Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.     

GALILEO系统仿真与分析

本文着重阐述了GALILEO仿真系统星座和误差模型的构建过程,利用该系统进行DOP值分析并通过定位解算验证了GALILEO系统的性能指标。通过与GPS系统性能指标进行比较,得出GALILEO系统的星座设计具有较好的DOP值分布特性,定位精度优于GPS定位精度。在进行差分定位时,其误差贡献比较大的是接收机噪声和卫星钟差,因此提高差分定位的关键是降低接收机的噪声水平和提高卫星钟差预报精度。     

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.     

陡坡林区的LIDAR点云滤波方法

提出了基于坡度对陡坡林区LIDAR点云数据滤波的预处理算法,结合迭代最小二乘滤波方法改进了滤波效果,实测数据表明,有效地降低了第一类误差和第二类误差。     

基于GIS的区域经济统计分析系统的设计与实现

随着经济的发展,区域间经济相互作用和影响的关系越来越密切,忽略空间相互作用的传统区域经济分析手段和方法开始显现出一些明显的不足。而GIS在处理和分析区域地理数据上具有强大的空间分析能力,为此我们引入GIS工具对区域经济进行分析,相较于传统的分析手法有了很大改善。本文以江西省区域经济数据为例,设计了一个基于GIS的区域经济统计分析系统,并利用Arcob-jects二次开发控件结合VB可视化编程语言,实现了大部分区域经济统计分析功能,最后并将结果进行网络发布。研究结果表明将GIS引入到区域经济统计分析中,更能正确、有效的揭示区域经济发展在空间上的联系,为区域经济研究决策提供服务。     

点质模型求定月球重力场及其特征分析

利用Lunar-Prospector扩展任务的视线加速度数据,根据点质模型恢复了月球近区的重力场,将其与LP165月球重力场模型进行了比较和分析,并利用恢复的重力场联合月球地形数据对Mas-con进行分析,总结了月球重力场的主要特征及其研究方向发展趋势,将重力场恢复技术与我国的探月计划-"嫦娥"工程结合起来,为建立高精度的月球重力场和地形模型提供了一种有效而实用的方法。     

Magnetite-Fluorite Rock: A New Rock Type of Hot Water Sedimentation

The new type hot water sedimentary rock - magnetite-fluorite rock occurs as quasi-layers inflat parts of contact zones between rock body and strata in Bamiaushan of Changshan County,Zhejiang Province, China. The main mineral assemblage is fluorite magnetite cassiterite. The rockshows typical laminated structure and obvious mosaic texture. Its formation temperature is between123℃-160℃, averaging at 142℃. The major chemical composition of the rock includes CaF2, SiO2,Al2O3, FeO, and Fe2O3; the high-content microelement association includes W, Sn, Be, Rb, Sr, S, andCl; and the total content of REE is low (∑REE between 35.34x10-6-38.35x10-6), showing LREEenrichment type of distribution pattern. Diagenesis: driven by the tectonic stress, the formation waterheated in the deep strata had moved along the fissures or fractures in strata and had extractedcomponents from the strata on the way, and finally stagnated in the flat parts of contact zones betweenrock body and strata. With drop in temperature, magnetite and fluorite were separated from the hotwater and precipitated alternately, forming this hot water sedimentary rock with new typemineralogical composition, typical laminated structure, obvious mosaic texture and sub-horizontaloccurrence. The characteristics of the new type mineralogical composition, sedimentary tectonicenvironment and chemical composition are different from that of the well-known traditionalhydrothermai sedimentary rocks.     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

海量三维GIS数据可视化系统的实现研究

建立在OpenGL,OSG图形APIs和各种开源图片支持库之上,基于DEM、影像和常用的GIS地图数据文件,提出一套基于数据网格化管理、动态调度、LOD地形动态简化为主要思想的解决方案,成功构建了海量三维GIS数据可视化系统。系统基于102 G原始数据实现了流畅显示,并基于DEM数据与影像数据的合成实现了红绿立体显示效果,同时基于不同基础数据实现了各种数据的操作、分析等功能。     

玉米冠层FPAR的高光谱遥感估算研-基于PCA方法及近、短波红外波段

光合有效辐射分量(Fraction of Photosynthetically Active Radiation,FPAR)是进行生态系统功能和全球变化研究的重要参数,准确估算FPAR具有重要意义。通过对野外实测玉米高光谱数据和光合有效辐射数据的分析,探讨了主成分分析方法在高光谱信息提取及估算玉米冠层FPAR参数方面的可行性,在此基础上,结合植被指数验证FPAR估算效果,分析近红外及短波红外高光谱数据在FPAR估算方面的应用潜力。