The upper Miocene diatomaceous sediments of the northernmost Mediterranean region: A lamina-scale investigation of an overlooked palaeoceanographic archive

During the late Miocene the Mediterranean experienced a dramatic intensification of opaline accumulation, recorded by the deposition of diatomaceous sediments. The fine lamination of these deposits potentially records annual to sub-annual palaeoceanographic processes that occurred during a critical phase of the geodynamic evolution of the Mediterranean basin, which eventually led to the Messinian salinity crisis. The diatomaceous facies has been interpreted by previous researchers as the product of intensified upwelling currents and of bottom anoxia formation in the Mediterranean basin. However, until now, no efforts have been made to unravel the sedimentological and micropalaeontological content of these deposits at the lamina-scale. This paper presents the first case study of a systematic scanning electron microscope-based morphological investigation of the diatomaceous sediments deposited during the late Miocene at the northernmost offshoot of the Mediterranean basin (Piedmont Basin, north-west Italy). Using a non-invasive analytical approach, six faciological components (laminae, laminated packets, non-laminated intervals, burrows, opal-rich aggregates and mixed pelletal structures) and their relationships are described and interpreted herein. Following the lamina-scale study of these sediments, an annual sedimentary cycle could be identified and an accumulation rate (ca 50 cm kyr⁻¹) inferred that is atypical for a setting actively influenced by upwelling. The role played by the entanglement of diatom valves in creating a physical barrier to the bioturbation is here emphasized as the main process responsible for the preservation of the laminated fabric of diatomaceous sediments, challenging the supposed role of deep anoxia. These results suggest that the late Miocene diatomaceous deposition in the Piedmont Basin cannot be univocally considered as a by-product of upwelling intensification and seafloor oxygen depletion.     

Anti-erosive effectiveness of Eucalyptus coppices through the cover management factor estimate

In this paper sediment yield data, measured from 1978 to 1994 in two small Calabrian basins (W2 and W3) reafforested with eucalyptus trees (Eucalyptus occidentalis Engl.), and the Modified Universal Soil Loss Equation (MUSLE) applied in a distributed form are used to evaluate the anti-erosive effects of eucalyptus cover. At first step the sediment yield measurements observed in W2 basin are used to estimate a single cover management factor representative of the eucalyptus coppice and equal to the median value (0·164) of the cover management factor values calculated for each runoff event. Then, the reliability of the selected representative cover management factor is verified on W3 by comparing the cumulative distribution function (CDF) of the measured sediment yield with the CDF of the calculated one. Finally, the temporal analysis of the crop and management factor is developed searching, at monthly and annual scale, the correlation between crop anti-erosive effectiveness and rainfall erosivity index. © 1998 John Wiley & Sons, Ltd.     

An ecotoxicological protocol with caged mussels, Mytilus galloprovincialis, for monitoring the impact of an offshore platform in the Adriatic Sea

An ecotoxicological protocol with caged mussels, Mytilus galloprovincialis, was developed to evaluate the potential impact of an offshore gas platform in the central Adriatic Sea. Reference organisms were collected on a seasonal basis from an unpolluted site and transplanted for four weeks in both the sampling area and to the investigated platform. Chemical analyses of trace metals in mussel tissues were integrated with a multi-biomarker approach for the early detection of biological responses at several cellular targets. Induction of metallothioneins, peroxisomal proliferation and activity of acetylcholinesterase were measured as markers for specific classes of chemicals. Special attention was given to oxyradical metabolism and appearance of oxidative-mediated toxicity to reveal a more general onset of cellular disturbance. In addition to individual antioxidants (superoxide dismutase, catalase, glutathione S-transferases, glutathione reductase, Se-dependent and Se-independent glutathione peroxidases, and levels of total glutathione), the total oxyradical scavenging capacity (TOSC) allowed a quantification of the overall capability to neutralize specific forms of intracellular reactive oxygen species (ROS; i.e. peroxyl and hydroxyl radicals). Cellular damages were evaluated as lysosomal destabilization (membrane stability, accumulation of lipofuscin and neutral lipids), lipid peroxidation products (malondialdehyde) and DNA integrity (strand breaks and micronuclei); the air survival test was finally applied to evaluate the overall physiological condition of mussels. Concentration of trace metals (As, Ba, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Zn) revealed only limited variations in transplanted mussels during various experimental periods and such changes appeared partly related to natural fluctuations. Among biological responses, variations of antioxidants and lysosomal stability were confirmed as sensitive early warning signals for biological disturbance of both natural and anthropogenic origin. The presented protocol with caged mussels allowed marked biological effects caused by the investigated platform to be excluded, and represented a useful approach that is easy to extend for monitoring the impact of offshore activities in the Adriatic sea.     

Physical dynamics and biological implications of Cyclone Noah in the lee of Hawaii during E-Flux I

Quasi-synoptic observations of the horizontal and vertical structure of a cold-core cyclonic mesoscale eddy feature (Cyclone Noah) were conducted in the lee of Hawai’i from November 4–22, 2004 as part of the E-Flux interdisciplinary collaborative research program. Cyclone Noah appears to have spun up to the southwest of the ‘Alenuihaha Channel (between Maui and Hawai’i) as a result of strong and persistent northeasterly trade winds through the channel. Shipboard hydrographic surveys 2.5 months later suggest that Noah weakened and was in a hypothesized spin-down phase of its life cycle. Although the initial surface expression of Noah was limited in scale to 40 km in diameter and, as evidenced by surface temperatures, 2–3 °C cooler than the surrounding waters, depth profiles revealed a fully developed semi-elliptical shallow feature (200 m), 144 km long and 90 km wide (based on sigma-t=23 kg m⁻³) with tangential speeds of 40–80 cm s⁻¹, and substantial isopycnal doming. Potential vorticity distribution of Noah suggests that radial horizontal flow of the core water was inhibited from the surface to depths of 75 m, with high vorticity confined above the sigma-t=23.5 kg m⁻³ isopycnal surface. Upward displacements of isopycnal surfaces in the eddy's center (50 m) were congruent with enhanced pigment concentrations (0.50 mg m⁻³). Comparisons of the results obtained for E-Flux I (Noah) and E-Flux III (Opal) suggest that translation characteristics of cyclonic Hawaiian lee eddies may be important in establishing the biogeochemical and biological responses of the oligotrophic ocean to cyclonic eddies.     

The transient oasis: Nutrient-phytoplankton dynamics and particle export in Hawaiian lee cyclones

Macronutrients, photosynthetic pigments, and particle export were assessed in two eddies during the E-Flux I and III cruises to investigate linkages between biogeochemical properties and export flux in Hawaiian lee cyclonic eddies. Cyclone Noah (E-Flux I), speculated to be in the ‘decay’ stage, exhibited modest increases in macronutrients and photosynthetic pigments at the eddy center compared to ambient waters. Cyclone Opal (E-Flux III) also exhibited modest increases in macronutrient concentrations, but a 2-fold enhancement in total chlorophyll a (TChl a) concentration within the eddy center. As indicated by fucoxanthin concentrations, the phytoplankton community in the deep chlorophyll maximum (DCM) of Opal was comprised mainly of diatoms. During an 8-day time series in the center of Opal, TChl a concentration and fucoxanthin in the DCM decreased by 50%, which was potentially triggered by silicic acid limitation. Despite the presence of a substantial diatom bloom, Opal did not deliver the expected export of particulate carbon and nitrogen, but rather a large biogenic silica export (4-fold increase relative to export in surrounding waters). Results suggest that controls on the life cycle of a Hawaiian lee cyclone are likely a combination of physical (eddy dynamics), chemical (nutrient limitation), and biological (growth and grazing imbalance) processes. Comparisons between Noah and Opal and previously studied cyclones in the region point to a relationship between the spin-up duration of a cyclone and the resulting biological response. Nonetheless, Hawaiian lee cyclones, which strongly influence the biogeochemistry of areas 100's of km in scale in the subtropical North Pacific Ocean, still remain an enigma.     

Petrographic evidence of the past occurrence of gas hydrates in the Tertiary Piedmont Basin (NW Italy)

Methane-derived rocks in Monferrato and the Tertiary Piedmont Basin (NW Italy) consist of seep carbonates, formed by gas seepage at the seafloor, and macroconcretions resulting from the cementation of buried sediments crossed by gas-rich fluids. These rocks are characterized by both negative δ¹³C values and a marked enrichment in δ¹⁸O. Petrographic features not commonly described and that point to enigmatic depositional and diagenetic conditions have been observed in both types of rocks: inhomogeneous distribution of cements within cavities; dolomite crystals floating within cavity-filling calcite spar; non-gravitational fabrics of internal sediments plastering cavity walls; open framework within microbial crusts. These features suggest the former presence of gas hydrates in sediments. During their dissociation, new space was formed and filled with authigenic carbonates or injected sediments. Analogous mechanisms of clathrate freeze-and-thaw processes have been inferred for the genesis of zebra and stromatactis structures and particular kinds of carbonate breccias. The term melt-seal structure is proposed for this kind of diagenetic structure. The fabrics of gas hydrates and the geochemical conditions of sediments, in turn depending on the relative rates of supply of methane-rich fluids and normal seawater, conditioned the final aspect of the rocks.     

Improving radiometry of imaging spectrometers by using programmable spectral regions of interest

Programmable imaging spectrometers can be adjusted to fit specific application requirements that differ from the instrument initial spectral design goals. Sensor spectral characteristics and its signal-to-noise ratio (SNR) can be changed by applying customized online binning patterns.We present a software utility that generates application driven spectral binning patterns by using an SNR dependent sensor model. The utility, named BinGO (BInning patterN Generator and Optimiser), is used to produce predefined binning patterns that either (a) allow an existing imaging spectrometer to optimize its spectral characteristics for a specific application, (b) allow an existing imaging spectrometer to spectral and/or spatially emulate another instrument, or (c) design new multispectral or imaging spectrometer missions (i.e. spaceborne, airborne, terrestrial). We present a variety of BinGO case studies, including the simulation of airborne (APEX) [Itten, K.I. et al., 2008. APEX — The hyperspectral ESA Airborne Prism Experiment. Sensors 8(1), 1–25], spaceborne (SENTINEL III) [Nieke, J., Frerick, J., Stroede, J., Mavrocordatos, C., Berruti, B., 2008. Status of the optical payload and processor development of ESA’s Sentinel 3 mission. In: Proceedings of the Geoscience and Remote Sensing Symposium IGARSS 2008, pp. 427–430], as well as scientific and performance optimized approaches. We conclude that the presented approach can successfully be used to increase the efficiency of spectral information retrieval by using imaging spectroscopy data and to simulate various missions and requirements, finally supporting proper trade-off decisions to be made between performance optimization and scientific requirements. In addition, if specific sensor parameters are known, BinGO can also model other imaging spectrometers.