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651.
Frank Reith Steven A. Wakelin Adrienne L. Gregg Andreas Schmidt Mumm 《Chemical Geology》2009,258(3-4):315-326
The formation of pedogenic carbonate (calcrete) in terrestrial environments is commonly mediated by microorganisms. In Australia, Au-anomalous calcrete is an important sampling medium for geochemical exploration, but current models describing its formation do not include a confirmed microbial component. This study demonstrates that bacterial communities in calcareous sands from dunes overlying the Barns Gold Deposit in semi-arid South Australia, are capable of mediating the biomineralisation of Au-anomalous carbonates. Bacterial enrichment cultures obtained from calcareous sands at three depths (0.1, 0.64 and 2.1 m, plus abiotic control) were incubated in urea and Ca2+-containing growth media (pH 8), unamended and amended with Au (100 parts-per-billion, ppb) as Au–aspartic-acid complex. During the incubation of the enrichment cultures urea was turned over to NH4+ within 96 h to 220 h. The solution pH increased concurrently by approximately 1.2 units, and Au-anomalous Ca-carbonate crystallites were precipitated on cells, which functioned as nucleation sites; no carbonate precipitation was observed in abiotic controls. Compared to the medium, Au was strongly enriched in these carbonates and appeared to be uniformly dispersed in the individual crystallites, as shown using LA-ICP-MS; a similar distribution is present in naturally occurring Au-anomalous calcrete. Phylogenetic 16S rRNA PCR DGGE analyses, shotgun cloning and functional microbial analyses (BioLog, ureC quantitative PCR) demonstrated that naturally occurring and culture-enriched bacterial communities were dominated by alkaliphylic, halotolerant Bacillus spp. The indigenous bacterial communities were capable of utilising amino acids (including l-aspartic acid) and urea, which appears to lead to the destabilisation of the Au–amino acid complexes and concomitant co-precipitation of Au in the Ca-carbonates. In conclusion, a model combining geomicrobial– with evapotranspiration– and plant-based components is likely to best describe the formation of (Au-anomalous) calcrete in semi-arid and arid zones. 相似文献
652.
653.
Stephanie Kastner Christian Ohlendorf Torsten Haberzettl Andreas Lücke Christoph Mayr Nora I. Maidana Frank Schäbitz Bernd Zolitschka 《Journal of Paleolimnology》2010,44(4):887-902
We studied the internal lake processes that control the spatial distribution and characteristics of modern sediments at the
ICDP (International Continental Scientific Drilling Program) deep drilling site in Laguna Potrok Aike, southern Patagonia,
Argentina. Sediment distribution patterns were investigated using a dense grid of 63 gravity cores taken throughout the lake
basin and 40 additional shoreline samples. Analysis of the surficial sediment distribution points to distinct internal depositional
dynamics induced by wind-driven lake internal currents. Distribution maps illustrate that the spatial characteristics of analysed
variables are linked to high erosional wave activity. Persistent wave action and littoral erosion along all shores, especially
the eastern shore, is caused by prevailing Southern Hemispheric Westerlies. Several sediment variables (grain size, benthic
diatoms, total inorganic carbon and calcium) indicate re-suspension of littoral sediment followed by re-distribution to profundal
accumulation areas near the eastern shore. Variations within the catchment influence sediment characteristics in the north-eastern
bay. That area is characterized by different mineralogical and sedimentological conditions as well as greater accumulation
of pollen, inorganic carbon and diatoms. These findings are related to the influence of episodic inflow into this bay. Spatial
differences in stable isotope values throughout the lake suggest that ephemeral tributaries around the lake basin may also
contribute to the detected spatial sediment variations. 相似文献
654.
Philippe Rentzel Frank Preusser Christine Pümpin Jean-Jacques Wolf 《Swiss Journal of Geoscience》2009,102(3):387-401
Pedological investigations in combination with luminescence dating have been used to reconstruct the genesis and chronology
of a sediment succession at Sierentz, France. The sequence comprises loess and palaeosols on top of gravel attributed to the
High Terrace of River Rhine. According to the dating results, three phases of soil development occurred during different warm
phases of Marine Isotope Stage (MIS) 7 (245–190 ka). Soil development on top of the gravel occurred either during early MIS
7 or during an earlier warm phase, possibly MIS 9. The results imply a minimum age of 250 ka for the formation of the High
Terrace in this part of the Upper Rhine Graben, contrary to previous assumptions that correlated gravel sheet deposition with
MIS 6 (ca. 150 ka). These results and recent findings at other sites suggest that the chronological setting of terrace formation
north of the Alps is much more complex than previously assumed. 相似文献
655.
On the occurrence,trace element geochemistry,and crystallization history of zircon from in situ ocean lithosphere 总被引:10,自引:2,他引:8
Craig B. Grimes Barbara E. John Michael J. Cheadle Frank K. Mazdab Joseph L. Wooden Susan Swapp Joshua J. Schwartz 《Contributions to Mineralogy and Petrology》2009,158(6):757-783
We characterize the textural and geochemical features of ocean crustal zircon recovered from plagiogranite, evolved gabbro,
and metamorphosed ultramafic host-rocks collected along present-day slow and ultraslow spreading mid-ocean ridges (MORs).
The geochemistry of 267 zircon grains was measured by sensitive high-resolution ion microprobe-reverse geometry at the USGS-Stanford
Ion Microprobe facility. Three types of zircon are recognized based on texture and geochemistry. Most ocean crustal zircons
resemble young magmatic zircon from other crustal settings, occurring as pristine, colorless euhedral (Type 1) or subhedral
to anhedral (Type 2) grains. In these grains, Hf and most trace elements vary systematically with Ti, typically becoming enriched
with falling Ti-in-zircon temperature. Ti-in-zircon temperatures range from 1,040 to 660°C (corrected for a
TiO2 ≈ 0.7, a
SiO2 ≈ 1.0, pressure ≈ 2 kbar); intra-sample variation is typically ~60–150°C. Decreasing Ti correlates with enrichment in Hf
to ~2 wt%, while additional Hf-enrichment occurs at relatively constant temperature. Trends between Ti and U, Y, REE, and
Eu/Eu* exhibit a similar inflection, which may denote the onset of eutectic crystallization; the inflection is well-defined
by zircons from plagiogranite and implies solidus temperatures of ~680–740°C. A third type of zircon is defined as being porous
and colored with chaotic CL zoning, and occurs in ~25% of rock samples studied. These features, along with high measured La,
Cl, S, Ca, and Fe, and low (Sm/La)N ratios are suggestive of interaction with aqueous fluids. Non-porous, luminescent CL overgrowth rims on porous grains record
uniform temperatures averaging 615 ± 26°C (2SD, n = 7), implying zircon formation below the wet-granite solidus and under water-saturated conditions. Zircon geochemistry reflects,
in part, source region; elevated HREE coupled with low U concentrations allow effective discrimination of ~80% of zircon formed
at modern MORs from zircon in continental crust. The geochemistry and textural observations reported here serve as an important
database for comparison with detrital, xenocrystic, and metamorphosed mafic rock-hosted zircon populations to evaluate provenance. 相似文献
656.
Hafnium isotopes in Arctic Ocean water 总被引:1,自引:0,他引:1
Bettina Zimmermann Martin Frank M. Baskaran Alex N. Halliday 《Geochimica et cosmochimica acta》2009,73(11):3218-5926
The first isotopic compositions of dissolved hafnium in seawater from across the Arctic Ocean are reported. Most samples from the four sub-basins of the Arctic Ocean have values within error of an average of εHf = +0.8. Combined Hf-Nd isotope compositions do not fall on the well-established positive correlation for mantle and crustal rocks. Instead, Arctic waters have Hf that is more radiogenic than that typically found in rocks with similar Nd isotope compositions, a feature previously found in ferromanganese crusts and waters from the Pacific Ocean. Arctic seawater samples generally fall on the lower part of the ferromanganese crust array, reflecting influences of inputs from Arctic rivers and interactions of shelf waters with underlying sediments. Arctic rivers have much higher Hf concentrations (7-30 pM) than Arctic seawater (0.36-4.2 pM). Water from the Mackenzie River has the least radiogenic Hf, with εHf = −7.1 ± 1.7, and plots furthest away from the ferromanganese crust array, while waters from the Ob, Yenisey, and Lena Rivers have values that are indistinguishable from most Arctic waters. In the Amundsen, Makarov, and Canada basins, Hf concentrations are highest at the surface and lowest in the deeper waters, reflecting the influences of riverine inputs and of waters that have flowed over the extensive Siberian continental shelves and have Nd and Hf characteristics that reflect water-sediment interactions. This is in contrast to the relatively low near surface Hf concentrations reported for locations elsewhere. The Pacific water layer in the Canada Basin exhibits the highest value of εHf = +6.8 ± 1.8, reflecting the Hf isotopic composition of waters entering the Arctic from the Pacific Ocean. Mixing relationships indicate that a substantial fraction of the Hf in the Mackenzie River is lost during estuarine mixing; the behaviour of Hf from other rivers is less constrained. 相似文献
657.
Shallow plumbing systems for small-volume basaltic volcanoes 总被引:3,自引:3,他引:0
Gordon N. Keating Greg A. Valentine Donathon J. Krier Frank V. Perry 《Bulletin of Volcanology》2008,70(5):563-582
Eruptive dynamics in basaltic volcanoes are controlled, in part, by the conduit geometry. However, uncertainties in conduit
shape and dike-to-conduit transition geometry have limited our predictive capability for hazards assessments. We characterize
the subvolcanic geometry of small-volume basaltic volcanoes (magmatic volatile-driven eruptions, 0.1 to 0.5 km3) based on a synthesis of field studies of five basaltic volcanoes exposed to varying degrees by erosion and exhibiting feeder
dikes, conduits, and vent areas ≤250 m depth. Study areas include East Grants Ridge (New Mexico, USA), Basalt Ridge, East
Basalt Ridge, Paiute Ridge, and Southeast Crater Flat (Nevada, USA). Basaltic feeder dikes 250 to 100 m deep have typical
widths of 4–12 m, with smooth host-rock contacts (rhyolite tuff). At depths less than 100 m, heterogeneities in the host rock
form preferential pathways for small dike splays and sills, resulting in a 30-m effective width at 50 m depth. The development
of a complex conduit at depths less than 70 m is reflected in bifurcating dikes and brecciation and incorporation of the country
rock. The overall zone of effect at depths less than 50 m is ≤110 m wide (220 m elongated along the feeder dike). Based on
comparisons with theoretical conduit flow models, the width of the feeder dike at depths from 250 to 500 m is expected to
range from 1 to 10 m and is expected to decrease to about 1–2 m at depths greater than 500 m. The flaring shape of the observed
feeder systems is similar to results of theoretical modeling using lithostatic pressure-balanced flow conditions. Sizes of
observed conduits differ from modeled dimensions by up to a factor of 10 in the shallow subsurface (<50 m depth), but at depths
greater than 100 m the difference is a factor of 2 to 4. This difference is primarily due to the fact that observed eroded
conduits record the superimposed effects of multiple eruptive events, while theoretical model results define dimensions necessary
for a single, steady eruption phase. The complex details of magma-host rock interactions observed at the study areas (contact
welding, brecciation, bifurcating dikes and sills, and stoping) represent the mechanisms by which the lithostatic pressure-balanced
geometry is attained. The similarity in the normalized shapes of theoretical and observed conduits demonstrates the appropriateness
of the pressure-balanced modeling approach, consistent with the conclusions of Wilson and Head (J Geophys Res 86:2971–3001,
1981) for this type of volcano. 相似文献
658.
Depositional and post-depositional controls on magnetic signals from saltmarshes on the north-west coast of Ireland 总被引:3,自引:0,他引:3
Magnetic measurements were carried out on samples from two saltmarshes deposited during the last century on the north-west coast of Ireland. Based on profiles from cliffed saltmarsh edge, mid-marsh and supratidal locations, the processes that affect the generation and persistence of magnetic properties in environments were investigated. This was done to help in understanding the geochemical processes affecting north-west Irish coast saltmarshes and to determine the frequency and provenance of sediment-laden flooding events; hence, disentangling the importance of clastic and organic contributions to saltmarsh growth. Magnetic properties indicate depositional and post-depositional effects varying on both temporal and spatial scales. The interpretations presented here suggest that both biogenic and diagenetic processes have a strong effect on the magnetic properties recorded: in the former case, the growth of magnetotactic bacteria is the main process; in the latter case, it is reductive diagenesis, associated with organic matter decomposition, that is important. The biogenic and diagenetic effects overprint and degrade the detrital magnetic signatures respectively. This suggests that magnetic measurements within the context of north-west Irish coast saltmarshes can provide limited information on clastic sediment input to these environments. Comparisons between sites on the north-west coast of Ireland show similar magnetic properties, despite differences in deposition rates, implying that significant post-depositional alteration of magnetic properties occurs within the first 20–40 years after deposition. Magnetic properties of north-west coast Irish saltmarshes are put into a regional context by comparison with magnetic profiles from similar sites. 相似文献
659.
On the design of formal theories of geographic space 总被引:1,自引:0,他引:1
This paper discusses the design of formal theories of geographic space for the application in Geographic Information Systems.
GIS software is an implementation of formal theories of geographic space. The notions of formal theories are introduced and
discussed in the context of examples from the GIS field.
Our approach is an application of the general framework of formal theories to the special class of theories of geographic
space, in particular to the geometry of geographic space. A framework is introduced for characterizing and evaluating formal
theories of geographic space and the process of their design. This is used to provide (1) a classification of formal theories
of geographic space, (2) criteria of their adequacy, and (3) an evaluation of design decisions in the process of formalization.
The paper demonstrates the choices in the design of GIS and the dependencies between these choices. Considering the design
space for theories underlying a GIS, we can see that current GIS are based on one choice: analytical geometry. Other designs
are possible and a systematic exploration of alternative types of GIS, for example, based on constraints or based on stored
spatial relations, becomes necessary.
Received: 30 April 1997/Accepted: 8 March 1999 相似文献
660.
We present a remotely-sensed degradation assessment technique based on the measurement of landscape heterogeneity (a key determinant of degradation status). The moving standard deviation index (MSDI) is derived by passing a moving standard deviation filter across the Landsat TM band 3 (red band). Degraded/unstable landscapes exhibit higher MSDI values than their undisturbed/stable counterparts. Significant differences in MSDI were detected (p<0·001) across four fence-lines which separated rangeland of contrasting condition. The relationship of the index to normalized difference vegetation index (NDVI) was tested in five different ecosystems and significant correlations were obtained in all cases (p<0·001). We propose the MSDI as a powerful adjunct to vegetation indices. 相似文献