Slope stabilization in difficult conditions: the case study of a debris slide in NW Italian Alps

A case study of a debris slide (estimated volume of about 35,000 m³) is described in this paper. This slide occurred in April 2009 in the North Western Italian Alps (Aosta valley) and damaged the SR25 road along the Valgrisenche valley. Ground investigations started with severe safety and logistic issues being posed. Given the need to open as soon as possible the road, the design of the landslide stabilization works was carried out using a “design as you go” approach. The stabilization measures were conceived to be flexible in order to allow for changes and integration during construction, in line with the progressive refinement of the geological–geotechnical slope model being developed. Back analysis by means of the limit equilibrium method (LEM) and the finite element method (FEM) was used. Groundwater level rise following heavy rainfall and spring snow melting was found to be the main cause of the debris slide. The stabilization works were designed by using both the LEM and FEM methods. The stability conditions of the engineered slope were assessed based on the available performance monitoring data.     

Space/time tectono-sedimentary evolution of the Umbria-Romagna-Marche Miocene Basin (Northern Apennines, Italy): a foredeep model

The space/time evolution of the Umbria-Romagna-Marche domains of the northern Apennine Miocene foredeep is proposed. In this period, the turbidite siliciclastic sedimentation is represented mainly by the Miocene Marnoso-Arenacea Formation, which generally ends with mainly marly deposits. From the internal Apennine sectors (Umbria-Romagna domain) to the external Adriatic Margin (Marche domain) the siliciclastic succession overlies hemipelagic marly deposits (Schlier Formation). The whole depositional area can be considered as a single wide basin with depocenter or main sedimentation areas progressively migrating eastwards. This basin is characterized by some morphological highs which did not constitute real dams for the sedimentary flows (turbidity currents). Multiple feeding (arkose, litharenites, calcarenites) from different sources is related to palaeogeographical and palaeotectonic reorganization of the most internal, previously deformed, Apennine areas. The activation of the foredeep stage is marked by the beginning of the siliciclastic sedimentation (Late Burdigalian in the most internal sector). This sedimentation ends in the most external sector in the Early Messinian, pointing to a depositional cycle of about 9?C10?Ma. The diachronism of the base of the siliciclastic deposition proves to be almost 5?Ma. The syn-depositional compressional deformation, which shows a marked diachronism, affected the internal area of the foredeep in the Early-Middle Serravallian, and progressively migrated up to Late Miocene, involving more and more external sectors. The deformed siliciclastic sedimentary wedge constitutes an orogenic pile incorporated in the Apennine Chain, represented by different tectonic elements superimposed by means of NE-vergent thrusts. The main stratigraphic and tectonic events of the Toscana-Romagna-Marche Apennines are presented in a general framework, resulting also in a terminological revision.     

Numerical simulation of the tsunami generated by a past catastrophic landslide on the volcanic island of Ischia, Italy

The island of Ischia, Gulf of Naples, Italy, like many other volcanic islands is affected by mass failures, that are mainly related to secondary volcanic processes such as slope steepening and seismic shaking. The block resurgence of its main relief, Mount Epomeo, has been recognised to contribute cyclically to mass instability and cause landslides, that occasionally may reach the sea and start tsunamis. In this work we explore the consequences of the Ischia Debris Avalanche (IDA), a flank collapse that occurred in historical times, and involved the whole Mount Epomeo edifice including its submarine portion, and that may have caused gigantic sea waves affecting all the coasts of Ischia and of the Gulf of Naples. The IDA and the generated tsunami have been taken as the worst-case scenario for the occurrence of a new tsunami in the area. They have been simulated through numerical codes developed and maintained by the University of Bologna. The simulation shows that the IDA-induced tsunami attacks severely all the coasts of the Gulf of Naples with the highest waves obtained for the island of Ischia, the island of Capri and the peninsula of Sorrento. The propagation pattern of the IDA tsunami can be used to get hints on the impact that such an event may have had on early populations habiting Gulf of Naples, but also to get clues on the area that could be most severely hit by a tsunami generated by a smaller-scale landslide that may occur in the same source zone.     

Low reproductive success for copepods during a bloom of the non‐aldehyde‐producing diatom Cerataulina pelagica in the North Adriatic Sea

Egg production rates and/or hatching success in the copepods Acartia clausi, Calanus helgolandicus and Temora longicornis were negatively affected by a late spring (May–June 2003) phytoplankton bloom in the North Adriatic Sea, dominated mainly by the large diatom Cerataulina pelagica. Highest total concentrations of 3.3·10⁴ cells·ml^?1 were located in the vicinity of the Po River, which also corresponded to the area where the highest numbers of phaeophorbides were measured (0.779, 0.528 and 0.419 μg·l^?1, respectively, compared to an average of the remaining stations of 0.183 ± 0.049 SD), suggesting some grazing on the bloom. Phytoplankton biomass in terms of carbon was dominated by diatoms, representing on average 42% of total phytoplankton carbon and more than 80% at several stations. Cerataulina pelagica, Cyclotella spp., Chaetoceros spp. and small unidentified centric diatoms dominated the diatom community numerically but C. pelagica was by far the dominant diatom in terms of carbon due to its large cell size. This species represented more than 60% of the diatom biomass at nine of the 14 stations sampled, and was absent only at one station, which was the most offshore station sampled during the cruise. Although polyunsaturated aldehydes (PUAs) were not detected, other oxylipins which are hydroxy and keto derivatives of eicosapentaenoic and docosahexaenoic acids that affect copepod reproduction were found in these samples. Hence, we can attribute the negative impact of diatoms not only to PUAs, as previously believed, but also to these compounds. This is the first direct evidence of the presence of oxylipins other than PUAs in marine blooms dominated by diatoms.     

U?Pb and 40Ar?39Ar geochronology of Palaeozoic units in the northern Apennines: determining protolith age and alpine evolution using the Calamita Schist and Ortano Porphyroid

In the northern Apennines, the Palaeozoic basement involved in the Late Oligocene–Middle Miocene nappe stack contains metamorphic units for which hypothetical ages have been assigned on the basis of lithological correlations with the Palaeozoic formations of the Variscan chain in Sardinia. This uncertainty concerning the age poses limitations to reconstructing the Palaeozoic stratigraphy, defining the Alpine and pre‐Alpine histories and correlations with other domains of the Variscan chain. We present the U Pb age of detrital zircon and the ⁴⁰Ar ³⁹Ar age of metamorphic muscovite for the Calamita Schist and Ortano Porphyroid, two metamorphic units of undetermined Palaeozoic age cropping out in the eastern Elba Island. The radioisotopic data allows us to: (i) define the Early Carboniferous and Middle Ordovician ages for the Calamita Schist and Ortano Porphyroid, respectively, as well as their derivation (flysch deposit and magmatic rocks); (ii) pose some constraints concerning their alpine tectonic and metamorphic histories. These new data generate a more precise reconstruction of the Palaeozoic sequence in the northern Apennines, and they document that the Palaeozoic basement involved in the alpine deformation underwent internal stacking with an inversion of the original sequence. Copyright © 2010 John Wiley & Sons, Ltd.     

A Fe K-edge XAS study of amethyst

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.     

A hydraulic invariance‐based methodology for the implementation of storm‐water release restrictions in urban land use master plans

A hydraulic invariance (HI)‐based methodology was developed as a tool to support implementation of storm flow control measures into land use master plans (LUMPs) for urban catchments. The methodology is based on the use of simple hydrologic analysis to compare predevelopment and postdevelopment catchment flow release scenarios. Differently from previous literature examples, for which the parcel scale is usually considered for the analysis, HI was pursued assuming the LUMP areas of transformation as the basic units for assigning storm water control measures in the form of flow release restrictions. The methodology was applied to a case study catchment in the southern part of the City of Catania (Italy), for which the LUMP re‐design has been recently proposed. Simulations were run based on the use of the EPA‐Storm Water Management Model and allowed deriving flow release restrictions in order to achieve HI at the subcatchment level for design events of different return period.     

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.     

Morphometric and landsliding analyses in chain domain: the Roccella basin,NE Sicily,Italy

The dynamic interaction of endogenic and exogenic processes in active geodynamic context leads to the deterioration of the physico-mechanical characteristics of the rocks, inducing slopes instability. In such context, the morphometric parameters and the analysis of landslide distribution contribute to appraise the evolutive state of hydrographic basins. The aim of the study is the morphometric characterization of the Roccella Torrent basin (Rtb) located in South Italy. Landsliding and tectonic structure dynamically interact with the drainage pattern that records these effects and permits the definition of the evolutive geomorphic stage of the basin. The Air Photograph Investigation and field surveys permitted to draw the main geomorphic features, the drainage pattern of the Rtb, to calculate the morphometric parameters and to delimit the landslides’ bodies. Detailed analysis about the landslide distribution within a test site 17 km² wide were carried out to elaborate indicative indexes of the landslides type and to single out the lithotypes that are more involved in slope instability phenomena. The morphometric parameters indicate the rejuvenation state within the Rtb where the stream reaches show the effects of increased energy relief in agreement with the geological settings of this sector of the Apennine–Maghrebian Chain.