Paleocene alkaline volcanism in the Nares Strait region: evidence from volcanic pebbles

Paleogene sediments in fault-bounded basins on Judge Daly Promontory, northeast Ellesmere Island, Canadian High Arctic, are rich in volcanogenic material. Volcanic pebbles within the Cape Back basin near Nares Strait were studied for their petrography, geochemistry, Sr and Nd isotopes, and geochronology to identify and characterize their parent rock. The pebbles are derived from lava flows and ignimbrites of a continental rift-related, strongly differentiated, highly incompatible element enriched, alkaline volcanic suite, the proposed Nares Strait volcanic suite, which is distinct from other alkaline volcanic suites on the northern coasts of Ellesmere Island and Greenland. ⁴⁰Ar/³⁹Ar amphibole and alkali feldspar ages indicate that volcanism was active around 61–58 Ma and was probably contemporaneous with sedimentation resulting in Middle to Late Paleocene age for deposition within the Cape Back basin and the other Paleogene basins on Judge Daly Promontory.     

A microbial pathway for the formation of gold-anomalous calcrete

The formation of pedogenic carbonate (calcrete) in terrestrial environments is commonly mediated by microorganisms. In Australia, Au-anomalous calcrete is an important sampling medium for geochemical exploration, but current models describing its formation do not include a confirmed microbial component. This study demonstrates that bacterial communities in calcareous sands from dunes overlying the Barns Gold Deposit in semi-arid South Australia, are capable of mediating the biomineralisation of Au-anomalous carbonates. Bacterial enrichment cultures obtained from calcareous sands at three depths (0.1, 0.64 and 2.1 m, plus abiotic control) were incubated in urea and Ca²⁺-containing growth media (pH 8), unamended and amended with Au (100 parts-per-billion, ppb) as Au–aspartic-acid complex. During the incubation of the enrichment cultures urea was turned over to NH₄⁺ within 96 h to 220 h. The solution pH increased concurrently by approximately 1.2 units, and Au-anomalous Ca-carbonate crystallites were precipitated on cells, which functioned as nucleation sites; no carbonate precipitation was observed in abiotic controls. Compared to the medium, Au was strongly enriched in these carbonates and appeared to be uniformly dispersed in the individual crystallites, as shown using LA-ICP-MS; a similar distribution is present in naturally occurring Au-anomalous calcrete. Phylogenetic 16S rRNA PCR DGGE analyses, shotgun cloning and functional microbial analyses (BioLog, ureC quantitative PCR) demonstrated that naturally occurring and culture-enriched bacterial communities were dominated by alkaliphylic, halotolerant Bacillus spp. The indigenous bacterial communities were capable of utilising amino acids (including l-aspartic acid) and urea, which appears to lead to the destabilisation of the Au–amino acid complexes and concomitant co-precipitation of Au in the Ca-carbonates. In conclusion, a model combining geomicrobial– with evapotranspiration– and plant-based components is likely to best describe the formation of (Au-anomalous) calcrete in semi-arid and arid zones.     

Great Lakes Hydrology Under Transposed Climates

Historical climates, based on 43 years of daily data from areas south and southwest of the Great Lakes, were used to examine the hydrological response of the Great Lakes to warmer climates. The Great Lakes Environmental Research Laboratory used their conceptual models for simulating moisture storages in, and runoff from, the 121 watersheds draining into the Great Lakes, over-lake precipitation into each lake, and the heat storages in, and evaporation from, each lake. This transposition of actual climates incorporates natural changes in variability and timing within the existing climate; this is not true for General Circulation Model-generated corrections applied to existing historical data in many other impact studies. The transposed climates lead to higher and more variable over-land evapotranspiration and lower soil moisture and runoff with earlier runoff peaks since the snow pack is reduced up to 100%. Water temperatures increase and peak earlier. Heat resident in the deep lakes increases throughout the year. Buoyancy-driven water column turnover frequency drops and lake evaporation increases and spreads more throughout the annual cycle. The response of runoff to temperature and precipitation changes is coherent among the lakes and varies quasi-linearly over a wide range of temperature changes, some well beyond the range of current GCM predictions for doubled CO₂ conditions.     

Remotely sensed soil moisture integration in an ecosystem carbon flux model. The spatial implication

While remote sensing is able to provide spatially explicit datasets at regional to global scales, extensive application to date has been found only in the reporting and verification of ecosystem carbon fluxes under the Kyoto Protocol. One of the problems is that new remote sensing datasets can be used only with models or data assimilation schemes adapted to include a data input interface dedicated to the type and format of these remote sensing datasets. In this study, soil water index data (SWI), derived from the ERS scatterometer (10-daily time period with a spatial resolution of 50 km), are integrated into the ecosystem carbon balance model C-Fix to assess 10-daily Net Ecosystem Productivity (NEP) patterns of Europe from the remote sensing perspective on an approximate 1-by-1 km² pixel scale using NDVI-AVHRR data. The modeling performance of NEP obtained with and without the assimilation of remotely sensed soil moisture data in the carbon flux model C-Fix is evaluated with EUROFLUX data. Results show a general decrease of the RRMSE of up to 11 with an average of 3.46. C-Fix is applied at the European scale to demonstrate the potential of this ecosystem carbon flux model, based on remote sensing inputs. More specifically, the strong impact of soil moisture on the European carbon balance in the context of the Kyoto Protocol (anthropogenic carbon emissions) is indicated at the country level. Results suggest that several European countries shift from being a carbon sink (i.e., NEP > 1) to being a carbon source (i.e., NEP < 0) whether or not short-term water availability (i.e., soil moisture) is considered in C-Fix NEP estimations.     

Synoptic drivers of 400 years of summer temperature and precipitation variability on Mt. Olympus,Greece

The Mediterranean region has been identified as a global warming hotspot, where future climate impacts are expected to have significant consequences on societal and ecosystem well-being. To put ongoing trends of summer climate into the context of past natural variability, we reconstructed climate from maximum latewood density (MXD) measurements of Pinus heldreichii (1521–2010) and latewood width (LWW) of Pinus nigra (1617–2010) on Mt. Olympus, Greece. Previous research in the northeastern Mediterranean has primarily focused on inter-annual variability, omitting any low-frequency trends. The present study utilizes methods capable of retaining climatically driven long-term behavior of tree growth. The LWW chronology corresponds closely to early summer moisture variability (May–July, r = 0.65, p < 0.001, 1950–2010), whereas the MXD-chronology relates mainly to late summer warmth (July–September, r = 0.64, p < 0.001; 1899–2010). The chronologies show opposing patterns of decadal variability over the twentieth century (r = ?0.68, p < 0.001) and confirm the importance of the summer North Atlantic Oscillation (sNAO) for summer climate in the northeastern Mediterranean, with positive sNAO phases inducing cold anomalies and enhanced cloudiness and precipitation. The combined reconstructions document the late twentieth—early twenty-first century warming and drying trend, but indicate generally drier early summer and cooler late summer conditions in the period ~1700–1900 CE. Our findings suggest a potential decoupling between twentieth century atmospheric circulation patterns and pre-industrial climate variability. Furthermore, the range of natural climate variability stretches beyond summer moisture availability observed in recent decades and thus lends credibility to the significant drying trends projected for this region in current Earth System Model simulations.     

A three-dimensional model of the global ammonia cycle

Using a three-dimensional (3-D) transport model of the troposphere, we calculated the global distributions of ammonia (NH₃) and ammonium (NH ₄ ⁺ ), taking into account removal of NH₃ on acidic aerosols, in liquid water clouds and by reaction with OH. Our estimated global 10°×10° NH₃ emission inventory of 45 Tg N-NH₃ yr^– provides a reasonable agreement between calculated wet NH ₄ ⁺ deposition and measurements and of measured and modeled NH ₄ ⁺ in aerosols, although in Africa and Asia especially discrepancies exist.NH₃ emissions from natural continental ecosystems were calculated applying a canopy compensation point and oceanic NH₃ emissions were related to those of DMS (dimethylsulfide). In many regions of the earth, the pH found in rain and cloud water can be attributed to acidity derived from NO, SO₂ and DMS emissions and alkalinity from NH₃. In the remote lower troposphere, sulfate aerosols are calculated to be almost neutralized to ammonium sulfate (NH₄)₂SO₄, whereas in the middle and upper troposphere, according to our calculations, the aerosol should be more acidic, as a result of the oxidation of DMS and SO₂ throughout the troposphere and removal of NH₃ on acidic aerosols at lower heights. Although the removal of NH₃ by reaction with the OH radical is relatively slow, the intermediate NH₂ radical can provide a substantial annual N₂O source of 0.9 _–0.4 ^+0.9 Tg, thus contributing byca. 5% to estimated global N₂O production. The oxidation by OH of NH₃ from anthropogenic sources accounts for 10% of the estimated total anthropogenic sources of N₂O. This source was not accounted for in previous studies, and is mainly located in the tropics, which have high NH₃ and OH concentrations. Biomass burning plumes, containing high NO _x and NH₃ concentrations provide favourable conditions for gas phase N₂O production. This source is probably underestimated in this model study, due to the coarse resolution of the 3-D model, and the rather low biomass burning NH₃ and NO _x emissions adopted. The estimate depends heavily on poorly known concentrations of NH₃ (and NO _x ) in the tropics, and uncertainties in the rate constants of the reactions NH₂ + NO₂ N₂O + H₂O (R4), and NH₂ + O₃ NH₂O + O₂ (R7).     

Some aspects of determining the stable boundary layer depth from sodar data

The question of estimating the height of the stable boundary layer (SBL) based on digitalized vertical profiles of sodar signal intensity has been re-examined. A simple one-dimensional numerical boundary-layer model is used to compute vertical profiles of the temperature structure parameterC _T ² . It is shown that especially at the beginning of the night (when stratification is weak) one can not expect any significant profile structure in the upper part of the SBL if its depth is determined in terms of common turbulent height scales. From this it is concluded that the SBL-height will be underestimated early in the night when derived from the maximum gradient in the signal intensity profiles. Later in the night in contrast, the computations often show elevated maxima or even zones with reduced, and above them enhanced, vertical gradients ofC _T ² , from which a SBL-height can be deduced that compares well with other common height scales. The computed profiles ofC _T ² are shown to be in qualitative agreement with observed profiles of sodar signal intensity for several analysed cases from the HAPEX-MOBILHY experiment.Comparing different SBL-depth scales with sodar observations, it is demonstrated that most of them are often closely related to a sodar-derived SBL-height only during certain phases of the night. Thus the sodar-SBL-height can, after a transition period, be perhaps associated with the lower turbulent layer of the growing surface inversion during the first part and with the height of the low-level wind maximum during the second part of the night.     

Satellite kinematics – II. The halo mass–luminosity relation of central galaxies in SDSS

The kinematics of satellite galaxies reflect the masses of the extended dark matter haloes in which they orbit, and thus shed light on the mass–luminosity relation (MLR) of their corresponding central galaxies. In this paper, we select a large sample of centrals and satellites from the Sloan Digital Sky Survey and measure the kinematics (velocity dispersions) of the satellite galaxies as a function of the r -band luminosity of the central galaxies. Using the analytical framework presented in More, van den Bosch & Cacciato, we use these data to infer both the mean and the scatter of the MLR of central galaxies, carefully taking account of selection effects and biases introduced by the stacking procedure. As expected, brighter centrals on average reside in more massive haloes. In addition, we find that the scatter in halo masses for centrals of a given luminosity,  σ_{log  M}   , also increases with increasing luminosity. As we demonstrate, this is consistent with  σ_{log  L}   , which reflects the scatter in the conditional probability function   P ( L _c| M )  , being independent of halo mass. Our analysis of the satellite kinematics yields  σ_{log  L} = 0.16  ±  0.04  , in excellent agreement with constraints from clustering and group catalogues, and with predictions from a semi-analytical model of galaxy formation. We thus conclude that the amount of stochasticity in galaxy formation, which is characterized by  σ_{log  L}   , is well constrained, independent of halo mass and in a good agreement with current models of galaxy formation.