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111.
Multicomponent reactive transport modeling of uranium bioremediation field experiments 总被引:1,自引:0,他引:1
Yilin Fang Steven B. Yabusaki James P. Amonette 《Geochimica et cosmochimica acta》2009,73(20):6029-290
A reaction network integrating abiotic and microbially mediated reactions has been developed to simulate biostimulation field experiments at a former Uranium Mill Tailings Remedial Action (UMTRA) site in Rifle, Colorado. The reaction network was calibrated using data from the 2002 field experiment, after which it was applied without additional calibration to field experiments performed in 2003 and 2007. The robustness of the model specification is significant in that (1) the 2003 biostimulation field experiment was performed with 3 times higher acetate concentrations than the previous biostimulation in the same field plot (i.e., the 2002 experiment), and (2) the 2007 field experiment was performed in a new unperturbed plot on the same site. The biogeochemical reactive transport simulations accounted for four terminal electron-accepting processes (TEAPs), two distinct functional microbial populations, two pools of bioavailable Fe(III) minerals (iron oxides and phyllosilicate iron), uranium aqueous and surface complexation, mineral precipitation and dissolution. The conceptual model for bioavailable iron reflects recent laboratory studies with sediments from the UMTRA site that demonstrated that the bulk (∼90%) of initial Fe(III) bioreduction is associated with phyllosilicate rather than oxide forms of iron. The uranium reaction network includes a U(VI) surface complexation model based on laboratory studies with Rifle site sediments and aqueous complexation reactions that include ternary complexes (e.g., calcium-uranyl-carbonate). The bioreduced U(IV), Fe(II), and sulfide components produced during the experiments are strongly associated with the solid phases and may play an important role in long-term uranium immobilization. 相似文献
112.
Mountain areas are often rich in ecological diversity and recreational opportunities. Mountain tourism is thought to be an effective and important means for maintaining and expanding rural economies and, thus, improving the living conditions of rural societies. As mountain tourism service research is a professional field with several disciplines involved, a multi-disciplinary management pIatform is needed and it facilitates participation in sustainable mountain development by diverse stakeholders. With the source regions of the Yangtze and the Yellow River as a case study, this paper presents a conceptual framework for an adaptation management of mountain tourism services according to technical, policy, social and economic dimensions. The framework is based on a vulnerability assessment of mountain ecosystems, and can serve as a reference for the development of tourism service in other mountain areas. 相似文献
113.
针对现有速度场模型采用数据少、现势性不强的问题,详细论述了速度场模型建立的数据获取与处理方法,利用中国大陆地壳运动监测网络中260个连续运行基准站2011~2015年的连续观测数据,采用GAMIT/GLOBK与GMT软件,获得高精度的定位及速度成果,并基于上述速度成果采用克里金插值法构建了中国大陆地壳运动速度场1°×1°格网模型。最后利用IERS公布的中国区域7个IGS站实测速度以及全国范围内均匀分布的陆态网络区域站实测速度,对模型内插结果进行检核,验证了模型的现势性、精确性和可靠性。 相似文献
114.
本文应用统计方法,首先探讨南方涛动指数与西北太平洋副热带高压的联系,然后分析赤道和热带太平洋区域海温对南方涛动的响应情况,同时分析南方涛动响应区域的海温与当时及滞后的西北太平洋副热带高压的联系,从中探讨南方涛动、厄尔尼诺海温异常及西北太平洋副热带高压之间的一种可能的相互作用机制。 相似文献
115.
Yun Jiang Piers Koefoed Olga Pravdivtseva Heng Chen Chun‐Hui Li Fang Huang Li‐Ping Qin Jia Liu Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76
The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
116.
There is observational evidence showing that stellar and solar flares occur with a similar circumstance, although the former are usually much more energetic. It is expected that the bombardment by high-energy electrons is one of the chief heating processes of the flaring atmosphere. In this paper we study how a precipitating electron beam can influence the line profiles of Ly α , H α , Ca ii K and λ 8542. We use a model atmosphere of a dMe star and make non-LTE computations taking into account the non-thermal collisional rates owing to the electron beam. The results show that the four lines can be enhanced to different extents. The relative enhancement increases with increasing formation height of the lines. Varying the energy flux of the electron beam has different effects on the four lines. The wings of Ly α and H α become increasingly broad with the beam flux; change of the Ca ii K and λ 8542 lines, however, is most significant in the line centre. Varying the electron energy (i.e. the low-energy cut-off for a power-law beam) has a great influence on the Ly α line, but little on the H α and Ca ii lines. An electron beam of higher energy precipitates deeper, thus producing less enhancement of the Ly α line. The Ly α /H α flux ratio is thus sensitive to the electron energy. 相似文献
117.
Trachysalambria curvirostris is an economically important shrimp in the coastal waters of the Western Indo-Pacific. However, there is no information about its carotenoid composition and distribution.The carotenoid profiles including concentration, composition, molecular forms(free or esterified) and configuration(geometrical and optical isomers) of raw and dried T. curvirostris(Stimpson, 1860) were qualitatively and quantitatively assessed. In the raw shrimp, astaxanthin and β-carotene were the two dominant carotenoids, which contributed 75.18%–88.86% and 2.86%–16.83% of the total carotenoid content. Traces of echinenone, canthaxanthin and astacene were also detected. The carotenoid content in the waste(80.28 mg/kg dry weight) was nearly two-fold higher than that in the meat(49.69 mg/kg dry weight). Of the total astaxanthin in these shrimp, 85.18%–90.59% was esterified. All-trans astaxanthin was the predominant geometrical isomer followed by 13-cis, 9-cis, di-cis and 15-cis isomers. A mix of three stereoisomers was found in all parts and the percentages of meso(3 S, 3' R) and(3 S, 3' S) forms were significantly higher than the(3 R, 3' R) isomer. Compared to the carotenoid content of the raw shrimp,only 26.17 mg/kg remained in the dried shrimp. Nearly half of the carotenoids were lost during the drying process. Substantial hydrolysis and isomerization also occurred. 相似文献
118.
We developed a method to automatically detect and trace solar filaments in Hα full-disk images. The program is able not only to recognize filaments and determine their properties, such as the position, the area, the spine, and other relevant parameters, but also to trace the daily evolution of the filaments. The program consists of three steps: First, preprocessing is applied to correct the original images; second, the Canny edge-detection method is used to detect filaments; third, filament properties are recognized through morphological operators. To test the algorithm, we successfully applied it to observations from the Mauna Loa Solar Observatory (MLSO). We analyzed Hα images obtained by the MLSO from 1998 to 2009 and obtained a butterfly diagram of filaments. This shows that the latitudinal migration of solar filaments has three trends in Solar Cycle 23: The drift velocity was fast from 1998 to the solar maximum, after which it became relatively slow. After 2006, the migration became divergent, signifying the solar minimum. About 60 % of the filaments with latitudes higher than 50° migrate toward the polar regions with relatively high velocities, and the latitudinal migrating speeds in the northern and the southern hemispheres do not differ significantly in Solar Cycle 23. 相似文献
119.
ZHOU Yuliang LU Guihua JIN Juliang TONG Fang ZHOU Ping 《中国海洋大学学报(英文版)》2006,5(4):322-326
Precise comprehensive evaluation of flood disaster loss is significant for the prevention and mitigation of flood disasters. Here, one of the difficulties involved is how to establish a model capable of describing the complex relation between the input and output data of the system of flood disaster loss. Genetic programming (GP) solves problems by using ideas from genetic algorithm and generates computer programs automatically. In this study a new method named the evaluation of the grade of flood disaster loss (EGFD) on the basis of improved genetic programming (IGP) is presented (IGP-EGFD). The flood disaster area and the direct economic loss are taken as the evaluation indexes of flood disaster loss. Obviously that the larger the evaluation index value, the larger the corresponding value of the grade of flood disaster loss is. Consequently the IGP code is designed to make the value of the grade of flood disaster be an increasing function of the index value. The result of the application of the IGP-EGFD model to Henan Province shows that a good function expression can be obtained within a bigger searched function space; and the model is of high precision and considerable practical significance. Thus, IGP-EGFD can be widely used in automatic modeling and other evaluation systems. 相似文献
120.