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11.
The flow of lava into the ocean at the shoreline of Kilauea Volcano during the ongoing Pu’u O’o eruption has allowed a detailed study of the geochemical interaction between lava and seawater. This paper focuses on the chemistry of the major and minor elements in the fluids that resulted from this interaction. The elemental enrichments in these fluids are dominated by three processes: (1) evaporation of water from seawater, which creates solutions enriched in the major elements found in seawater, (2) congruent dissolution of the basalt glass matrix, which is limited by the solubility of some of the elements in seawater, and (3) removal of volatile phases from the lava on contact with seawater.Using a simple model of volatile emanation (using published emanation coefficients) and congruent dissolution, we are able to explain the concentrations observed for the majority of elements in precipitation from the steam plume at the shoreline lava entry and in water allowed to interact with molten lava in controlled experiments. Fe, Al, Ti, and some of the rare earth elements (REEs) in precipitation samples from the steam plume at the lava entry were > 10,000-times enriched over their ambient seawater concentrations, suggesting that these elements may be useful for identifying submarine eruptions. The flux of elements from the Kilauea ocean lava entry is greater than that from a typical midocean ridge hydrothermal vent field for Al, Cd, Co, and the REEs, whereas the opposite is true for the remainder of the elements studied. 相似文献
12.
Philippe Telouk Estelle F. Rose-Koga Francis Albarede 《Geostandards and Geoanalytical Research》2003,27(1):5-11
Preliminary results are given from an excimer 157 nm laser ablation multiple-collector inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS), used for the isotopic measurements of solid materials. Elements of geological interest with different volatilities such as Pb and U (e.g. zircon geochronology) and Cu and Zn (as examples of geochemical/biochemical tracers) were analysed. The range of ablation rates of 20-150 nm s-1 enabled us to ablate the sample down to a depth of 45 μm for a 50 μm diameter pit. The Cu and Zn isotopic measurements gave values that were very stable with, on average, a 0.01 % standard error, comparable with that achieved in liquid mode measurements. 相似文献
13.
Francis Leo Collins 《New Zealand geographer》2004,60(1):52-59
This paper discusses some of the ways that international students, particularly those from East Asia, are involved in the transformation of urban space in Auckland City. Using existing economic reports, local media accounts and the author's initial observations, the paper identifies how the embodied and linguistic practices of international students are involved in the changing landscapes of Auckland's inner city. This cursory reading serves to identify a research agenda and to reflect upon some key theoretical textxs. The insights of Arjun Appadurai, Michael Peter Smith and Ulrich Beck are used to suggest that the changes in Auckland, whilst certainly local, are also influenced fry factors that emerge from beyond the borders of international students' origin communities, cities and nations. 相似文献
14.
High-resolution historical records from Pettaquamscutt River basin sediments: 2. Pb isotopes reveal a potential new stratigraphic marker 总被引:2,自引:0,他引:2
Ana Lúcia Lima Bridget A. Bergquist Matthew K. Reuer Francis O. Dudas Timothy I. Eglinton 《Geochimica et cosmochimica acta》2005,69(7):1813-1824
A high-resolution record of Pb deposition in Rhode Island over the past 250 yr was constructed using a sediment core from the anoxic Pettaquamscutt River basin. The sedimentary Pb concentration record shows the well-described maximum associated with leaded gasoline usage in the United States. Diminished Pb variability during recorded periods of local industrial activity (1735 to 1847) supports the greater importance of regional atmospheric lead transport vs. local inputs. The Pb isotopic composition at this site shows a clear maximum in anthropogenic 206Pb/207Pb in the mid-1800s. Similar peaks have also been observed in sediments from Chesapeake Bay and the Great Lakes, suggesting a common source. Possible causes for this event include mining and smelting of Pb ores in the Upper Mississippi Valley district, which accounted for almost all Pb production in the United States in that period. The timing of this event can provide an important stratigraphic marker for sediments deposited in the past 200 yr in the Northeastern United States. The downcore profile of anthropogenic 206Pb/207Pb provides a classic example of how changes in the mixture of ores for production of tetraethyl lead caused a regional-scale shift in the sedimentary record, and suggests that coal could have played a secondary role in Pb emissions after 1920. 相似文献
15.
Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola 下载免费PDF全文
Sylvie Leroy Nadine Ellouz‐Zimmermann Jordane Corbeau Frédérique Rolandone Bernard Mercier de Lépinay Bertrand Meyer Roberte Momplaisir José‐Luis Granja Bruña Anne Battani Céline Baurion Evgueni Burov Valérie Clouard Rémy Deschamps Christian Gorini Youri Hamon Manfred Lafosse Jottin Leonel Laetitia Le Pourhiet Pilar Llanes Estrada Nicolas Loget Francis Lucazeau Daniel Pillot Jeffrey Poort Kevin R. Tankoo José‐Luis Cuevas José‐Fernando Alcaide Claude Jean Poix Alfonso Muñoz‐Martin Serge Mitton Yamil Rodriguez Julien Schmitz Leonardo Seeber Andres Carbo‐Gorosabel Santiago Muñoz 《地学学报》2015,27(6):467-478
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary. 相似文献
16.
The issue of extending healthcare to marginalized underserved rural population remains a cardinal rhetoric policy of the Ghana Government. Meanwhile we note a growing inequity in terms of access and utilization of quality and affordable healthcare between urban and rural areas of the country. The Government of Ghana through its various policy initiatives in 2002 collaborated with civil societies with the aim of bringing healthcare to the doorsteps of rural folks in the country. Using a mixed method approach through a semi structured interviews and questionnaire administration, and focusing on the Community-based Health Planning and Services (CHPS) programme in Nsanfo community in the Mfanstiman municipal area, this study assesses the effectiveness and challenges confronting state–civil society partnership in co-producing a public good (healthcare). We found that synergy between the state (Mfanstiman Municipal Health Directorate) and the civil society (community health volunteers) has yielded positive results in bringing healthcare to the door steps as well as improving the health conditions of the local people in the study area. Nonetheless, certain challenges such as lack of volunteer motivation, deplorable state of the CHPS compound and logistics threaten the very existence of this collaboration. Our study has far reaching implications for healthcare planning in Ghana. 相似文献
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19.
Francis H. Chapelle Yuan Shen Eric W. Strom Ronald Benner 《Hydrogeology Journal》2016,24(6):1413-1422
Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L?1) and ultraviolet absorption coefficient values (a 254?<?5 m?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers. 相似文献
20.
Julian Damashek Karen L. Casciotti Christopher A. Francis 《Estuaries and Coasts》2016,39(4):1050-1071
Understanding rates of nitrogen cycling in estuaries is crucial for understanding their productivity and resilience to eutrophication. Nitrification, the microbial oxidation of ammonia to nitrite and nitrate, links reduced and oxidized forms of inorganic nitrogen and is therefore an important step of the nitrogen cycle. However, rates of nitrification in estuary waters are poorly characterized. In fall and winter of 2011–2012, we measured nitrification rates throughout the water column of all major regions of San Francisco Bay, a large, turbid, nutrient-rich estuary on the west coast of North America. Nitrification rates were highest in regions furthest from the ocean, including many samples with rates higher than those typically measured in the sea. In bottom waters, nitrification rates were commonly at least twice the magnitude of surface rates. Strong positive correlations were found between nitrification and both suspended particulate matter and ammonium concentration. Our results are consistent with previous studies documenting high nitrification rates in brackish, turbid regions of other estuaries, many of which also showed correlations with suspended sediment and ammonium concentrations. Overall, nitrification in estuary waters appears to play a significant role in the estuarine nitrogen cycle, though the maximum rate of nitrification can differ dramatically between estuaries. 相似文献