Mineral-scale Sr-isotope constraints on magma evolution and chamber dynamics in the Rum layered intrusion,Scotland

Sr isotopic zoning within single plagioclase crystals from rocks from Unit 9 of the Rum layered intrusion is used to infer events during crystal growth in a magma undergoing contamination. The ⁸⁷Sr/⁸⁶Sr diversity among minerals and between cores and rims of plagioclase crystals increases as the boundary between unit 9 and the overlying Unit 10 peridotite is approached. Models of near-solidus interaction of the cumulate with a fluid or melt, or large scale textural re-equilibration, cannot easily account for the systematic differences in ⁸⁷Sr/⁸⁶Sr between small crystals and the rims of larger crystals.We propose a simple interpretation in which crystal growth is concentrated along the cool margins of the reservoir. Crystals are subsequently advected to a site of accumulation at the base of the reservoir, probably by episodic plume-like dense downwellings allowing mixing of isotopically zoned and unzoned crystals.If the core-rim isotope variations are inherited from primary magmatic growth, then the small distances over which they are now preserved (1–2 mm) place constraints on the minimum cooling rate of the intrusion. Although the length scale of diffusive equilibration is influenced by a number of poorly-constrained variables (starting temperature, feldspar composition, temperature-time path) cooling was clearly very rapid with cooling to effective closure (~1,000 °C) within a few thousand years.Editorial responsibility: I. Parsons     

Hafnium and neodymium isotopes in surface waters of the eastern Atlantic Ocean: Implications for sources and inputs of trace metals to the ocean

We present hafnium (Hf) and neodymium (Nd) isotopic compositions and concentrations in surface waters of the eastern Atlantic Ocean between the coast of Spain and South-Africa. These data are complemented by Hf and Nd isotopic and concentration data, as well as rare earth element (REE) concentrations, in Saharan dust.Hafnium concentrations range between a maximum of 0.52 pmol/kg in the area of the Canary Islands and a minimum value of 0.08 pmol/kg in the southern Angola Basin. Neodymium concentrations also show a local maximum in the area of the Canary Islands (26 pmol/kg) but are even higher between ∼20°N and ∼4°N reaching maximum concentrations of 35 pmol/kg. These elevated concentrations provide evidence of inputs from weathering of the Canary Islands and from the partial dissolution of dust from the Sahara/Sahel region. The inputs from ocean island weathering are also reflected in radiogenic Hf and Nd isotopes.The Hf isotopic compositions of dust samples themselves are highly variable, ranging between ε_Hf = −20 and −0.6. The combined Hf and Nd isotopic compositions of dust plot close to the “terrestrial array” during periods of appreciable dust load in the atmosphere. During low atmospheric dust loading combined Hf and Nd isotopic compositions similar to seawater are observed. Most of the variability can be explained in terms of variable degrees of zircon loss from the dust samples, which in turn is linked to sorting during atmospheric transport to the eastern Atlantic Ocean and possibly presorting by sedimentary redistribution on the continent. In addition, increasing relative proportions of radiogenic clay minerals with decreasing grain size may contribute to the radiogenic Hf isotopic compositions observed.While the Nd isotopic composition in the surface ocean reflects the Nd isotopic composition of the Saharan dust adjacent to the Sahara/Sahel region, the release of Hf from that dust appears to be incongruent and results in surface ocean Hf isotopic compositions which are ∼10 ε_Hf more radiogenic than the bulk dust. Radiogenic Hf appears to be released from clays and possibly from trace apatite. Rare earth element patterns of dust samples indicate the presence of apatite but provide no evidence for ferromanganese grain coatings, suggesting that such coatings are insignificant in the release of Hf and Nd from Saharan dust to the surface ocean.The Nd isotopic composition of the surface waters becomes less radiogenic south of the equator, most likely reflecting the release of Nd from Congo river sediments. The release of Hf from Saharan dust and the Congo river sediments, however, does not produce distinct Hf isotopic signatures in the surface ocean, implying that the mobile fraction of Hf integrated over large continental areas is isotopically uniform. The Hf isotopic uniformity in the surface ocean means that the limited variability in deep water isotopic compositions is consistent with a short deep water residence time and reflects homogenous continental inputs rather than efficient deep water homogenization.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Spatial Response to Major Volcanic Events in or about AD 536, 934 and 1258: Frost Rings and Other Dendrochronological Evidence from Mongolia and Northern Siberia: Comment on R. B. Stothers, ‘Volcanic Dry Fogs, Climate Cooling, and Plague Pandemics in Europe and the Middle East’ (Climatic Change, 42, 1999)

Hypothesized large-scale climatic extremes require verification from distantregions in order toconfirm the magnitude and timing of such events. Three of the most massivehypothesized volcanic events of the past two millennia, occurring in or aboutAD 536, 934 and1258, had profound climatic and demographic repercussions over much of Europe,the MiddleEast, and other areas, according to historical accounts recently described inStothers (1998, 1999,2000) as well as other research. Here we report on frost ring and otherdendrochronologicalevidence derived from a 1738-year tree-ring chronology from Mongolia andmillennial-scaletree-ring data from northern Siberia which demonstrate that these three eventsmay have alsoimpacted conditions in these distant regions.     

Modeling the temperature of the polar mesopause region: Part II—Intra-seasonal monthly oscillations

Measurements show that the polar mesospheric clouds (PMC) can vary, in the zonal mean, with periods around 1 month [Bailey et al., 2005. Observations of polar mesospheric clouds by the Student Nitric Oxide Explorer. J. Geophys. Res. 110, D13203, doi:10.1029/2004JD005422]. This observation has been the impetus for the present paper, where we describe corresponding temperature oscillations generated by the Numerical Spectral Model (NSM). Our numerical results are taken from the 3D and 2D versions of the NSM, which produce inter-annual and long-term variations in the polar mesopause region, as discussed in the accompanying paper (Part I). In the NSM, the intra-seasonal temperature variations with periods around 2 months are generated by the meridional winds that in turn are accelerated by the momentum deposition from small-scale gravity waves (GW) propagating north/south. The wave-driven dynamical process underlying the oscillations is intrinsically non-linear like that generating the quasi-biennial oscillation (QBO). Our analysis demonstrates that the seasonal annual and semi-annual variations excite the oscillation frequencies through non-linear cascading.     

Storm track response to ocean fronts in a global high-resolution climate model

Synoptic atmospheric eddies are affected by lower tropospheric air-temperature gradients and by turbulent heat fluxes from the surface. In this study we examine how ocean fronts affect these quantities and hence the storm tracks. We focus on two midlatitude regions where ocean fronts lie close to the storm tracks: the north-west Atlantic and the Southern Ocean. An atmospheric climate model of reasonably high resolution (~50 km) is applied in a climate-length (60 year) simulation in order to obtain stable statistics. Simulations with frontal structure in the sea surface temperature (SST) in one of the regions are compared against simulations with globally smoothed SST. We show that in both regions the ocean fronts have a strong influence on the transient eddy heat and moisture fluxes, not just in the boundary layer, but also in the free troposphere. Local differences in these quantities between the simulations reach 20–40 % of the maximum values in the simulation with smoothed SST. Averaged over the entire region of the storm track over the ocean the corresponding differences are 10–20 %. The effect on the transient eddy meridional wind variance is strong in the boundary layer but relatively weak above that. The potential mechanisms by which the ocean fronts influence the storm tracks are discussed, and our results are compared against previous studies with regional models, Aquaplanet models, and coarse resolution coupled models.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Social identity, perception and motivation in adaptation to climate risk in the coffee sector of Chiapas, Mexico

Most investigation into climate adaptation to date has focused on specific technological interventions and socio-economic aspects of adaptive capacity. New perspectives posit that socio-cognitive factors may be as or more important in motivating individuals to take adaptive actions. Recent research indicates that incorporating insights from motivation theory can enhance theorization of adaptive capacity. Yet unexplored, and what we propose here, is the addition of social identity to models of adaptive capacity and adaptation. To apply this conceptual framework, the first author undertook in-depth interviews with a sample of farmers who had participated in broader surveys the previous year to explore their perceptions of their social identity, climate-related information and its sources, and climate risk. These interviews elicited compelling evidence that social identity mediates between risk perception and adaptation through its influence on motivation. Interviews revealed significant links between social identity and perception of information, risk perception and adaptation, of which the most salient were the relative credibility and legitimacy of information sources (related to us vs. them social group differentiation); the role of coffee organizations; and ethnicity and geographic marginalization. Strong in-group identity and perceptions of potentially influential out-groups such as the scientific community appear to particularly influence perception and use of information. These findings have rich policy implications for adaptation management and merit further investigation to identify how, where and why social identity plays a role in climate-risk perception, motivation and adaptation in other geographic areas of vulnerability worldwide.     

Canary in a coal mine: perceptions of climate change risks and response options among Canadian mine operations

A survey documenting how climate change is perceived and responded to by Canadian mine operations was administered to a random sample of practitioners working at mine sites across Canada. Key findings include: (1) Mines are sensitive to climatic hazards; (2) There is concern about climate change among mine practitioners, but the majority have not yet noticed climate change to be affecting operations; (3) Future climate change is expected to have negative impacts for mine operations; (4) Mines are responding to climate change mainly through efforts to reduce greenhouse gas emissions but also through adaptation, although to a lesser degree; and (5) Knowledge of future climate change projections and impacts is limited, potentially constraining understanding of the nature of climate change risks. The survey compliments previous work documenting perceptions among upper level management on climate change in the Canadian mining industry. The results from both surveys are largely consistent, establishing that the mining sector perceives climate change as an emerging risk and is developing response options, but needs to invest more time and resources for adaptation to what are inevitable changes in climate. The results support the need for targeted in-depth research to assess the vulnerability of mining to climate change and to evaluate response options.