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Physical and chemical activation of pyrolyzed oil shale residue for the adsorption of phenol from aqueous solutions 总被引:4,自引:0,他引:4
Batch kinetics and isotherm studies were carried out to evaluate the sorption of phenol by pyrolyzed and activated Jordanian oil-shale. The effects of contact time, initial sorbate concentration, sorbent concentration, temperature, pH and inorganic salts (NaCl and KCl), on the adsorption process by different sorbents were considered. Chemically activated oil shale, pretreated with ZnCl 2, gave the highest uptake of phenol. The isotherm experimental data fit well to Freundlich and Redlich-Paterson models and to a less extent to the Langmuir model. The increase in the initial sorbate concentration resulted in an increase in the uptake. Three kinetics models, namely the Morris-Weber model, the Lagergren model, and the pseudo-second-order model (PSOM), were applied to represent the experimental results for pyrolyzed and ZnCl 2-oil shale sorbents. Pyrolyzed oil shale was prepared using a fluidized bed reactor at 520 °C in the presence of nitrogen. Physical activation was carried out by treating the resulted pyrolyzed oil shale with CO 2 at 830 °C, while chemical activation of oil shale was carried out using KOH and ZnCl 2 as impregnating agents. 相似文献
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Fawzi Asadi Dr. 《GeoJournal》1990,21(4):375-383
A key objective of the Israeli occupation of the West Bank and Gaza Strip in Palestine has been to render the economy of these regions dependent on the Israeli economy and thus hamper their economic development. Large areas of land have been confiscated or expropriated by the Israeli authorities to establish Jewish settlements. Other severe measures imposed include control of irrigation water and obstacles for the Arab agricultural and industrial sector in the Occupied Territories aimed at preventing Arab competition with Israeli products.Palestinian agriculturalists have met this challenge and have worked to achieve higher production levels in agriculture. Nonetheless, economic development there was blocked, and many agriculturalists sought employment inside Israel. The Intifada since December 1987 has aimed at encouraging Arab economic independence and intensification of efforts to meet national requirements of greater self-sufficiency in subsistence crops and stimulation of agriculture-related industries. The Intifada is thus functioning as a stimulus to development and economic viability. 相似文献
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Adsorption of copper and zinc by oil shale 总被引:8,自引:0,他引:8
Oil shale is able to remove appreciable amounts of copper and zinc ions from aqueous solutions. It was noted that an increase
in the adsorbent concentration with constant copper or zinc concentration resulted in greater metal removal from solution.
An increase in the copper or zinc concentration with a constant sorbent concentration resulted in higher metal loading per
unit weight of sorbent. For both metals, copper and zinc, equilibrium was attained after 24-h contact time. Increase in the
initial pH or temperature of the metal solution resulted in an increase in the metal uptake per unit weight of the sorbent.
Freundlich isotherm model was found to be applicable for the experimental data of Cu2+ and Zn2+. The results showed that oil shale could be used for the adsorption of the Cu2+ and Zn2+ with higher affinity toward Zn2+ ions. Addition of sodium salt to the metal solution influenced copper removal positively, but inhibited zinc removal.
Received: 3 January 2000 · Accepted: 27 June 2000 相似文献
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Marco Moro Michele Saroli Stefano Salvi Salvatore Stramondo Fawzi Doumaz 《Geomorphology》2007,89(3-4):297-307
This paper re-evaluates the origin of some peculiar patterns of ground deformation in the Central Apennines, observed by space geodetic techniques during the two earthquakes of the Colfiorito seismic sequence on September 26th, 1997. The surface displacement field due to the fault dislocation, as modelled with the classic Okada elastic formulations, shows some areas with high residuals which cannot be attributed to non-simulated model complexities. The residuals were investigated using geomorphological analysis, recognising the geologic evidence of deep-seated gravitational slope deformations (DSGSD) of the block-slide type. The shape and direction of the co-seismic ground displacement observed in these areas are correlated with the expected pattern of movement produced by the reactivation of the identified DSGSD. At least a few centimetres of negative “Line of Sight” ground displacement was determined for the Costa Picchio, Mt. Pennino, and Mt. Prefoglio areas. A considerable horizontal component of movement in the Costa Picchio DSGSD is evident from a qualitative analysis of ascending and descending interferograms. The timing of the geodetic data indicates that the ground movement occurred during the seismic shaking, and that it did not progress appreciably during the following months. This work has verified the seismic triggering of DSGSD previously hypothesized by many researchers. A further implication is that in the assessment of DSGSD hazard seismic input needs to be considered as an important cause of accelerated deformation. 相似文献
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We investigated the northern-central portion of Sicily region (southern Italy) using aerial photographs and Synthetic Aperture Radar (SAR) data obtained by ERS1 and ERS2 satellites. This area shows a geological-structural setting generated by the tectonic superposition of Apenninic-Maghrebian carbonatic structures on terrigenous deposits. Such a structural setting favoured the development of large-scale gravity-driven phenomena (known in the geological literature as deep-seated gravitational slope deformations) that are mostly responsible for the landscape evolution of the whole area. Morphological evidences such as landslides, sacking or rock-flow, lateral spread and block slide can be detected from photogeological analysis. In order to understand the temporal behaviour and spatial distribution of such deformations we applied the interferometric SAR (InSAR) technique. Interferograms show fringe patterns spatially coinciding with some of the large-scale gravitative phenomena previously identified by means of aerial-photo analysis. The comparison between photogeological data and InSAR results allows delimiting the active sectors in the study area. 相似文献
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In this study, we provide the first absolute ages for a Big Circle megalithic structure in Jordan, using rock surface luminescence dating of the buried surface of rocks collected from circle J4 in southern Jordan. Five rocks were used for this study. All rocks showed evidence of previous daylight exposure before being used in the construction of the circle. The exposure was sufficient to bleach the latent luminescence signal to a negligible level compared to the subsequent burial dose. Three rocks gave indistinguishable ages, and were last exposed to daylight in 1500 ± 100 BCE; this is very likely to be the date of circle construction. Two others gave younger ages, indicating later disturbance or reworking. These new results provide very strong evidence for construction during the Late Bronze Age, and refute the earlier hypothesis of construction during Umayyad period (661–750 CE) as a hunting trap. 相似文献