GOCE: The Earth Gravity Field by Space Gradiometry

An artificial satellite, flying in a purely gravitational field is a natural probe, such that, by a very accurate orbit determination, would allow a perfect estimation of the field. A true satellite experiences a number of perturbational, non-gravitational forces acting on the shell of the spacecraft; these can be revealed and accurately measured by a spaceborne accelerometer. If more accelerometers are flown in the same satellite, they naturally eliminate (to some extent) the common perturbational accelerations and their differences are affected by the second derivatives of the gravity fields only (gradiometry). The mission GOCE is based on this principle. Its peculiar dynamical observation equations are reviewed. The possibility of estimating the gravity field up to some harmonic degree (200) is illustrated.     

GPS sensitivity analysis applied to non-permanent deformation control networks

This paper illustrates the surveys and the results obtained in an experiment whose goal is to evaluate the Global Positioning System (GPS) sensitivity and accuracy for deformation control on non-permanent network of different extensions. To this aim a high-precision device was properly built to set up known displacements along three orthogonal axes of a GPS antenna. One of the antennas in the considered GPS networks was moved according to centimeter and sub-centimeter displacements; after careful GPS data processing, it was evaluated whether these simulated deformations were correctly a posteriori detected and at which probability level. This experiment was carried out both on a local (baselines ranging between 3 and 30 km) and on a regional (baselines ranging between 300 and 600 km) GPS network. The results show that in the local network it is possible to identify the displacements at a level of 10 mm in height and at a level of 5 mm in horizontal position. The analysis of the regional network showed that it is fundamental to investigate new strategies to model the troposphere; in fact, it is necessary to improve the precision of the height in order to correctly identify displacements lower than 60–80 mm; on the contrary, horizontal displacements can be evidenced at the level of 20 mm. Received: 27 April 1998 / Accepted: 14 December 1998     

Sequence stratigraphy based on high-resolution seismic profiles in the late Pleistocene and Holocene deposits of the Venice area

The sequence-stratigraphic investigation by Very High-Resolution (VHR) seismic profiles allowed recognition of the detailed architecture of the late Pleistocene and Holocene succession of the Venice area. In this way deposits previously known by the analyses of scattered cores, mainly taken along the lagoon margin and the littoral strips, have been correlated at regional scale including the near offshore sector and the result has pointed out the lateral variability of the stratal architecture. Late Pleistocene deposits consist of an aggrading floodplain and fluvial channel fills accumulated during decreasing eustatic sea level, and they are coeval with offlapping forced regressive marine wedges in the Central Adriatic basin. The Holocene sequence is composed of three main seismic units separated by major stratal surfaces. Unit 1 (up to 9 m thick) is formed by channelized deposits separated by areas showing sub-horizontal and hummocky reflectors, and is bounded at the base by a surface that records prolonged conditions of subaerial exposure and at the top by a flatter surface resulting from erosion by marine processes. Deposits of Unit 1 are interpreted as estuarine and distributary channel fills, and back-barrier strata. Unit 2 is well distinguishable from Unit 1 only in the offshore area and at the barrier island bounding the Venice Lagoon, and is composed of a prograding marine wedge (up to 10 m thick) that interacts laterally with ebb tidal deltas. Unit 3 consists of a tidal channel complex and inlet deposits, which testify the evolution of the lagoon area. Tidal channels are entrenched in the lagoon mud flat (coeval with Units 1–2) and cut the Pleistocene–Holocene boundary in several places.Following current sequence-stratigraphic concepts, the Holocene sequence is composed of a paralic transgressive systems tract (TST) (Unit 1) overlying a sequence boundary (the Pleistocene–Holocene boundary) and overlain by a marine highstand systems tract (HST) (Unit 2) in seaward locations and by highstand lagoonal deposits landwards. TST and HST are separated by a downlap surface that is amalgamated with a wave ravinement surface in several places. Unit 3 is coeval with the upper part of Unit 2, and its development has been favoured by human interventions, which led to a transgression limited to the lagoon area.Local factors during the deposition, i.e. subsidence, sediment supply, physiography, and current/wave regimes, led to a significant lateral variability in the architecture of the Holocene sequence, as evidenced by the extreme thickness variation of the TST along both depositional strike and dip. The HST, instead, shows less pronounced strike variations in the stratal architecture. Also, present data clearly evidence that the human impact has a great relevance in influencing the late Holocene sedimentation.     

Polycyclic aromatic hydrocarbons (PAHs) in transplanted Manila clams (Tapes philippinarum) from the Lagoon of Venice as assessed by PAHs/shell weight index: A preliminary study

Variation of polycyclic aromatic hydrocarbons (PAHs) levels was assessed in Tapes philippinarum from the Lagoon of Venice. Clams were transplanted from a polluted area next to Porto Marghera to two rearing areas of the Southern Lagoon. Analyses of PAHs were made in sediments and clams by GC/MS at first sampling and after 30, 60 and 180 days. Principal component analysis was performed to elucidate bioaccumulation and depuration pattern and input sources. Biota-Sediment-Accumulation-Factor (BSAF) was applied to evaluate the PAHs input sources from sediment. Condition index was calculated to compare the seasonal variation of clam tissue to PAHs levels. To propose results not affected by seasonal changes in flesh weight of clams, the approach based on the calculation of PAHs/SW index was applied. From the results, it was concluded that PAHs/SW index is more recommendable to asses temporal variation of PAHs levels in Manila clams.     

Fourier Analysis Applied to Mimomys (Arvicolidae, Rodentia, Mammalia) First Lower Molars – Biochronological Implications

Fourier analysis was used in this study to help a specific determination of some Mimomys (Arvicolidae, Rodentia, Mammalia) species. Several Pliocene and Pleistocene Central and Western European Mimomys species first lower molar contours have been decomposed by Complex Discrete Fourier Transform. Inter- and intra-specific comparisons have been performed on the harmonics obtained from the decomposition and some problematic specimens have been classified.     

From the green color of eskolaite to the red color of ruby: an X-ray absorption spectroscopy study

The best known cause for colors in insulating minerals is due to transition metal ions as impurities. As an example, Cr³⁺ is responsible for the red color of ruby (α-Al₂O₃:Cr³⁺) and the green color of eskolaite (α-Cr₂O₃). Using X-ray absorption measurements, we connect the colors of the Cr _x Al_2−x O₃ series with the structural and electronic local environment around Cr. UV–VIS electronic parameters, such as the crystal field and the Racah parameter B, are related to those deduced from the analysis of the isotropic and XMCD spectra at the Cr L_2,3-edges in Cr_0.07Al_1.93O₃ and eskolaite. The Cr–O bond lengths are extracted by EXAFS at the Cr K-edge in the whole Cr _x Al_2−x O₃ (0.07≤x< 2) solid solution series. The variation of the mean Cr–O distance between Cr_0.07Al_1.93O₃ and α-Cr₂O₃ is evaluated to be 0.01₅ Å (≈1%). The variation of the crystal field in the Cr _x Al_2−x O₃ series is discussed in relation with the variation of the averaged Cr–O distances.     

The distribution of meiofauna on back‐reef sandy platforms in the Maldives (Indian Ocean)

The Maldivian archipelago comprises some of the most characteristic and significant world atoll systems, but the meiobenthic assemblages of these islands continue to be largely unknown. To investigate variations in meiofaunal spatial distribution and biodiversity in back‐reef platforms, three transects were studied, two at Felidhoo (the north and east sides) and one at South Malé. The sedimentological features of the samples obtained were also analyzed to further current knowledge on the relationships that exist between sediments and meiofauna. Our results reveal that the meiofaunal assemblage at these locations is well diversified and includes 20 major taxa. Nematodes and copepods are dominant, together forming 68% of the total meiofauna, followed by platyhelminthes, polychaetes and ostracods. The nematode assemblage is very rich and composed of 34 families and 123 genera – 96 of which (78%) set new records for the Maldives. The structures of the meiofaunal and nematode assemblages are relatively similar on the ‘large‐scale’ level (i.e. when the different platforms are compared) and reveal a low β‐diversity. However, significant dissimilarities were detected within each platform, emphasizing that such ‘small‐scale’ differences are the main factors determining the structure of the meiofauna and, in particular, the nematode assemblages. Although significant differences were not detected between the transects, greater levels of dissimilarity were recognized at North Felidhoo. Here, the building of inclined deposit layers plays a significant role in increasing the heterogeneity of the platform habitats and sediments, confirming the great importance of sediment granulometry as an environmental variable. Indeed, a close relationship is observed between meiofauna (especially for the nematodes) and grain size, which appears to control the structure, diversity and trophic composition of the Maldivian meiofauna assemblages, thus highlighting the high biodiversity existing in the medium‐coarse sands.     

Ground motion amplification due to shallow cavities in nonlinear soils

Subsurface cavities or stiff inclusions represent mechanical discontinuities for seismic waves propagating in soils. They modify the propagation pattern of seismic waves and alter soil response in correspondence to the ground level or building foundations. In the literature, different analytical and numerical solutions have been proposed to account for the effect of underground cavities or inclusions on the motion generated by P, S or R waves. In these former studies, the subsoil was assimilated to a homogeneous, isotropic and linear elastic halfspace containing one or more cavities. In the present study, the effect of subsurface cavities on ground motion amplification has been analysed accounting for soil stiffness degradation and associated damping increase with increasing levels of shear strains, a fundamental aspect of soil behaviour under earthquakes. The analysed model was inspired to a real case represented by the village of Castelnuovo (Italy), which during the 2009 Abruzzo earthquake suffered huge damage. The main shock (6 April 2009) caused the collapse of 50 % of the whole built environment. The historical centre of Castelnuovo rises on a hill. In its subsoil, there are many cavities with roofs 2–3 m below the ground level. The longitudinal NW–SE section of the hill has been investigated by 2D nonlinear site response analyses. A preliminary site response analysis was performed without modelling cavities, to identify ground motion amplification due to mere stratigraphic and topographic factors. The numerical model was later refined inserting: (1) a single cavity below the hilltop, (2) multiple cavities placed below the ground surface of the hill and (3) multiple cavities filled with concrete (inclusions). The performed study highlights the important role exerted by underground cavities on the ground motion computed at the hill surface. This effect should be properly considered for both microzonation studies and the correct determination of the seismic actions on specific buildings.     

Microstructure characteristics during hydrate formation and dissociation revealed by X-ray tomographic microscopy

Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.