Origin of quartz geodes from Laño and Tubilla del Agua sections (middle–upper Campanian,Basque‐Cantabrian Basin,northern Spain): isotopic differences during diagenetic processes

Quartz geodes and nodular chert have been found within middle–upper Campanian carbonate sediments from the Laño and Tubilla del Agua sections of the Basque‐Cantabrian Basin, northern Spain. The morphology of geodes together with the presence of anhydrite laths included in megaquartz crystals and spherulitic fibrous quartz (quartzine‐lutecite), suggest an origin from previous anhydrite nodules. The anhydrite nodules at Laño were produced by the percolation of marine brines, during a period corresponding to a sedimentary gap, with δ³⁴S and δ¹⁸O mean values of 18.8‰ and 13.6‰ respectively, consistent with Upper Cretaceous seawater sulphate values. Higher δ³⁴S and δ¹⁸O mean values of 21.2‰ and 21.8‰ recorded in the Tubilla del Agua section are interpreted as being due to a partial bacterial sulphate reduction process in a more restricted marine environment. The idea that sulphates may have originated from the leaching of previously deposited Keuper sulphate evaporites with subsequent precipitation as anhydrite, is rejected because the δ³⁴S, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values of anhydrite laths observed at both the Tubilla del Agua and Laño sections suggest an origin from younger marine brines. Later calcite replacement and precipitation of geode‐filling calcite is recorded in both sections, with δ¹³C and δ¹⁸O values indicating the participation of meteoric waters. Synsedimentary activity of the Peñacerrada diapir, which lies close to the Laño section, played a significant role in the local shallowing of the basin and the formation of quartz geodes. In contrast, eustatic shallowing of the inner marine series of the Tubilla del Agua section led to the generation of morphologically similar quartz geodes. Copyright © 2002 John Wiley & Sons, Ltd.     

Evaluation of trenching,ground penetrating radar (GPR) and electrical resistivity tomography (ERT) for sinkhole characterization

This paper explores the suitability and advantages of combining the trenching technique with geophysical surveys [ground penetrating radar (GPR) and electrical resistivity tomography (ERT)] for sinkhole characterization in a mantled karst area. The approach is applied to two active sinkholes concealed by anthropogenic deposits and formed by contrasting subsidence mechanisms; collapse and sagging. The ERT section acquired across the collapse sinkhole images the clayey fill of the depression as an obvious low resistivity area, showing the approximate location of the sinkhole edges. Spatially dense GPR surveys provide information on the position of the boundaries of the concealed subsidence structures and their three‐dimensional (3D) internal geometry, revealing the dominant subsidence mechanism. We illustrate the impact of several factors on the quality of the GPR data such as sinkhole size, nominal frequency of the antennas, antenna shielding, and the presence of backfilled excavations and above‐surface objects. Trenches provided detailed information on the subsurface structure of the sinkhole, subsidence magnitude, partitioning of the strain, and the position of the sinkhole edges, especially when they are deep enough and excavated across the central sector and perpendicular to the boundaries. The stratigraphic and structural relationships observed in the trench were then used to infer the spatial evolution of the sinkholes (e.g. enlargement), their kinematic behavior (episodic versus progressive), and to differentiate discrete subsidence events and their associated magnitude. Numerical dates were used to estimate average subsidence rates and the recurrence of subsidence events. Such integrated data sets may be used as an objective basis to forecast the future behavior of potentially damaging sinkholes and to assess the associated hazard and risk. Copyright © 2013 John Wiley & Sons, Ltd.     

Methane levels in shallow subtropical lake sediments: Dependence on the trophic status of the lake and allochthonous input

The vertical sediment profiles (10 cm) of the margins of three shallow subtropical lakes (Rio Grande, Brazil) with different trophic states and surrounding areas were evaluated to identify the effects of the allochthonous input on the methane concentration in the sediment. Sediment cores were collected to quantify the organic matter content (OM) and total carbon (TC), total nitrogen (TN), total phosphorous (TP) and methane (CH₄) concentrations.The three lakes were distinguished according to the trophic status and classified as oligotrophic, dystrophic and eutrophic. The natural characteristics of the dystrophic and eutrophic lakes have been changed due to the allochthonous input of leaves and twigs (Eucalyptus sp.) and the excreta of birds, respectively. In the eutrophic lake, the allochthonous input contributed to high autochthonous production. The highest values of OM, TC, TN and TP were found in the superficial sediments of the dystrophic and eutrophic lakes. The accumulation of allochthonous organic matter in the littoral zone promoted changes in the vertical sediment profiles and contributed to increases in the CH₄ concentrations in the sediment.     

New discoveries of mud volcanoes on the Moroccan Atlantic continental margin (Gulf of Cádiz): morpho-structural characterization

During the MVSEIS-08 cruise of 2008, ten new mud volcanoes (MVs) were discovered on the offshore Moroccan continental margin (Gulf of Cádiz) at water depths between 750 and 1,600?m, using multibeam bathymetry, backscatter imagery, high-resolution seismic and gravity core data. Mud breccias were recovered in all cases, attesting to the nature of extrusion of these cones. The mud volcanoes are located in two fields: the MVSEIS, Moundforce, Pixie, Las Negras, Madrid, Guadix, Almanzor and El Cid MVs in the western Moroccan field, where mud volcanoes have long been suspected but to date not identified, and the Boabdil and Al Gacel MVs in the middle Moroccan field. Three main morphologies were observed: asymmetric, sub-circular and flat-topped cone-shaped types, this being the first report of asymmetric morphologies in the Gulf of Cádiz. Based on morpho-structural analysis, the features are interpreted to result from (1) repeated constructive (expulsion of fluid mud mixtures) and destructive (gravity-induced collapse and submarine landsliding) episodes and (2) interaction with bottom currents.     

Site effects in 3D basins using 1D and 2D models: an evaluation of the differences based on simulations of the seismic response of Euroseistest

Site effects are one of the most predictable factors of destructive earthquake ground motion but results depend on the type of model chosen. We compare simulations of ground motion for a 3D model of the Mygdonian basin in northern Greece (Euroseistest) using different approximation for this basin. Site effects predicted using simple 1D models at many points inside the basin are compared to site effects predicted using four different 2D cross sections across the basin and with results for a full 3D simulation. Surface topography was neglected but anelastic attenuation was included in the simulations. We show that lateral heterogeneity may increase ground motion amplification by 100 %. Larger amplification is distributed in a wide frequency range, and amplification may occur at frequencies different from the expected resonant frequencies for the soil column. In contrast, on a different cross section, smaller conversion of incident energy into surface waves and larger dispersion leads to similar amplitudes of ground motion for 2D and 1D models. In general, results from 2D simulations are similar to those from a complete 3D model. 2D models may overestimate local surface wave amplitudes, especially when the boundaries of the basin are oblique to the selected cross section. However, the differences between 2D and 3D site effects are small, especially in regard of the difficulties and uncertainties associated to building a reliable 3D model for a large basin.     

Biomonitoring of coastal areas in Tunisia: Stable isotope and trace element analysis in the Yellow-legged Gull

We used Yellow-legged Gull (YLG) chicks to monitor trace elements in Tunisian areas subject to different pollution stresses: urban contamination (Chikly), industrial pollution (Thyna) and an unpolluted area (Kneis).We measured trace element concentrations (Hg, Se and Pb) in chick feathers. We also assessed their feeding ecology by analyzing both regurgitates and stable isotopes (SIA) in chick feathers and in their prey, to determine the main entry route of pollutants. SIA revealed that YLG feed mainly on aquatic resources from the Lake of Tunis (Chikly colony) and the Gulf of Gabès (Thyna and Kneis colonies). Moreover, the enriched δ¹⁵N found in feathers from Chikly are attributed to the eutrophication of the Lake of Tunis. Hg and Se were higher in Kneis and Thyna colonies, in agreement with the higher consumption of marine resources and the greater availability of these elements resulting from the impact of the industrial activity in the area. Pb concentrations were higher in Chikly, related to the heavier traffic around the Lake of Tunis and the use of leaded gasoline.