This study focused on the target injection layers of deep saline aquifers in the Shiqianfeng Fm. in the Carbon Capture and Sequestration (CCS) Demonstration Projects in the Ordos Basin, northwestern China. The study employed a combination method of experiments and numerical simulation to investigate the dissolution mechanism and impact factors of CO2 in these saline aquifers. The results showed (1) CO2 solubility in different types of water chemistry were shown in ascending order: MgCl2-type water < CaCl2-type water < Na2SO4-type water < NaCl-type water < Na2CO3-type water < distilled water. These results were consistent with the calculated results undertaken by TOUGHREACT with about 5% margin of error. CO2 solubility of Shiqianfeng Fm. saline was 1.05 mol/L; (2) compared with distilled water, the more complex the water’s chemical composition, the greater the increase in HCO3?concentration. While the water’s composition was relatively simple, the tested water’s HCO3?concentrations were in close accord with the calculated value undertaken by the TOUGHREACT code, and the more complex the water’s composition, the poorer the agreement was, probably due to the complex and unstable HCO3? complicating matters when in an aqueous solution system including both tested HCO3?concentration and calculated HCO3?concentration; (3) the CO2 solubility in the saline at the temperature conditions of 55 °C and 70 °C were 1.17 and 1.02 mol/L. When compared with the calculated value of 1.20 and 1.05 mol/L, they were almost the same with only 1 and 3% margin of error; concentrations of HCO3? were 402.73 mg/L (0.007 mol/L) and 385.65 mg/L (0.006 mol/L), while the simulation results were 132.16 mg/L (0.002 mol/L) and 128.52 mg/L (0.002 mol/L). From the contrast between the tested data and the calculated data undertaken by the TOUGHREACT code, it was shown that TOUGHRACT code could better simulate the interaction between saline and CO2 in the dissolution sequestration capacity. Therefore, TOUGHREACT code could be used for the inter-process prediction of CO2 long-term geological storage of CO2; (4) The Ca2+ concentration and SO42?concentration in saline water had less effect on the solubility of CO2 and HCO3?concentration. In addition, TDS and pH values of saline affected not only the solubility of CO2, but also the conversion of CO2 to HCO3? due to that they can affect the activity and acid-base balance. So in fact, we just need to consider that the TDS and pH values are main impact factors in the dissolution sequestration capacity of CO2 geological sequestration in deep saline aquifers. 相似文献
This paper briefly presents the research progress of the State Major Basic Research Project 2001CB309400, “Theory and Application
for Retrieval and Fusion of Spatial and Temporal Quantitative Information from Complex Natural Environment”. Based on the
rapid advancement of synthetic aperture radar (SAR) imagery technology, information theory of fully polarimetric scattering
and applications in polarimetric SAR remote sensing are developed. To promote the modeling of passive microwave remote sensing,
the vector (polarized) radiative transfer theory (VRT) of complex natural media such as inhomogeneous, multi-layered and 3-dimensional
VRT is developed. With these theoretical progresses, data validation and retrieval algorithms for some typical events and
characteristic parameters of earth terrain surfaces, atmosphere, and oceans from operational and experimental remote sensing
satellites are studied. Employing remote sensing, radiative transfer simulation, geographic information systems (GIS), land
hydrological process, and data assimilation, the Chinese land data assimilation system (CLDAS) is established. Towards the
future development of China’s microwave meteorological satellites, employing remote sensing data of currently available SSM/I
(special sensor microwave/imager), AMSU (advanced microwave sounding unit), MTI (microwave temperature imager), etc., with
ground-based measurements, several operational algorithms and databases for atmospheric precipitation, water vapor and liquid
water in clouds, and other hydrological/hydrological applications are developed. To advance China’s SAR and InSAR (interferometric
SAR) technologies, the image processing and analysis of ERS (European remote sensing), Radarsat SAR, and Chinese SAR, etc.,
the software platforms are accomplished. Based on the researches of multi-information fusion, some simulations, identification,
and information extractions of the targets from complex background clutter scenes are studied. Some experiments of radio wave
propagation in anomalous atmospheric status are also carried out.
Translated from Advances in Earth Science, 2007, 22(2): 111–125 [译自: 地球科学进展] 相似文献
Subsurface-water flow pathways in three different land-use areas (non-irrigated grassland, poplar forest, and irrigated arable land) in the central North China Plain were investigated using oxygen (18O) and hydrogen (2H) isotopes in samples of precipitation, soils, and groundwater. Soil water in the top 10 cm was significantly affected by both evaporation and infiltration. Water at 10–40 cm depth in the grassland and arable land, and 10–60 cm in poplar forest, showed a relatively short residence time, as a substantial proportion of antecedent soil water was mixed with a 92-mm storm infiltration event, whereas below those depths (down to 150 cm), depleted δ18O spikes suggested that some storm water bypassed the shallow soil layers. Significant differences, in soil-water content and δ18O values, within a small area, suggested that the proportion of immobile soil water and water flowing in subsurface pathways varies depending on local vegetation cover, soil characteristics and irrigation applications. Soil-water δ18O values revealed that preferential flow and diffuse flow coexist. Preferential flow was active within the root zone, independent of antecedent soil-water content, in both poplar forest and arable land, whereas diffuse flow was observed in grassland. The depleted δ18O spikes at 20–50 cm depth in the arable land suggested the infiltration of irrigation water during the dry season. Temporal isotopic variations in precipitation were subdued in the shallow groundwater, suggesting more complete mixing of different input waters in the unsaturated zone before reaching the shallow groundwater.