Geochemical assessment,mixing behavior and environmental impact of thermal waters in the Guelma geothermal system,Algeria

A study of thirteen geothermal springs located in the geothermal field of Guelma, northeastern Algeria, was conducted. Samples were collected during the period between January 2014 and February 2016. Geochemical processes responsible for the chemical composition of thermal and mineralized water were evaluated. The hydrochemical analysis shows that the thermal waters are characterized by the presence of two different chemical facies, the first type SO₄–Ca in the east, west and south of Guelma, the second type HCO₃–Ca in the south. This analysis also attributed to sodium, chlorides, and sulfates to an evaporitic terrigenous origin by the molar ratio Sr²⁺/Ca²⁺. The thermal spring waters from Guelma geothermal system have a meteoric origin, and all samples are immature with strong mixing between hot and shallow waters with 19–38.5% rate of mixing. The silica geothermometer shows that these thermal waters have a temperature varying from 84 to 122 °C and that the water came from a depth of 2100–3000 m through a fault system that limits the pull-apart basin of Guelma. Potential environmental effluent from thermal spas could pollute in both the irrigation and drinking waters, and which imposes danger on the health of the inhabitants of the region.

     

Effects of long-term irrigation with treated wastewater. Part II: Role of organic carbon on Cu,Pb and Cr behaviour

The long-term impact of irrigation on a Mediterranean sandy soil irrigated with treated wastewater (TWW) since 1980 was evaluated. The main soil properties (CEC, pH, size distribution, exchangeable cations and chloride, hydraulic conductivity) as well as the organic matter and Cu, Cr and Pb speciation in an irrigated soil and a non-irrigated control soil at various soil depths were monitored and compared during a 2 year experiment. In this second part, we focused on Cu, Cr and Pb behaviour in relation with soil organic carbon (SOC). Soil samples were collected every 3 months during 2 years at the depths 0–20, 20–40 and 40–60 cm and were analysed for exchangeable and total metals, organic carbon content, metal sequential extraction and humic substances – Humic Acids (HA), Fulvic Acids (FA) and Non-Humified Fraction (NHF). Long-term irrigation with a domestic treated wastewater (TWW) may be considered safe with regard to trace metal accumulation in soil. Irrigation lowered the HA and NHF fractions of SOC and made the FA fraction more mobile. Cu bound preferentially to the SOC fraction, Cr was found mainly in the reducible fraction and Pb was bound to all fractions indiscriminately. Cu exhibited a high affinity for the HA fraction, while Pb and Cr had a high affinity for the FA fraction, which indicates a greater mobility of the organically-bound Pb and Cr than of the organically-bound Cu. Evaluation of the potential metal mobility has to take into account not only the usual speciation between labile, reducible and oxidisable fractions, but also the nature of the SOC responsible for the oxidisable fraction.     

Temporal and spatial changes of the submarine Cretaceous paleoslope in Northern Tunisia,inferred from slump folds analysis

This paper presents the first comprehensive, non-exhaustive, study of the genetic relationship between slump folds and the synsedimentary paleoslope during Cretaceous time in northern Tunisia. Slump folds occur mainly in the Cretaceous marl-dominated lithofacies, which exposes numerous slump folds structures. In addition, fault kinematic analysis is conducted to define the paleostress fields and the stress states characterizing the Cretaceous extension that triggers soft-sediment deformation and slumping. The MAM and the APM methods are used to deduce the paleoslope in several localities. The calculated values of paleoslope trend derived from MAM and APM methods precise the variation of the paleoslope trend during Cretaceous times in northern Tunisia. This paleoslope is ～NW-dipping during Berriasian, ～SSW-dipping during Valanginian, ～NW-dipping during the Barremian and ～N- to ～NNE or ～S- to ～SSW-dipping during Aptian–Albian period. The results of the back-tilted fault diagram show a ～North to ～Northeast-trending tectonics extension. The back-tilting of Cenomanian slump axis and poles of axial planes (MAM and APM methods) give close results with ～Southward or ～Northward-dipping paleoslope. The restored fault diagrams show ～North to ～Northeast-trending extension during Cenomanian times. Coniacian-Santonian marls deposits seal all the gravity-driven deformation structures. North Tunisian area exposes evidences for abundant soft-sediment deformation and slumping atop a northward facing submarine slope, which was probably dominant from the Early Cretaceous to Santonian with ～North-South tectonic extension related to the Southern Tethyan rifted continental margin evolution.     

Manifestations tectono-diapiriques synsédimentaires et polyphasées d'âge Crétacé supérieur–Quaternaire dans la région de Zag Et Tir (Tunisie centre-nord)

The geodynamic evolution of the diapir of Zag Et Tir is the result of the coexistence of the diapiric and tectonic activity from the Upper Cretaceous until the Quaternary. The interference of the tectonic and diapiric phenomena is at the origin of the basin individualization with differential sedimentation during the Miocene. This explains the current distribution of the Neogene deposits on both sides of Zag Et Tir Triassic structure. The submeridian faults that subdivide our sector played a significant role during the Atlasic compression, inducing an unequal distribution of the folds on both sides of these accidents, as well in kind as in number, showing the anteriority of the faults compared to the folds. To cite this article: R.A. Gharbi et al., C. R. Geoscience 337 (2005).     

Hydrogeochemistry and geothermometry of thermal springs from the Guelma region,Algeria

This paper reports the results of our studies, the chemical analysis of thermal spring’s waters and their geological settings, the use of different statistical methods to evaluate the origin of the dissolved constituents of spring waters and the estimation of the reservoir temperature of the associated geothermal fields of the Guelma region, Algeria. A major component in 13 spring water samples was analyzed using various techniques. The waters of the thermal springs at Guelma basin vary in temperature between 20 and 94oC. Q-mode hierarchical cluster analysis suggests three groups. The water springs were classified as low, moderate and high salinity. Mineral saturation indices (SI) calculated from major ions indicate the spring waters are supersaturated with the most of the carbonate minerals, and all of the spring water samples are under-saturated with evaporite minerals. The thermal spring waters have a meteoric origin, and all samples are immature with strong mixing between warm and shallow waters, where the temperatures of reservoirs to which the thermal waters are related ranged between 64° and 124°C. The deep circulation of meteoric waters in the study area is supplied by the high geothermal gradient around 4.5°C per 100 m and reaches a high temperature before rising to the surface. The estimated circulation depths ranged from 1425 and 3542 m.     

Heavy metal distribution in soil and plant in municipal solid waste compost amended plots

A field study was carried out to evaluate long-term heavy metal accumulation in the top 20 cm of a Tunisian clayey loam soil amended for four consecutive years with municipal solid waste compost at three levels (0, 40 and 80 t/ha/y). Heavy metals uptake and translocation within wheat plants grown on these soils were also investigated. Compared to untreated soils, compost-amended soils showed significant increases in the content of all measured metals: cadmium, chromium, copper, nickel, lead and zinc in the last three years, especially for plots amended with municipal solid waste compost at 80 t/ha/y. Wheat plants grown on compost-amended soils showed a general increase in metal uptake and translocation, especially for chromium and nickel. This heavy metal uptake was about three folds greater in plots amended at 80 t/ha/y as compared to plots amended at 40 t/ha/y. At the end of the experimental period, the diluting effect resulting from enhanced growth rates of wheat plants due to successive compost applications resulted in lower concentrations in the plants (grain part) grown on treated plots. On the other hand, chromium and nickel were less mobile in the aerial part of wheat plants and were accumulated essentially in root tissues. Plant/soil transfer coefficients for compost-amended treatments were higher than threshold range reported in the literature, indicating that there was an important load/transfer of metal ions from soils to wheat plants.     

Fluage du sel gemme sous très faibles charges

Long-term creep tests have been performed under very small uniaxial loadings ($\sigma =0.02$ to 0.1 MPa). Testing devices were set in an underground gallery, where temperature fluctuations are in the order of one hundredth of a Celsius degree. The mechanical loading was provided by dead weights. The displacements were measured through special sensors whose resolution is $\mathrm{\Delta }?={10}^{\mathrm{?8}}$. Strain rates as small as $\dot{?}={10}^{\mathrm{?12}}{\text{s}}^{\mathrm{?1}}$ were measured. The tests prove that constitutive laws deduced from tests performed on rock salt samples under standard mechanical loadings cannot be extrapolated to very small loadings. To cite this article: P. Bérest et al., C. R. Geoscience 336 (2004).     

Cretaceous paleomargin tilted blocks geometry in northern Tunisia: stratigraphic consideration and fault kinematic analysis

New stratigraphic data, lithostratigraphic correlations, and fault kinematic analysis are used to discuss the basin geometry and sedimentation patterns of the northeastern Tunisia during Cretaceous times. Significant facies and thickness variations are deduced along the northeastern Atlas of Tunisia. The NW-SE 80-km-long regional correlation suggests a high sedimentation rate associated with irregular sea floor. The fault kinematic analysis highlights N-S to NE-SW tectonic extension during Early Cretaceous. During Aptian–Albian times, an extensional regime is recognized with NE-SW tectonic extension. The Cenomanian–Turonian fault populations highlight a WNW-ESE to NW-SE extension, and Campanian–Maastrichtian faults illustrate an NW-SE extension. The normal faulting is associated to repetitive local depocenters with a high rate of sedimentation as well as abundant syntectonic conglomeratic horizons, slump folds, and halokinetic structures. The sequence correlation shows repetitive local depocenters characterizing the basin during Early Cretaceous times. All the above arguments are in favor of basin configuration with tilted blocks geometry. This geometry is shaped by major synsedimentary intra-basin listric normal faults, themselves related to the extensional setting of the southern Tethyan paleomargin, which persisted into the Campanian–Maastrichtian times. The results support a predominant relationship between tilted blocks geometry and sedimentation rather than E-W “Tunisian trough” as it was previously accepted.     

Effects of long-term irrigation with treated wastewater. Part I: Evolution of soil physico-chemical properties

The long-term impact of irrigation on a Mediterranean sandy soil irrigated with Treated wastewater (TWW) since 1980 was evaluated. The main soil properties (CEC, pH, size distribution, exchangeable cations and chloride, hydraulic conductivity) as well as the organic matter and Cu, Cr and Pb speciation in an irrigated soil and a non-irrigated control soil at various soil depths were monitored and compared during a 2 years experiment. In this first part, the evolution of the physico-chemical soil properties was described. The irrigation with TWW was beneficial with regard to water and nutrient supplying. All the exchangeable cations other than K⁺ were higher in the irrigated soil than in the reference one. A part of the exchangeable cations was not fixed on the exchange complex but stored as labile salts or in concentrated soil solution. Despite the very sandy soil texture, both saturated and unsaturated hydraulic conductivity exhibited a significant diminution in the irrigated soil, but remained high enough to allow water percolation during rainy periods and subsequent leaching of accumulated salts, preventing soil salinization. In the irrigated soil, exchangeable sodium percentage (ESP) exhibited high values (20% on average) and the soil organic C was lower than in the reference. No significant effect was noticed on soil mineralogical composition due to irrigation.