possibly mantle-derived, component. The main crustal component can be attributed to Ordovician peraluminous metagranitoids. The La Chinchilla stock derives from a more primitive source, suggesting an increase with time in the participation of the primitive component during magma genesis. The studied granites were generated during a post-orogenic period in a within-plate setting, possibly as a response to the collapse of the previous Famatinian orogen, extension of the crust and mantle upwelling. They are part of the group of Middle Devonian–Lower Carboniferous granites of the Sierras Pampeanas. The distribution and U–Pb ages of these granites suggests a northward arc-parallel migration of this mainly post-orogenic magmatism with time.     

西藏班公湖-怒江缝合带白垩系沉积特征及其构造意义

班公湖—怒江位于西藏中部 ,西起班公湖日土 (33.5°N ,79°E) ,向东经由措勤、尼玛、那曲至东部怒江带 ,走向近东西、其中部大致平行于北纬 32°线 ,延长大于 15 0 0km。该带蛇绿岩发育 ,是中生代板块缝合线 ,是南部拉萨地块与北部羌塘地块的分界线。其中段班戈地区白垩系地层发育 ,包括下白垩统底部川巴组 (K1c)、多巴组 (K1d)、郎山组 (K1l)和上白垩统江巴组 (K2 j)。川巴组为浅海相黑色页岩、泥岩、粉砂岩、砂岩、煤层和火山岩 ;多巴组为含有海侵夹层的陆相碎屑岩建造 ,海侵层为含园笠虫 (Orbitolinasp .)钙质砂岩 ;郎山组为浅海相—泻湖相台地型碳酸盐岩沉积 ;江巴组以陆相、厚层块状的砂砾岩红层为特征。本区白垩系层序的总体特征 ,是以海相火山岩—细碎屑岩为先导、经海陆过渡相碎屑岩和海相碳酸盐岩到陆相红层 ,形成于与B型俯冲作用有关的活动大陆边缘构造背景.     

Trace and minor elements in sphalerite: A LA-ICPMS study

Sphalerite is an important host mineral for a wide range of minor and trace elements. We have used laser-ablation inductively coupled mass spectroscopy (LA-ICPMS) techniques to investigate the distribution of Ag, As, Bi, Cd, Co, Cu, Fe, Ga, Ge, In, Mn, Mo, Ni, Pb, Sb, Se, Sn and Tl in samples from 26 ore deposits, including specimens with wt.% levels of Mn, Cd, In, Sn and Hg. This technique provides accurate trace element data, confirming that Cd, Co, Ga, Ge, In, Mn, Sn, As and Tl are present in solid solution. The concentrations of most elements vary over several orders of magnitude between deposits and in some cases between single samples from a given deposit. Sphalerite is characterized by a specific range of Cd (typically 0.2-1.0 wt.%) in each deposit. Higher Cd concentrations are rare; spot analyses on samples from skarn at Baisoara (Romania) show up to 13.2 wt.% (Cd²⁺ ↔ Zn²⁺ substitution). The LA-ICPMS technique also allows for identification of other elements, notably Pb, Sb and Bi, mostly as micro-inclusions of minerals carrying those elements, and not as solid solution. Silver may occur both as solid solution and as micro-inclusions. Sphalerite can also incorporate minor amounts of As and Se, and possibly Au (e.g., Magura epithermal Au, Romania). Manganese enrichment (up to ∼4 wt.%) does not appear to enhance incorporation of other elements. Sphalerite from Toyoha (Japan) features superimposed zoning. Indium-sphalerite (up to 6.7 wt.% In) coexists with Sn-sphalerite (up to 2.3 wt.%). Indium concentration correlates with Cu, corroborating coupled (Cu⁺In³⁺) ↔ 2Zn²⁺ substitution. Tin, however, correlates with Ag, suggesting (2Ag⁺Sn⁴⁺) ↔ 3Zn²⁺ coupled substitution. Germanium-bearing sphalerite from Tres Marias (Mexico) contains several hundred ppm Ge, correlating with Fe. We see no evidence of coupled substitution for incorporation of Ge. Accordingly, we postulate that Ge may be present as Ge²⁺ rather than Ge⁴⁺. Trace element concentrations in different deposit types vary because fractionation of a given element into sphalerite is influenced by crystallization temperature, metal source and the amount of sphalerite in the ore. Epithermal and some skarn deposits have higher concentrations of most elements in solid solution. The presence of discrete minerals containing In, Ga, Ge, etc. also contribute to the observed variance in measured concentrations within sphalerite.     

The origin of K-feldspar megacrysts hosted in alkaline potassic rocks from central Italy: a track for low-pressure processes in mafic magmas

In situ Sr-isotope and microchemical studies were used to determine the provenance of K-feldspar megacrysts hosted in mafic alkaline potassic, ultrapotassic rocks and in differentiated rocks from two nearby volcanic apparatus in central Italy.

At Monte Cimino volcanic complex, mafic leucite-free ultrapotassic megacryst-bearing rocks of olivine latitic composition are associated with evolved latite and trachyte. Here, latites and trachytes straddle the sub-alkaline field. Age-corrected ⁸⁷Sr/⁸⁶Sr values (Sr_i) of the analysed Cimino olivine latites vary from 0.71330 and 0.71578 and strongly increase at constant Mg value. Latite and trachyte have lower Sr_i than olivine latites ranging between 0.71331 and 0.71361. Sr_i of K-feldspar megacrysts from olivine latites are between 0.71352 and 0.71397, but core and rim ⁸⁷Sr/⁸⁶Sr ratios within individual megacryst are indistinguishable. In all the mafic rocks, the megacrysts are not in isotopic equilibrium with the hosts. K-feldspar megacrysts from both the latite and trachyte have similar Sr-isotope compositions (Sr_i=0.71357–0.71401) to those in the olivine latites. However, Sr_i of megacryst in the trachyte vary significantly from core to rim (Sr_i from 0.71401 to 0.71383). As with the olivine latites, the K-feldspar megacrysts are not in isotopic equilibrium with bulk rock compositions of the latite or trachyte.

At Vico volcano, megacryst-bearing rocks are mafic leucite-free potassic rocks, mafic leucite-bearing ultrapotassic rocks and old trachytic rocks. The mafic leucite-bearing and leucite-free rocks are a tephri-phonolite and an olivine latite, respectively. A megacryst in Vico trachyte is isotopically homogeneous (Sr_i CORE=0.71129, RIM=0.71128) and in equilibrium with the host rock (Sr_i bulk ROCK=0.71125). Sr_i of megacryst from tephri-phonolite is clearly not in isotopic equilibrium with its host (Sr_i bulk ROCK=0.71158), and it increases from core (Sr_i=0.71063) to rim (Sr_i=0.71077). A megacryst in Vico olivine latite is isotopically homogeneous (Sr_i CORE=0.71066, RIM=0.71065), but not in equilibrium with the host rock (Sr_i bulk ROCK=0.71013).

The Sr isotope microdrilling technique reveals that Cimino megacrysts were crystallised in a Cimino trachytic magma and were subsequently incorporated by mixing/mingling processes in the latitic and olivine latitic melts. A model invoking the presence of a mafic sub-alkaline magma, which was mixed with the olivine latite, is proposed to justify the lack of simple geochemical mixing relation between Cimino trachytes and olivine latites. This magmatological model is able to explain the geochemical characteristics of Cimino olivine latites, otherwise ascribed to mantle heterogeneity.

The similarity of core Sr_i of megacrysts hosted in Vico tephri-phonolite and olivine latite suggests that the K-feldspar megacrysts are co-genetic. Isotopic equilibrium between megacryst and Vico host trachyte indicates that the trachyte is the parent of this megacryst. On the contrary, the megacrysts hosted in tephri-phonolite and olivine latite do not derive from the old trachytic magma because no diffusion process may explain the core to rim Sr isotope increase of the xenocryst hosted in the tephri-phonolite. The megacrysts hosted in the Vico mafic rocks might derive from a trachytic melt similar in composition to the old Vico trachytes.     

Constraining the chronology of Pleistocene glaciations on Svalbard: Kapp Ekholm re‐visited

The Kapp Ekholm site, in central Spitsbergen, shows alternating units of glaciomarine sandy silt and diamicton representing three glacial cycles and is key in reconstructing the Late Pleistocene glacial history of Svalbard. Part of the site is reinvestigated here by focusing on re‐dating two units (B and F) interpreted as interglacial/interstadial glaciomarine deposits, in order to constrain the controversial chronology. A combination of Optical Stimulated Luminescence (OSL) on quartz, infrared stimulated luminescence with a 50 °C readout temperature (IRSL₅₀) and post infrared‐infrared stimulated luminescence (pIR), both on feldspar, was applied. While Formation B was beyond the dateable range of OSL, IRSL₅₀ and pIR ages lead to the conclusion that this unit represents the Last Interglacial, Marine Isotope Stage (MIS) 5e, and the underlying diamicton the MIS 6 glacial. Formation F yielded ages implying that the formation represents the MIS 5a interstadial and the underlying diamicton is interpreted to represent the MIS 5b stadial. This agrees with conclusions drawn concerning the Pleistocene glaciations elsewhere on Svalbard.     

Alfvén-Jeans and Magnetosonic Modes in Multispecies Self-Gravitating Dusty Plasmas

Perpendicularly propagating electromagnetic waves in magnetized, multispecies, self-gravitating dusty plasmas are investigated in terms of their wave dispersion properties as well as with respect to their susceptibility to gravitational collapse. In particular, waves on the ordinary as well as extraordinary mode branches are considered. Within the one-dimensional propagation model employed, all modes except the ordinary mode produce density perturbations that can be unstable to gravitational collapse. The wavelengths that are unstable are comparable to the well-known Jeans length for a neutral gas/dust, but there are interesting modifications due to the presence of a magnetic field and charged particles. Furthermore, the effects of the gravitational coupling of a multicomponent plasma to a neutral dust are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

The spectrum of the inner corona observed during the total solar eclipse of 30 May 1965

A series of spectrograms of the inner solar corona were obtained at the total solar eclipse of 30 May 1965 using a fast spectrograph with a circular slit that recorded the spectrum from 3000 to 9000 at all position angles around the limb simultaneously. In this paper absolute intensity is given as a function of position angle for the stronger lines and the continuum. In the coronal enhancement or condensation centered at heliocentric position angle 293°, absolute intensity is given for 34 forbidden emission lines and the continuum.     

The global oscillation network group site survey

The Global Oscillation Network Group (GONG) Project is planning to place a set of instruments around the world to observe solar oscillations as continuously as possible for at last three years. The Project has now chosen the sites that will comprise the network. This paper describes the methods of data collection and analysis that were used to make this decision.Solar irradiance data were collected with a one-minute cadence at fifteen sites around the world and analyzed to produce statistics of cloud cover, atmospheric extinction, and transparency power spectra at the individual sites. Nearly 200 reasonable six-site networks were assembled from the individual stations, and a set of statistical measures of the performance of the networks was analyzed using a principal component analysis. An accompanying paper presents the results of the survey.