Correlation studies on an RC frame shaking-table specimen

This paper presents the correlation of the results of a new model for the dynamic analysis of reinforced concrete (RC) frames with the experimental time history of a two storey RC frame shaking-table specimen. The frame member model consists of separate subelements that describe the deformations due to flexure, shear and bond slip in RC structural elements. The subelements are combined by superposition of flexibility matrices to form the frame element. A non-linear solution method which accounts for the unbalance of internal forces between different subelements during a given load increment is used with the model. The ability of the proposed model to describe the dynamic response of frame structures under earthquake excitations is evaluated by comparing the analytical results with experimental evidence from a two-storey, one bay reinforced concrete frame tested on the shaking-table. The model parameters for the shaking-table specimen are derived from available experimental evidence and first principles of reinforced concrete. The effect of reinforcing bar slip on the local and global dynamic response of the test structure is assessed. © 1997 John Wiley & Sons, Ltd.     

Crystal chemistry and OH defect concentrations in spodumene from different granitic pegmatites

Thirty spodumene samples of distinct paragenetic types (primary magmatic, secondary after petalite and hydrothermal) from variety of granitic pegmatites were characterized by electron microprobe, polarized FTIR spectroscopy and Mössbauer spectroscopy. The FTIR spectra of OH (weak sharp pleochroic bands at 3,425, 3,410, 3,395 cm⁻¹ and in the 3,500–3,470 spectral region) are strongly polarized with maximum absorption parallel to n_γ. The majority of OH dipoles are presumably generated by a partial replacement of O2 oxygen atoms with an orientation pointing above the Li vacancy site. The separation of the bands probably resulted from a replacement of the coordinating Al by Fe and Si by Al. Homogeneous spodumene mostly close to its ideal formula LiAlSi₂O₆ shows Fe (0.00–0.10 apfu as Fe³⁺; Fe³⁺ >> Fe²⁺) and Na (0.00–0.04 apfu) as the only minor cations and Fe³⁺Al₋₁ substitution up to 10 mol% of the LiFe³⁺Si₂O₆ component. Hydrogen concentrations (from 0.1 up to <5 ppm H₂O by weight) vary as a function of genetic type with the highest amounts in high-temperature magmatic spodumene. Differences among particular genetic types of spodumene are related to maximum solubility of OH in spodumene structure at given P–T conditions and at actual chemical composition of spodumene. OH defect concentrations in spodumene follow a trend, LT/LP pyroxenes containing lower hydrogen contents compared to HT/HP ones. The hydrogen contents in particular genetic types of spodumene and their decrease with decreasing T and P are consistent with petrologic models of the pegmatite (sub)types formations.     

On possible fluid detection in equivalent transversely isotropic media

We consider a transversely isotropic medium that is long-wave equivalent to a stack of thin, parallel, isotropic layers and is obtained using the Backus average. In such media, we analyse the relations among anisotropy parameters; Thomsen parameters, ε and δ, and a new parameter ϕ. We discuss the last parameter and show its essential properties; it equals 0 in the case of isotropy of equivalent medium and/or constant Lamé coefficient λ in layers. The second property occurs to make ϕ sensitive to variations of λ in thin-bedded sequences. According to Gassmann, in isotropic media the variation of fluid content affects only the Lamé coefficient λ, not μ; thus, the sensitivity to changes of λ is an essential property in the context of possible detection of fluids. We show algebraically and numerically that ϕ is more sensitive to these variations than ε or δ. Nevertheless, each of these parameters is dependent on the changes of μ; to understand this influence, we exhibit comprehensive tables that illustrate the behaviour of anisotropy parameters with respect to specific variations of λ and μ. The changes of μ in layers can be presented by the Thomsen parameter γ that depends on them solely. Hence, knowing the values of elasticity coefficients of equivalent transversely isotropic medium, we may compute ϕ and γ, and based on the aforementioned tables, we predict the expected variation of λ; in this way, we propose a new method of possible fluid detection. Also, we show that the prior approach of possible detection of fluids, proposed by Berryman et al., may be unreliable in specific cases. To establish our results, we use the Monte Carlo method; for the range and chosen variations of Lamé coefficients λ and μ – relevant to sandstones – we generate these coefficients in thin layers and, after the averaging process, we obtain an equivalent transversely isotropic medium. We repeat that process numerous times to get many equivalent transversely isotropic media, and – for each of them  – we compute their anisotropy parameters. We illustrate ϕ, ε and δ in the form of cross-plots that are relevant to the chosen variations of λ and μ. Additionally, we present a table with the computed ranges of anisotropy parameters that correspond to different variations of Lamé coefficients.     

Degradation and Transformation of Aquatic Humic Substances by Laccase-producing Fungi Cladosporium cladosporioides and Polyporus versicolor

A phenoloxidase-producing fungus – Cladosporium cladosporioides – was isolated from water of a bog lake. At high concentrations of carbon (333 mM) and nitrogen (12 mM), the fungus demonstrated the formation of a laccase and a high ligninolytic activity. After addition of riverine or groundwater humic substances into culture media (ca. 1 mg mL^–1), the fungus showed the ability of degrading (utilizing) of about 60% of these substances. However, the exact quantification of the degree of degradation was difficult because of adsorption of humic matter on fungal mycelium. Reisolated humic substances were lower in aromatic and higher in aliphatic structures. A crude enzyme from the C. cladosporioides culture showed only low activity in decolorizing humic substances, whereas decolorization up to 50% was observed when using a laccase preparation from Polyporus versicolor, and especially in the presence of a redox mediator.     

Macroscopic diffusivity in concrete determined by computational homogenization

Effective moisture and chloride ion diffusivity coefficients for concrete are determined by computational homogenization, where concrete is modeled on the mesoscale as a heterogenous three‐phase composite material. By imposing moisture and chloride ion gradients on a representative volume element, effective macroscale properties are obtained through finite element analysis. A parametric study of the effects of the ballast content was carried out. The numerical results correspond well with an estimate of the Hashin–Shtrikman type available in the literature. The computational homogenization strategy proposed here also includes the interfacial transition zone, and its influence on the effective diffusivity coefficients is assessed. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial analysis of high-resolution urban thermal patterns in Vojvodina,Serbia

Main objective of this study was to establish a relationship between land cover and land surface temperature (LST) in urban and rural areas. The research was conducted using Landsat, WorldView-2 (WV-2) and Digital Mapping Camera. Normalised difference vegetation index and normalised difference built-up index were used for establishing the relation between built-up area, vegetation cover and LST for spatial resolution of 30 m. Impervious surface and vegetation area generated from Digital Mapping Camera from Intergraph and WV-2 were used to establish the relation between built-up area, vegetation cover and LST for spatial resolutions of 0.1, 0.5 and 30 m. Linear regression models were used to determine the relationship between LST and indicators. Main contribution of this research is to establish the use of combining remote sensing sensors with different spectral and spatial resolution for two typical settlements in Vojvodina. Correlation coefficients between LST and LST indicators ranged from 0.602 to 0.768.     

Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.     

Blue, complexly zoned, (Na,Mg,Fe,Li)-rich beryl from quartz-calcite veins in low-grade metamorphosed Fe-deposit Sk��ly near Ryma?ov, Czech Republic

Syn-tectonic quartz-calcite veins containing blue beryl are enclosed in hematite > magnetite-rich portions of the low-grade metamorphosed Fe-deposit Skály near Ryma?ov, Czech Republic. Aggregates of pale to deep blue beryl, up to 2?cm in diameter, are associated with euclase, clinochlore, hematite, albite and dravite. Complexly zoned beryl crystals consist of skeletal aggregates of beryl I randomly distributed within volumetrically dominant beryl II with narrow rims of beryl III. All types of beryl have similar contents of Na (0.32?C0.49 apfu) and Mg (0.31?C0.41 apfu) but variable contents of Fe_tot (0.05?C0.34 apfu) and Al (1.20?C1.62 apfu). The LA-ICP-MS study yielded elevated contents of Li, up 1,314?ppm (0.28?wt.% Li₂O) in beryl I. The quartz-calcite veins represent an unusual type of low-T metamorphic-hydrothermal vein related to Fe-ore deposit characterized by single-stage fracturing and mobilization in a closed system at T~200?C300°C and CO ₃ ^2- as a major complexing agent for the mobility of Be.